IPKM/dissertation-latex
4
0
Fork 0
Code Issues Pull Requests Projects Activity

Initial commit

Browse Source
This commit is contained in:
Christoph Saecke
2025-09-26 14:58:01 +02:00
parent 78b05938f5
commit 7eac92f9b4
52 changed files with 30729 additions and 0 deletions
Download Patch File Download Diff File Expand all files Collapse all files

18
Diss_Abstract.tex Normal file
View File

@@ -0,0 +1,18 @@
{\selectlanguage{ngerman}
\chapter{Zusammenfassung}
%
Dieses Dokument soll künftigen Doktoranden als \LaTeX\space Vorlage für Dissertationen dienen und enthält Hinweise und Beispiele, von denen ich mir gewünscht hätte sie im Voraus zu wissen. Ich hoffe es hift euch, aber ich kann weder für Richtigkeit noch Nützlichkeit garantieren. Ich werde davon ausgehen, dass ihr bereits mit grundlegenden \LaTeX-Funktionen vertraut seid. An manchen Stellen wird man, anstatt nur das pdf zu lesen, in den Quellcode schauen müssen um die Vorlage sinnvoll nutzen zu können. Zum Beispiel die Titelseiten (Titelseite, bibliographische Informationen, Promotionsordnung) haben einige auskommentierte Hinweise im \LaTeX\space Code zu den formalen Anforderungen und dem Hochladen auf TUprints. Diese Hinweise wollte ich nicht im PDF erscheinen lassen, damit sie für eine echte Dissertation nicht gelöscht werden müssen. Oft habe ich versucht den entsprechenden \LaTeX\space Code direkt im PDF erscheinen zu lassen, sodass ihr ihn (fast direkt, Vorsicht vor zusätzlichen Leerzeichen) copy-pasten könnt, und eine Beispielanwendung mitzuliefern. Ich selbst habe mich zu Beginn auch an einer Sammlung von Hinweisen zur \LaTeX-Dissertationen orientiert, die ich im Internet gefunden habe, schaut gerne auch dort vorbei: \url{http://alexanderfabisch.github.io/latex-for-dissertations.html} Stand 2023-03-22.%
}%end of \selectlanguage{ngerman}
\glsresetall%reset first-use tags in all glossary types, such that they are spelled out in the abstract of the secondary language as well. Currently (2025-08-07) relevant are the acronym and ignored glossaries.
%This reset could lead to problems if there are acronyms which appear in the abstract and only once elsewhere: They should have their short form introduced, but due to the reset, are counted as occurring only once, i.e. will only be displayed in their long form without the abbreviation. Similar problems arise if the acronym occurrs only once in the abstract and nowhere else, then it won't appear in the glossary. You will need to find a fancy general solution or manually handle such cases, e.g. via the \glsunset command
%
\begingroup
%save space by avoiding a pagebreak between a new part and its first chapter
\renewcommand{\cleardoublepage}{}%only necessary if the openright option is used. Otherwise only acting on \clearpage is sufficient, but keeping \cleardoublepage does no harm.
\renewcommand{\clearpage}{}
\chapter{Abstract}
\endgroup%reinstate normal function of the clearpage commands
%
This document is meant as a \LaTeX\space template to help future PhD students write their dissertations and contains notes and examples which I would have liked to know in advance. I hope it helps, but cannot guarantee that I got everything right. I will assume that you are familiar with the basic functions of \LaTeX. In some cases, you will need to look at the source code rather than the pdf to make sense of the template. For instance, the title pages (title page, bibliographic information, Promotionsordnung) contain some commented notes in the \LaTeX\space code regarding the formal requirements and upload to TUprints. I did not want these notes to appear in the pdf such you don't need to delete them in your actual dissertation. I often tried to display the \LaTeX\space code in the pdf, so you can copy and paste it (nearly as is, mind additional whitespaces), and also provide an example of what it looks like in practice. I myself took initial advise from a collection of notes for \LaTeX\space dissertations I found on the internet, you are encouraged to also visit: \url{http://alexanderfabisch.github.io/latex-for-dissertations.html} as of 2023-03-22.%
\glsresetall%reset first-use tags in all glossary types. Currently (2025-08-07) relevant are the acronym and ignored glossaries.
%This reset could lead to problems if there are acronyms which appear in the abstract and only once elsewhere: They should have their short form introduced, but due to the reset, are counted as occurring only once, i.e. will only be displayed in their long form without the abbreviation. Similar problems arise if the acronym occurrs only once in the abstract and nowhere else, then it won't appear in the glossary. You will need to find a fancy general solution or manually handle such cases, e.g. via the \glsunset command

41
Diss_AcademicCV.tex Normal file
View File

@@ -0,0 +1,41 @@
%https://www.tu-darmstadt.de/media/dezernat_ii/promotionen_dokumente/Dissertation-Titelblatt.de.pdf
%https://www.physik.tu-darmstadt.de/media/fachbereich_physik/formulare_3/promotionen/besonderebestimmungenderphysikzurpromo.pdf
\begin{titlepage}
% depending on you style preferences, you may also want to look at silentsections for the academic CV.
% \phantomsection
% \silentsection{Academic CV}
% \silentchapter{Academic CV}
%\includegraphics{athene}
% {\centering\huge\textbf{
% Academic CV\\[2\bigskipamount]%Cirriculum Vitae
% }}
\chapter{Academic CV}
% the tuprints publication team recommended not to make personal data (date and place of birth) public.
% {\large
% \begin{tabular}{ll}
% \textbf{Name}: & \myauthor \\
% \textbf{Year and \myplaceBirth}: & Your Date and Place of Birth \\%you may want to only give the year of your birthdate for data privacy reasons
% \end{tabular}
% }\\[2\bigskipamount]
{\large
\begin{tabular}{ll}
% \textbf{Education} & \\%if the paragraph with personal data is omitted, it looks nicer to also omit the ``Education'' headline
% & \\
2019-2025: & Doctorate Physics \\
& TU Darmstadt\\
& \\
2017-2019: & M.Sc. Physics \\
& TU Darmstadt\\
& \\
2013-2017: & B.Sc. Physics \\
& TU Darmstadt\\
& \\
2004-2012: & Abitur \\
& Friedrich-Dessauer-Gymnasium Aschaffenburg\\
\end{tabular}
}\\[2\bigskipamount]
\end{titlepage}

2
Diss_Acknowledgements.tex Normal file
View File

@@ -0,0 +1,2 @@
\chapter{Acknowledgements}
No new \LaTeX\space tricks.

26
Diss_Appendix.tex Normal file
View File

@@ -0,0 +1,26 @@
\part{Appendix}\label{sec:appendix}
%
\begingroup
\renewcommand{\cleardoublepage}{}%only necessary if the openright option is used. Otherwise only acting on \clearpage is sufficient, but keeping \cleardoublepage does no harm.
\renewcommand{\clearpage}{}
\chapter{Including the Appendix in your Main File}
%\endgroup%here, I do not reinstate the normal clearpage commands because I dont want chapters in the appendix to cause a pagebreak in general. And I also dont need the clearpage commands for something else. Alternatively, I could begin and end groups around every chapter
%
Before you start the appendix, either by writing directly in your document or by inserting a separate .tex file, you should use the \mbox{\textbackslash appendix} command, cf. main file of this template.
\begin{lstlisting}
\appendix%signals some commonly reasonable changes, e.g. a change in chapter numbering from arabic to alphabetic
\input{Diss_Appendix.tex}%information which is nice to have, but not essential to follow the arguments in the main text
\end{lstlisting}
\chapter{Reusing (Parts of) an Equation}\label{sec:appdx_relaxation-specdens-sto}
\endgroup% reinstate the normal clearpage commands
%
\Eqpl{eqs:autocorrelation-specdens} make use of macros which print a given math expression, such that I can derive this expression in the appendix and use the exact same expression (including potential future changes) in the main text. To help you jump back and forth in this template, have this poorly formatted (you are not supposed to reference the repeat equation anyway) link: \cref{dummytag}.
\begin{subequations}\label{eqs:autocorrelation-specdens}
\begin{align}
\correlationfunctiondef{&} \label{eq:autocorrelation}
\intertext{and its half-sided Fourier transform}
&\tilde{J}_{2,\RankOrderTypeface{m}}(\omega) \equiv \spectraldensitydefRHS \eqend{where $\omega = -\gamma B_0$} \eqend{.} \label{eq:specdens_tilde}
\end{align}
\end{subequations}
%

79
Diss_Bibliography.tex Normal file
View File

@@ -0,0 +1,79 @@
\usepackage[
sortcites=false,%sorts the citations in the order of the references if more than one is cited in a single command. Didnt trust the package option and sorted all references of a given citation command manually. Other sort styles may be possible, see https://tex.stackexchange.com/questions/361031/biblatex-how-to-automatically-sort-citation-by-year-sortcites-ynt-when-refere
%sorting=ynt,%sorting command may be discontinued due to bugs. try referencecontext instead.
style=alphabetic,%changing style to numeric saves only 2 pages at a total of 326 references. Could try numeric+superscript if pagecount becomes an issue.
natbib=true,
backend=bibtex,
maxnames=\globalmaxnames,%sets maximum number of names in citations for both intext (maxcitenames) as well as bibliography.
maxalphanames=2,%not sure what max|minalphanames do differently from max|mincitenames, but if I use them it looks like I want it to.
minalphanames=1,
minnames=1,%if number of names in citation is larger than maxnames, cut after minnames-many names and add '+'
maxbibnames=99,%overwrite maximum number of names bevor truncations in bibliography
uniquelist=true,%allows deviations from maxnames to make lists unique
backref,%references the pages where the citation was used
%url=false,%url can be set to false to ignore the url-fields of the .bib file. Do not want to generically throw away urls here, because I want to cite e.g. the grace-website. URLs are handled below.
]{biblatex}
\usepackage{xurl}% load after biblatex. Avoids URLS of references reaching into the margin. see https://tex.stackexchange.com/questions/686510/break-line-in-bibliography-for-doi
%avoid references with (chemicals in) titles reaching into the margins by adding discretionary hyphens (\-) in the affected entries of the .bib file. see https://tex.stackexchange.com/questions/381542/article-title-not-linebreaking-correctly-in-bibliography
%failed to have bibliography in two columns, except for the title. Contending myself with smaller font to keep required space reasonable.
%https://tex.stackexchange.com/questions/137100/two-columns-10pt-bibliography-specific-pages-only-in-a-one-column-12pt-text
\appto{\bibfont}{\small}%onecolumn, normal fontsize: 40 pages. small: 32 pages. footnotesize: 28 pages
%\appto{\bibsetup}{\raggedright\twocolumn}
%\AtEndBibliography{\onecolumn}
%https://tex.stackexchange.com/questions/20758/bibliography-in-two-columns-section-title-in-one
%\usepackage{multicol}
%\usepackage{etoolbox}
%\patchcmd{\thebibliography}{\section*{\refname}}
%{\begin{multicols}{2}[\section*{\refname}]}{}{}
%\patchcmd{\endthebibliography}{\endlist}{\endlist\end{multicols}}{}{}
\AtBeginRefsection{\GenRefcontextData{sorting=ynt}}%ensure that (also) a ynt sorted refcontext is created
\AtEveryCite{\localrefcontext[sorting=ynt]}%use the ynt refcontext for sorting within a citation. Did not trust this and sorted references manually, if there were multiple references in a single citation command
%different devices use had the .bib files stored in different directories. Could have used relative paths, but didnt.
%\addbibresource{C:/Users/saeck/Promotion/Sync_Seafile/Literatur_Promotion/Library/Promotion_Literatur.bib}%Laptop
%\addbibresource{F:/Seafile/Seafile/Sync_Seafile/Literatur_Promotion/Library/Promotion_Literatur.bib}%(Home Desktop)
\addbibresource{Promotion_Literatur.bib}%(path to bibliography file. In the case of this template, the file is in the same directory as the .tex documents)
%do not cite fields like 'comment' in the bibliography
\AtEveryBibitem{%
\clearfield{note}%
% \clearfield{url}%handled below
\clearfield{eprint}%
\clearfield{isbn}%
\clearfield{issn}%
\clearfield{month}%
\clearfield{abstract}%
\clearfield{creationdate}%
\clearfield{pages}%
\clearfield{file}%
\clearfield{issue}%
\clearfield{number}%
\clearfield{keywords}%
\clearfield{numpages}%
\clearfield{printed}%
\clearfield{ranking}%
\clearfield{readstatus}%
\clearfield{edition}%did not enter edition for every book and want to keep output consistent. Also, output formatting for first editions ("First") is for some reason different from other editions ("2nd ed.")
}
% want to show specific URLs only. Solution stolen from: https://tex.stackexchange.com/questions/152869/show-url-only-for-one-reference, 2024-11-04
%create a new category, for which the URL will be printed in the references
\DeclareBibliographyCategory{needsurl}
\newcommand{\entryneedsurl}[1]{\addtocategory{needsurl}{#1}}
\renewbibmacro*{url+urldate}{%
\ifcategory{needsurl}
{\printfield{url}%
\iffieldundef{urlyear}
{}
{\setunit*{\addspace}%
\printurldate}}
{}}
%manually mark bib-entries which should have their URL printed in the references
\entryneedsurl{PubChem2005NIPAM}
\entryneedsurl{PubChem2005NIPPA}
\entryneedsurl{grace1991}%grace
\entryneedsurl{Demuth2023}%nmreval
\entryneedsurl{MarvinDemo}%free demo version of marvin sketch

12
Diss_Conclusion.tex Normal file
View File

@@ -0,0 +1,12 @@
\part{Conclusion}\label{sec:conclusion}
%
%\glsresetall[acronym]%reset acronyms to have the long forms displayed in case someone only reads the conclusion. Tracking which terms only occur once in the whole document, and thus should not have an abbreviation introduced, is done in the glossary document as described here: https://tex.stackexchange.com/questions/646615/resetting-glossaries-abbreviations-each-chapter
%
In the conclusion, I want to reintroduce acronyms as if they had not been mentioned before, see \cref{sec:glossary_occurrence_counts}. This way, since some readers may read only the conclusion, they don't have to look through the glossary to find out what the acronym stands for. However, as for any mention of acronyms in the document, if there is only one document-wide use of some acronym that happens to be placed in the conclusion (maybe in a paragraph about future projects / outlook), the term should be spelled out without introducing its abbreviation. This makes complete glossary resets a bad idea and makes a completely automatized solution very tricky, although not impossible. As a compromise, I manually used the \mbox{\textbackslash fakefirstacr} macro for every conclusion-first occurrence of an acronym.\\\\
%
%
I mention \fakefirstacr{pNIPAM} twice \pNIPAM, as an example for an often-used acronym. I mention what a \glsreset{athermal}\gls{athermal} state is to check proper function of the non-acronym glossary and also use the test case from before (see \cref{sec:glossary_occurrence_counts_resets}), \fakefirstacr{TMUSC}, and another test case now: \gls{TSUC}. If you care about acronym formatting depending on their occurrence count (e.g. more than one occurrence), don't forget to also check the single-use test acronym in \cref{sec:glossary_occurrence_counts}.
%
%testing acronym usage after a complete glossary reset
%\glsresetall
%I mention \gls{pNIPAM} twice \pNIPAM, as an example for an often-used acronym. I mention what a \glsreset{athermal}\gls{athermal} state is to check proper function of the non-acronym glossary and also use the test case from before, \gls{TMUSC}, and another test case now: \gls{TSUC}. If you care about acronym formatting depending on their occurrence count (e.g. more than one occurrence), don't forget to also check the single-use test acronym in \cref{sec:glossary_occurrence_counts}.

170
Diss_ConvenienceCommands.tex Normal file
View File

@@ -0,0 +1,170 @@
%may need to define type of input for \newcommands if autocompletion is desired.
%See https://htmlpreview.github.io/?https://github.com/texstudio-org/texstudio/master/utilities/manual/usermanual_en.html#classification-format for documentation.
%See https://github.com/texstudio-org/texstudio/wiki/Frequently-Asked-Questions#why-does-a-command-not-show-up-in-the-completion for further explanations
%texstudio paths:
%/autohome/saeckech/.config/texstudio/completion/ (office computer)
%global booleans
\newif\ifshownotes%created a variable "shownotes" which I could set to be true or false, which was then used to show or hide a sections of text
\shownotesfalse% sets the value of this variable to false. change the ending from "false" to "true" to set it to true. I.e.: \shownotesfalse or \shownotestrue
%https://tex.stackexchange.com/questions/61933/best-practice-for-getting-if-not-foo-conditionals
%global plot parameters
\newcommand{\wrapfigscaling}{0.9\linewidth}%used as the default value for how much of the linewidth a figure with wrapped-around text should occupy. (Ended up not using wrapped text after all)
\def\defaultfigurewidth{0.95\linewidth}%used as the default value for how much of the linewidth a figure with a single panel should occupy
\def\defaulttwosubfigwidth{0.49\linewidth}%used as the default value for how much of the linewidth a figure with two panels should occupy
%
%mosaic plots were not used after all in my final dissertation version.
%\def\mosaiccolumnbig{0.575\linewidth}%used as the default value for how much space a big panel in a mosaic plot should occupy. I only used two sizes of panels in mosaic plots
%\def\mosaiccolumnsmall{0.375\linewidth}%used as the default value for how much space a small panel in a mosaic plot should occupy. I only used two sizes of panels in mosaic plots
\def\defaultfigureSmallHeight{5cm}%another default value, e.g. for a series of photos of the sample over time. Did not need to be as large as figures with data in my case
\captionsetup{format=plain, labelfont+=bf}%handles formatting of figure captions. https://latex-tutorial.com/caption-customization-latex/
%citations
%This commands overrides the biblatex maxcitenames package option% https://tex.stackexchange.com/questions/454868/biblatex-change-maximum-number-of-authors-locally
\makeatletter
\newrobustcmd*{\setmaxcitenames}{\numdef\blx@maxcitenames}
\makeatother
\def\globalmaxnames{2}%store number of names before abbreviating to "author et al". in a variable, so that it can be changed and reset in special cases (i.e. the group of Winnik et al. intensively studied cononsolvency with methanol)
%example: %\setmaxcitenames{1}\textcite{Winnik1990}\setmaxcitenames{\globalmaxnames}
%solution for new textcite command with only one author for different citation style: https://tex.stackexchange.com/questions/137104/new-command-like-textcite-but-with-only-one-author
%glossary shorthands: often-used glossary terms for which I did not want to type the glossary command every time.
%the \xspace command determines whether a space should be added (more words follow) or not (interpuncation follows). Package says that one should manually check whether it worked appropriately, but I did not have much trouble with it. Can be combined with the \unskip command to handle special cases
\newcommand{\AEON}{\SI{1}{\giga\hertz}-AEON spectrometer\xspace}
\newcommand{\CPMG}{\gls{CPMG}\xspace}
\newcommand{\LCST}{\gls{LCST}\xspace}
\newcommand{\pNIPAM}{\gls{pNIPAM}\xspace}
%\newcommand{\pNIPAMadj}[1]{\mbox{\pNIPAM-}\allowbreak#1\unskip\xspace}%adjectives such as ``pNIPAM-based''
\newcommand{\pNIPAMbinary}[1]{\mbox{\pNIPAM/}\allowbreak#1\unskip\xspace}%pNIPAM in binary mixtures such as ``pNIPAM/water''
\newcommand{\pNIPAMternary}[2]{\mbox{\pNIPAM/}\allowbreak \mbox{#1\unskip/}\allowbreak #2\unskip\xspace}%pNIPAM in ternary mixtures such as ``pNIPAM/ethanol/water''
%above few commands in their german version: (not used often but defined as commands to remember adjusting german versions as well if changes are made to english versions)
%in case you regularly need secondary-language acronym adaptions, see https://tex.stackexchange.com/questions/136634/glossaries-acronyms-two-languages or https://tex.stackexchange.com/questions/128334/using-bi-lingual-entries-with-the-glossaries-package
%otherwise, you can simply create new entries. Mind that they may appear in the glossary
%\newcommand{\PNIPAMadj}[1]{\mbox{\gls{pNIPAMgerman}-}\allowbreak#1\unskip\xspace}
%commands for future typesetting. I used a bunch of those, but only keep a few examples here.
%note: starred version of \newcommand have additional error checking and are apparently considered better practice, unless weird arguments require the non-starred version. I wont adhere to this however, because I dont care.
\newcommand{\AxisTypeface}[1]{\ensuremath{\mathrm{#1}}\xspace}%defer final decision on whether e.g. x in x-axis is a variable (italic) or descriptive (roman)
\newcommand*\chem[1]{\ensuremath{\mathrm{#1}}}%math mode to allow subscripts as in $H_2O$. Could also have used \textsubscript instead. Use a macro to penaltize hyphenation and easily unify (and possibly change) typesetting. Big packages like mchem or chemformula are a bit overkill for me.
\newcommand{\eqend}[1]{\text{\quad#1}}%argrument is for interpunctation in math environment after an equation.
\newcommand{\eqpl}[1]{eqs.~\eqref{#1}}%reference a parent equation. pluralequation crefformat (https://tex.stackexchange.com/questions/35772/referencing-subequations-with-cleveref) did not work.
\newcommand{\Eqpl}[1]{Equations~\eqref{#1}}
\newcommand{\HamOpQP}{\ensuremath{\hat{H}_\mathrm{Q}}}%Hamilton operator for quadrupolar interaction
\newcommand{\wL}{\ensuremath{\omega_\mathrm{L}}\xspace}%Larmor frequency
\newcommand{\RankOrderTypeface}[1]{\ensuremath{\mathrm{#1}}\xspace}%defer final decision on whether e.g. rank of a spherical harmonic is a variable (italic) or descriptive (roman)
\newcommand{\Rh}{\ensuremath{R_\mathrm{h}}}%hydrodynamic radius
\newcommand{\QCC}{\ensuremath{C_\mathrm{Q}}\xspace}%{\textit{QCC}\xspace}%quadrupole coupling constant
\newcommand{\deltaQ}{\ensuremath{\delta_\mathrm{Q}}\xspace}%quadrupole anisotropy
\newcommand{\etaQ}{\ensuremath{\eta_\mathrm{Q}}\xspace}%quadrupole asymmetry
\newcommand{\QMoment}{\ensuremath{\mathcal{Q}\xspace}}%(electrical) quadrupole moment (of a nucleus)
\newcommand{\tRhoChange}{\ensuremath{t}}%symbol for time-argument for $\derivative{\rho_\mathrm{R}(t)}{t}$. May conflict with the use of an subscript-free $\tau$ as the characteristic decay time of the orientational correlations or the time-argument of the correlation function
\newcommand{\tCorrfuncArg}{\ensuremath{\mathcal{T}}}%{\ensuremath{\tau}}%symbol for time-argument of the autocorrelation function f(t). May conflict with the use of an subscript-free $\tau$ as the characteristic decay time of the orientational correlations or the time-argument of the change in the density matrix
\newcommand{\TOne}[1][]{\ensuremath{{T_1^\textrm{#1}}}\xspace}%spin-lattice relaxation time T1
\newcommand{\TTwo}[1][]{\ensuremath{{T_2^\textrm{#1}}}\xspace}%spin-spin relaxation time T2
\newcommand{\DTwoO}{\chem{D_2O}\xspace}
%\newcommand{\HDO}{\chem{HDO}\xspace}
\newcommand{\HTwoSvntnO}{\chem{H_2}\chem{^{17}O}\xspace}
\newcommand{\HTwoSvntnOHighlight}{\chem{H_2}\chem{\textcolor{red}{^{17}O}}\xspace}
\newcommand{\EtOHDTwoChem}{\chem{CH_3C{^2H}_2OH}\xspace}
\newcommand{\EtOHDTwoChemHighlight}{\chem{CH_3C\textcolor{red}{^2H}_2OH}\xspace}
%sample abbreviations
%naming of samples with linear pNIPAM
\newcommand{\pLinSample}[2][O]{\mbox{%mbox to prevent linebreaks in sample name
\ifthenelse{\cnttest{#2}{=}{100}}%if (outer)
{\textrm{Lin-E#2\xspace}}%then (outer)
{\ifthenelse{\cnttest{#2}{=}{0}}%if (inner)
{\textrm{Lin-W\ensuremath{_\text{#1}}\SUBTRACT{100}{#2}{\wfrac}\wfrac}\xspace}%then (inner)
{\textrm{Lin-E#2W\ensuremath{_\text{#1}}\SUBTRACT{100}{#2}{\wfrac}\wfrac}\xspace}%else (inner)
}%else (outer)
}%close mbox
}%linear pNIPAM samples. Arg1=EtOH Concentration, Arg2=special suffixes (e.g. \pLinSample[0][-D$_2$O]}). Syntax: \newcommand{\commandname}[total number of arguments][default value of optional arguments, which are numbered from 1 to the total number of arguments]{code}
%naming of samples without pNIPAM
\newcommand{\BulkSample}[2][O]{\mbox{%mbox to prevent linebreaks in sample name
\ifthenelse{\cnttest{#2}{=}{100}}%if (outer)
{\textrm{F-E#2\xspace}}%then (outer)
{\ifthenelse{\cnttest{#2}{=}{0}}%if (inner)
{\textrm{F-W\ensuremath{_\text{#1}}\SUBTRACT{100}{#2}{\wfrac}\wfrac}\xspace}%then (inner)
{\textrm{F-E#2W\ensuremath{_\text{#1}}\SUBTRACT{100}{#2}{\wfrac}\wfrac}\xspace}%else (inner)
}%else (outer)
}%close mbox
}
%only one microgel sample made it into the final version of the dissertation, no need for a complex command
\newcommand{\pMGSample}{\mbox{MG-W\ensuremath{_\text{D}}100}\xspace}%mbox to prevent linebreaks in sample name
\newcommand{\BayreuthSample}[2][O]{\mbox{%mbox to prevent linebreaks in sample name
\ifthenelse{\cnttest{#2}{=}{100}}%if (outer)
{\textrm{Lin*-E#2\xspace}}%then (outer)
{\ifthenelse{\cnttest{#2}{=}{0}}%if (inner)
{\textrm{Lin*-W\ensuremath{_\text{#1}}\SUBTRACT{100}{#2}{\wfrac}\wfrac}\xspace}%then (inner)
{\textrm{Lin*-E#2W\ensuremath{_\text{#1}}\SUBTRACT{100}{#2}{\wfrac}\wfrac}\xspace}%else (inner)
}%else (outer)
}%close mbox
}
%write equations which are repeated (appendix and main part) as macro to ensure consistency
%https://tex.stackexchange.com/questions/254173/how-to-use-macros-to-repeat-math-equations-in-different-settings
%https://tex.stackexchange.com/questions/67651/repeating-an-equation-and-getting-the-same-equation-number
\newcommand{\correlationfunctiondef}[1]{#1f_{2,\RankOrderTypeface{m}}(\tCorrfuncArg) \equiv (-1)^m \overline{R_2^\RankOrderTypeface{-m}(t) R_2^\RankOrderTypeface{m}(\tRhoChange-\tCorrfuncArg)}}%optional command argument for potential alignment characters
\newcommand{\spectraldensitydefRHS}{\int_{0}^{\infty} f_{2,\RankOrderTypeface{m}}(\tCorrfuncArg) \exp(i m \omega) \diff \tCorrfuncArg}
%shorthands for special terms listed in the ignored glossary. %starred version of \gls does not create an internal link
\newcommand{\CD}{\gls*{Cole-Davidson}\xspace}
\newcommand{\fmX}[1][]{fast-motion #1\xspace}%as command in case I change my mind on hyphenation
\newcommand{\HE}{\gls*{HE}\xspace}
\newcommand{\SE}{\gls*{SE}\xspace}
\newcommand{\Tdem}{\gls*{Tdem}\xspace}
%physical constants shorthands
\newcommand{\kB}{\ensuremath{\mathrm{k}_\mathrm{B}}\xspace}% typesetting of the Boltzman constant
%\newcommand{\NA}{\ensuremath{N_\mathrm{A}}\xspace}% typesetting of the Avogadro number
%\newcommand{\Rgas}{\mathrm{R}}% typesetting of the universal gas constant
%additional units with the typesetting of \SI{}{}
\DeclareSIUnit{\wtpercent}{wt\%}
\DeclareSIUnit{\volpercent}{vol\%}
\DeclareSIUnit{\molpercent}{mol\%}
\DeclareSIUnit{\atpercent}{at\%}
\DeclareSIUnit{\barpress}{bar}%bar as a unit of pressure. keep distinct from overbar command
\DeclareSIUnit{\pH}{pH}
\DeclareSIUnit{\ppm}{ppm}%parts per million (chemical shifts)
\DeclareSIUnit{\poise}{P}
\DeclareSIUnit{\hour}{h}
\DeclareSIUnit{\day}{d}
\DeclareSIUnit{\rpm}{rpm}%rounds per minute (e.g. stirring during microgel synthesis)
%customizable row and column vectors. Taken from https://tex.stackexchange.com/questions/39051/typesetting-a-row-vector as of 2024-10-22
\ExplSyntaxOn
\NewDocumentCommand{\Rowvec}{ O{,} m }
{
\vector_main:nnnn { p } { & } { #1 } { #2 }
}
\NewDocumentCommand{\Colvec}{ O{,} m }
{
\vector_main:nnnn { p } { \\ } { #1 } { #2 }
}
\seq_new:N \l__vector_arg_seq
\cs_new_protected:Npn \vector_main:nnnn #1 #2 #3 #4
{
\seq_set_split:Nnn \l__vector_arg_seq { #3 } { #4 }
\begin{#1matrix}
\seq_use:Nnnn \l__vector_arg_seq { #2 } { #2 } { #2 }
\end{#1matrix}
}
\ExplSyntaxOff
\newcommand{\Transpose}{\ensuremath{^\mathrm{T}}\xspace}
%front- and backmatter sections
%https://tex.stackexchange.com/questions/197303/sections-in-toc-with-links-but-without-headings
%\newcommand*\silentsection[1]{%
% \addtocounter{section}{1}
% \addcontentsline{toc}{section}{\protect\numberline{\thesection}#1}
% \sectionmark{#1} % this is to get headers for the section
%}
%\newcommand*\silentchapter[1]{%
%\addtocounter{chapter}{1}
%\addcontentsline{toc}{chapter}{\protect\numberline{\thechapter}#1}
%\sectionmark{#1} % this is to get headers for the section
%}
%alternative: https://tex.stackexchange.com/questions/129978/how-to-remove-section-subsection-titles

63
Diss_ExperimentalDetails.tex Normal file
View File

@@ -0,0 +1,63 @@
%
\chapter{Table and Sample Macros}
%
Here is a table, \cref{tab:list-of-samples}, where some cells are joined with the \mbox{\textbackslash multirow} command. Also, the sample-name macros (see \cref{sec:samplename_macros}) are used.\\
%
\begin{table}
\begin{tabular}{|c|c|c|c|}
\hline
\multirow{2}*{\textbf{Shorthand(s)}} & \textbf{EtOH} & \multirow{2}*{\textbf{Labelling}} & \multirow{2}*{\textbf{Mention in Publication}} \\
& \textbf{Water} & & \\
\hline
\multirow{2}*{\pLinSample[D]{00}} & - & -, & \multirow{2}*{\autocite{Saeckel2024}} \\
& \SI{100}{\volpercent} & \chem{\textcolor{red}{^2H}_2O} & \\
\hline
\multirow{2}*{\pLinSample{00}, \BulkSample{00}} & - & -, & \multirow{2}*{\autocite{Saeckel2024} (SI), \autocite{Saeckel2025}}\\
& \SI{100}{\volpercent} & \HTwoSvntnOHighlight & \\
\hline
% \multirow{2}*{\pLinSample{05}} & \SI{95}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{-} \\
% & \SI{5}{\volpercent} & \HTwoSvntnOHighlight & \\
% \hline
\multirow{2}*{\pLinSample{10}, \BulkSample{10}} & \SI{90}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\
& \SI{10}{\volpercent} & \HTwoSvntnOHighlight & \\
\hline
\multirow{2}*{\pLinSample{20}, \BulkSample{20}} & \SI{80}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\
& \SI{20}{\volpercent} & \HTwoSvntnOHighlight & \\
\hline
\multirow{2}*{\pLinSample[D]{30}, \BulkSample[D]{30}} & \SI{30}{\volpercent} & \chem{CH_3CH_2O\textcolor{red}{\underline{\textcolor{black}{H}}}}, & \multirow{2}*{\autocite{Saeckel2025}} \\
& \SI{70}{\volpercent} & \chem{\textcolor{red}{^2H}_2O} & \\
\hline
\multirow{2}*{\pLinSample{30}, \BulkSample{30}} & \SI{30}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\
& \SI{70}{\volpercent} & \HTwoSvntnOHighlight & \\
\hline
\multirow{2}*{\pLinSample{40}, \BulkSample{40}} & \SI{40}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\
& \SI{60}{\volpercent} & \HTwoSvntnOHighlight & \\
\hline
\multirow{2}*{\pLinSample{50}, \BulkSample{50}} & \SI{50}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\
& \SI{50}{\volpercent} & \HTwoSvntnOHighlight & \\
\hline
\multirow{2}*{\pLinSample{60}, \BulkSample{60}} & \SI{60}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\
& \SI{40}{\volpercent} & \HTwoSvntnOHighlight & \\
\hline
\multirow{2}*{\pLinSample{70}, \BulkSample{70}} & \SI{70}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\
& \SI{30}{\volpercent} & \HTwoSvntnOHighlight & \\
\hline
\multirow{2}*{\pLinSample{90}, \BulkSample{90}} & \SI{90}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\
& \SI{10}{\volpercent} & \HTwoSvntnOHighlight & \\
\hline
\multirow{2}*{\pLinSample{100}, \BulkSample{100}} & \SI{100}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\
& - & - & \\
\hline
\multirow{2}*{\pMGSample} & - & -, & \multirow{2}*{-} \\
& \SI{100}{\volpercent} & \chem{\textcolor{red}{^2H}_2O} & \\
\hline
\multirow{2}*{\BayreuthSample[D]{00}} & - & -, & \multirow{2}*{\autocite{Saeckel2024}, SI} \\
& \SI{100}{\volpercent} & \chem{\textcolor{red}{^2H}_2O} & \\
\hline
\multirow{2}*{\BayreuthSample{30}} & \SI{30}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{-} \\
& \SI{100}{\volpercent} & \chem{\textcolor{red}{^2H}_2O} & \\
\hline
\end{tabular}
\caption{List of samples, introducing abbreviations and corresponding solvent concentrations and labelling. Abbreviations denote polymer type (\textbf{Lin}ear, \textbf{M}icro\textbf{G}el, polymer-\textbf{F}ree), \textbf{E}thanol and \textbf{W}ater concentrations (in \si{\volpercent}) and a subscript to indicate which isotope labelling was used for the water component. Thereby the shorthand notation also implicitly gives the labelling of ethanol (W\textsubscript{O} $\rightarrow$ ethanol-d\textsubscript{2}, W\textsubscript{D} $\rightarrow$ natural abundance ethanol). Samples prepared for experiments in the \AEON are marked with a star, e.g. \BayreuthSample[D]{00}. All polymer samples listed here contain \SI{4}{\wtpercent} polymer. Note that for neat \DTwoO, data from literature \autocite{Hindman1971} was used. Note further that hydrogen exchange leads to a distribution of $^2$H between water and ethanol in samples such as \BulkSample[D]{30}, whereby it is to be expected that $\gtrsim\SI{90}{\percent}$ of $^2$H is located in water molecules.}
\label{tab:list-of-samples}
\end{table}

154
Diss_Glossary.tex Normal file
View File

@@ -0,0 +1,154 @@
%Abbreviations
\usepackage[
acronym,%create an acronym-type glossary
toc,%table of contents
nomain,
%savewrites=true,%this option, in combination with the restoreused custom command, messes with backref pagenumbers but they would be needed to suppress single-occurrence abbreviations
%numberline,%snippet for suppressing single-occurrence abbreviations uses this option, dont see its use though.
]{glossaries-prefix}%should be loaded after relevant packages such as hyperref
%loading the glossaries-extra package would have been the better choice in hindsight. It provides professional solutions to many advanced problems I encountered and had to solve with my limited latex skills.
% for special terms that are not acronyms and should be displayed in a special way on first occurence, but not get a glossary entry. I later added the user1=off key and value to those entries - maybe I then would not have needed to sort them into a new type of glossary
\newcommand*{\glossfirstformat}[1]{\textit{#1}}%would prefer to use \emph over \textit here in case first occurrence is in italic text environment, but emph does not work for whatever reason
\newglossary[glignoredl]{ignored}{glignored}{glignoredin}{Ignored Glossary}
%formatting that applies to entries in the [type] glossary only
\defglsentryfmt[ignored]{%
\ifglsused{\glslabel}{%
\glsgenentryfmt%
}{%
% Typeset first use
\glossfirstformat{\glsgenentryfmt}%
% \glsgenentryfmt%
}%
}
\newglossary[glunignoredl]{unignored}{glunignored}{glunignoredin}{Unignored Glossary}%changed my mind on highlighting some of the terms. Want to keep them in a glossary so I dont have to change occurances in the text
\defglsentryfmt[unignored]{%
\ifglsused{\glslabel}{%
\glsgenentryfmt%
}{%
% Typeset first use
% \glossfirstformat{\glsgenentryfmt}%
\glsgenentryfmt%
}%
}
%option to change the format of glossary entries
%\renewcommand*{\glstextformat}[1]{\textbf{#1}}%https://tex.stackexchange.com/questions/38544/glossary-links-color
%\renewcommand*{\acronymfont}[1]{\textit{#1}}%https://tex.stackexchange.com/questions/313869/how-to-change-the-font-for-acronym-descriptions-using-glossaries
\makeglossaries%this may need an additional command after the first compile pass. See internet for more
%https://tex.stackexchange.com/questions/101753/specify-perl-location-for-makeglossaries
%suppress glossary style and entry for single occurrence acronyms.
%see https://tex.stackexchange.com/questions/98494/glossaries-dont-print-single-occurences
\glsenableentrycount %then use \cgls commands instead of \gls. Is troublesome with the glossary resets in abstracts and conclusion.
\let\gls\cgls
\let\Gls\cGls
\let\glspl\cglspl
\let\Glspl\cGlspl
%
%Automatic solution to reset glossary-first-use-style (without resetting occurrence counts) per custom chapter might be adaptable from https://tex.stackexchange.com/questions/646615/resetting-glossaries-abbreviations-each-chapter
%but currently requires glossary option savewrites=true, which messes with backref pagenumbers. Falling back to semi-manual \fakefirstacr custom commands
%\newcommand*{\restoreusedflag}{}%command does nothing by default, may get a function depending on conditional
%\preto\glslinkpresetkeys{%would need to adapt this line for use with glossaries-prefix, which does not provide \glslinkpresetkeys. Falling back to a semi-manual solution with a custom \fakefirstacr command which copies the style of a first-use-acronym, with the drawback that I manually need to ensure that the command is used if and only if the full acronym should be displayed. In theory this needs to be done also for acronyms mentioned exactly once after the reset at the end of the abstracts, which is never the case in the current (2025-08-07) version of the document.
%\ifnumcomp{\glsentrycurrcount{\glslabel}}{=}{0}
%{%
% \ifglsused{\glslabel}
% {\renewcommand*\restoreusedflag{\csuse{@@glsunset}{\glslabel}}}{}%if the glossary entry was used, possibly before the last glsreset, set the function of \restoreusedflag to marking the entry as used (use the \glsunset command on \glslabel), but do not yet apply \restoreusedflag
% \glsreset{\glslabel}%
%}{}%
%}
%\preto\glspostlinkhook{%
% \ifglsused{\glslabel}{}{\restoreusedflag}%if the glossary entry was not used since the last glsreset, apply \restoreusedflag which may or may not have a function
% \renewcommand*{\restoreusedflag}{}%clear any possible functionalty of the \restoreusedflag command for the next call
%}
%alternative approaches
%https://tex.stackexchange.com/questions/59449/acronym-package-dont-write-acronym-if-single-occurence https://tex.stackexchange.com/questions/651509/how-to-omit-acronyms-with-only-a-single-occurrence-in-acro
%https://tex.stackexchange.com/questions/26238/ignoring-an-acronym-that-is-only-used-once %needs two LaTeX runs to get everything right!
%acronyms
%https://tex.stackexchange.com/questions/232707/modify-appearance-of-first-acronym. see also https://mirrors.mit.edu/CTAN/macros/latex/contrib/glossaries/glossaries-user.pdf
%for linkcolors see https://tex.stackexchange.com/questions/38544/glossary-links-color and https://mirrors.mit.edu/CTAN/macros/latex/contrib/glossaries/glossaries-user.pdf p.226
\newacronymstyle{mystyleit}%custom style which yields italic long form, but roman parentheses and short form
{% use the same display as the long-short style as a basis
\GlsUseAcrEntryDispStyle{long-short}%
}%
{% use the same definitions as long-short
\GlsUseAcrStyleDefs{long-short}%
% Minor modifications:
\renewcommand*{\genacrfullformat}[1]{%
\glossfirstformat{\glsentrylong{##1}}\space\textnormal{(\glsentryshort{##1})}%
% \glsifhyperon{\textcolor{\mylinkcolor}{\textnormal{(\glsentryshort{##1})}}}{\textnormal{(\glsentryshort{##1})}}%thought I broke link colors while setting up the custom style and tried to mess with it even more to get them back. Hopefully it worked without this in the end - still have to check.
}%
\renewcommand*{\Genacrfullformat}[2]{%
\glossfirstformat{\Glsentrylong{##1}}\space\textnormal{(\glsentryshort{##1})}%
% \glsifhyperon{\textcolor{\mylinkcolor}{\textnormal{(\glsentryshort{##1})}}}{\textnormal{(\glsentryshort{##1})}}%
}%
\renewcommand*{\genplacrfullformat}[2]{%
\glossfirstformat{\glsentrylongpl{##1}}\space\textnormal{(\glsentryshortpl{##1})}%
% \glsifhyperon{\textcolor{\mylinkcolor}{\textnormal{(\glsentryshortpl{##1})}}}{\textnormal{(\glsentryshortpl{##1})}}%
}%
\renewcommand*{\Genplacrfullformat}[2]{%
\glossfirstformat{\Glsentrylongpl{##1}}\space\textnormal{(\glsentryshortpl{##1})}%
% \glsifhyperon{\textcolor{\mylinkcolor}{\textnormal{(\glsentryshortpl{##1})}}}{\textnormal{(\glsentryshortpl{##1})}}%
}%
}
\setacronymstyle{mystyleit}%breaks link colors in the current (2025-07-15) version, including color for references
\defglsentryfmt{%breaks link colors in the current (2025-07-15) version, including color for references
\ifglshaslong{\glslabel}{%
\ifglsused{\glslabel}{%
\glsgenacfmt%\glsifhyperon{\textcolor{\mylinkcolor}{\glsgenacfmt}}{\glsgenacfmt}%
}{%
\glossfirstformat{\glsgenacfmt}%
}%
}{%
\ifglsused{\glslabel}{%
\glsgenentryfmt%
}{%
\glossfirstformat{\glsgenentryfmt}%
}%
}%
}
\newcommand{\fakefirstacr}[1]{\ifglsused{#1}{\glsdisp{#1}{\genacrfullformat{#1}}}{\gls{#1}}}%manually set an acronym to be displayed as if it was its first use (keep consistent with setacronymstyle), in order to have the long forms displayed e.g. in the conclusion to give clarity to readers which only read the conclusion. Dont want to simply reset uses, such that occurrence counts are kept and thus document-wide single-uses do not have a redundant abbreviation introduced
%uppercase and plural versions:
\newcommand{\fakefirstAcr}[1]{\ifglsused{#1}{\glsdisp{#1}{\Genacrfullformat{#1}}}{\Gls{#1}}}
\newcommand{\fakefirstacrpl}[1]{\ifglsused{#1}{\glsdisp{#1}{\genplacrfullformat{#1}}}{\glspl{#1}}}
\newcommand{\fakefirstAcrpl}[1]{\ifglsused{#1}{\glsdisp{#1}{\Genplacrfullformat{#1}}}{\Glspl{#1}}}
%prefix version:
\newcommand{\fakefirstpacr}[1]{\ifglsused{#1}{\glsentryprefixfirst{#1}\glsdisp{#1}{\genacrfullformat{#1}}}{\pgls{#1}}}
%if needed in the future, define other prefix-glossary commands like pGls equivalently
%
%\glsdisablehyper%disables internal glossary links, can be used for testing
%linking only the short form is nicer, but too much effort. see https://tex.stackexchange.com/questions/127702/how-to-set-hyperfirst-to-just-one-glossary
%may not want to show abbreviations for single uses, see https://tex.stackexchange.com/questions/59449/acronym-package-dont-write-acronym-if-single-occurence in this case. Be mindful, however, of glossary resets such as for e.g. the conclusion
\newacronym{CPMG}{CPMG}{Carr-Purcell-Meiboom-Gill}
\newacronym[
prefixfirst={a\ },%prefix used on first use
prefix={an\ }%prefix used on subsequent use
]{LCST}{LCST}{lower critical solution temperature}%article-included glossary command is \pgls instead of \gls.}
\newacronym{pNIPAM}{pNIPAM}{poly(N-isopropylacrylamide)}
\newacronym[description={Poly(N-isopropylacrylamid); German for pNIPAM}]{pNIPAMgerman}{\mbox{PNIPAM}}{\foreignlanguage{ngerman}{Poly(N-isopropylacrylamid)}}%pNIPAM in German
\newacronym{TSUA}{TSUA}{test single-use acronym}
\newacronym{TMUSC}{TMUSC}{test multiple-use single in conclusion}
\newacronym{TSUC}{TMUSC}{test single-use in conclusion}
%special terms that are not acronyms. use the user1 key to mark entry for non-hyperlink
%syntax example: \newglossaryentry{variable name}{name=word), type=ignored, description={}, user1={off}}
\newglossaryentry{athermal}{name=athermal, type=ignored, description={}, user1={off}}
\newglossaryentry{complexation}{name=complexation, type=ignored, description={}, user1={off}}% as in solvent complexation
\newglossaryentry{Rh}{name=hydrodynamic radius, first=hydrodynamic radius \textnormal{(\Rh)}, prefixfirst={a\ }, prefix={an\ }, plural=hydrodynamic radii, type=unignored, description={}, user1={off}}%first set to belong to the ``ignored'' glossary for special formatting on first occurrence. Then I later changed my mind and decided that the reader is probably already familiar with the term ``hydrodynamic radius'' and therefore changed the type of glossary the entry should be assigned to to the ``unignored'' glossary
\newglossaryentry{Larmor frequency}{name={Larmor frequency}, first={Larmor frequency \textnormal{(\wL)}}, plural={Larmor frequencies}, firstplural={Larmor frequencies \textnormal{(\wL)}}, type={ignored}, description={}, user1={off}}
\newglossaryentry{spectral density}{name=spectral density, plural=spectral densities, type=ignored, description={}, user1={off}}
\newglossaryentry{Tdem}{name={demixing temperature}, type=ignored, description={}, user1={off}}
%disable links for for glossary entries that have a value 'off' to the key 'user1'
\renewcommand*{\glslinkcheckfirsthyperhook}{%
% Get the value of the user1 field
\glsletentryfield{\thisvalue}{\glslabel}{useri}%
% Test this value
\ifdefstring\thisvalue{off}%
{\setkeys{glslink}{hyper=false}}%
{}%
}

27
Diss_Hyphenation.tex Normal file
View File

@@ -0,0 +1,27 @@
%hyphenation on linebreaks fails in some cases. Not necessary my fault, see https://tex.stackexchange.com/questions/171084/why-does-usepackagebritishbabel-hyphenate-the-word-alternate-incorrectly
%fixing this by manually defining the hyphenation of words I notice in the (close to) final verison
%website to check hyphenation in british english (here for ``Figure''):
%https://www.hyphenator.net/en/word/Figure
\babelhyphenation[british]{abun-dance}
\babelhyphenation[british]{be-yond}
\babelhyphenation[british]{cen-tri-fuged}%really?
\babelhyphenation[british]{cor-re-la-tion}
\babelhyphenation[british]{de-pen-dence}
\babelhyphenation[british]{dom-i-nant}
\babelhyphenation[british]{en-gi-neer-ing}
\babelhyphenation[british]{ethanol}
\babelhyphenation[british]{foun-da-tion}
\babelhyphenation[british]{in-di-cat-ed}
\babelhyphenation[british]{in-di-ca-tions}
\babelhyphenation[british]{in-ves-ti-gat-ed}
\babelhyphenation[british]{in-ves-ti-ga-tion}
\babelhyphenation[british]{mea-sure-ment}
\babelhyphenation[british]{methanol}
\babelhyphenation[british]{mi-cro-gel}
\babelhyphenation[british]{pre-do-mi-nant-ly}
\babelhyphenation[british]{pulse-length}%in case I change my mind and return to writing pulse length as a single word
\babelhyphenation[british]{sep-a-rate-ly}
\babelhyphenation[british]{sep-a-ra-tion}
\babelhyphenation[british]{tem-per-a-ture}
%to break a line without a hyphen (e.g. for ``pNIPAM/\allowbreak water/\allowbreak ethanol mixture''), use \allowbreak. see https://tex.stackexchange.com/questions/26174/allow-line-break-but-without-inserting-a-dash

657
Diss_Introduction.tex Normal file
View File

@@ -0,0 +1,657 @@
\part{Parts Only Serve Demonstration Purposes Here}
\begingroup
%save space by avoiding a pagebreak between a new part and its first chapter
\renewcommand{\cleardoublepage}{}%only necessary if the openright option is used. Otherwise only acting on \clearpage is sufficient, but keeping \cleardoublepage does no harm.
\renewcommand{\clearpage}{}
\chapter{Spacing}
\endgroup%reinstate normal function of the clearpage commands
%
\section{Special Spacing for The First Chapter in a Given Part}\label{sec:part-nopagebreak-chapter}
%
Here is how to save space by avoiding a pagebreak between a new part and its first chapter:
\begin{lstlisting}
\begingroup
%save space by avoiding a pagebreak between a new part and its first chapter
\renewcommand{\cleardoublepage}{}%only necessary if the openright option is used in the documentclass options. Otherwise only acting on \clearpage is sufficient, but renewing also \cleardoublepage does no harm.
\renewcommand{\clearpage}{}
\chapter{Spacing}
\endgroup%reinstate normal function of the clearpage commands
\end{lstlisting}
%
\section{Margins}
%
I tried to get the current margin sizes for even and odd pages, so I can set new custom margin sizes to adjust for the binding. The macro you find below prints a short text which describes left and right margins and whether the code thinks that it is currently on an odd or even page (relevant to grant more space to the binding). You can then jump to the next page (which is then the other of odd or even) and let it give you the margin sizes there. This did not work fully for me (odd / even page recognition failed), but at least it worked for either an even or an odd page, which was good enough for me.\\
%
\begin{lstlisting}
%get margins
%https://tex.stackexchange.com/questions/537078/how-to-access-geometry-length
\usepackage{ifoddpage}% subsequent commands need the siunitx package. If you use the code from the steckexchange link, be sure not to keep the siunitx package options given there for your final version, otherwise all values of the \SI command will be given with the specified (two-decimal) precision, which sucks if you cannot make such a precise statement or only wanted to get a consistently formatted order of magnitude. Made this mistake and got over-precise polymer content (\SI{4}{\wtpercent} yielded "4.00 wt%" instead of "4 wt%") or completely wrong output (\SI{e7}{\hertz} yielded ".0010^7 Hz" instead of "10^7 Hz").
\makeatletter
% Macro for nicely printing a length in centimeters. You don't need it to *use* the lengths.
\newcommand*{\convertToCm}[1]{%
\begingroup
\edef\tmp{\strip@pt\dimexpr(#1)/7227*254\relax}%
\SI{\tmp}{\centi\meter}%
\endgroup
}
\makeatother
\newlength{\myLeftMargin}
\newlength{\myRightMargin}
\newcommand*{\myComputeMargins}{% To be called just after \checkoddpage
\setlength{\myLeftMargin}{%
\dimexpr 1in + \ifoddpage\oddsidemargin\else\evensidemargin\fi \relax}%
\setlength{\myRightMargin}{%
\dimexpr \paperwidth - \textwidth - \myLeftMargin \relax}%
}
\newcommand*{\myMarginCheck}{%this command did not differentiate between even and odd page for me, but was nonetheless useful to figure out how large the margin is
\checkoddpage\myComputeMargins
This is an \ifoddpage odd\else even\fi\ page. The left margin is thus an
\ifoddpage inner\else outer\fi\ one and its width is
\the\myLeftMargin, that is \convertToCm{\myLeftMargin}. The right margin is
\the\myRightMargin, that is \convertToCm{\myRightMargin}.\par
}
\end{lstlisting}
%
\begin{lstlisting}
Example usage:\\
\myMarginCheck
\newpage
\myMarginCheck
\end{lstlisting}
Example usage:\\
\myMarginCheck
\newpage
\myMarginCheck
%
\chapter{References with \textbackslash cref}\label{sec:cleveref}
%
\section{Simple Uses of \textbackslash cref}\label{sec:cleveref_simple}
%
I assume you are familiar with the basic \mbox{\textbackslash label} and \mbox{\textbackslash ref} functionality of \LaTeX. Let me just add that there is the \mbox{\textbackslash cref} command from the cleveref package, which automatically detects the environment (e.g. chapter, subsection, equation) it is used in. This comes in handy if you want to convert, say, a section into a chapter. If you simply always used \mbox{\textbackslash cref}, you don't need to find all instances like ``As mentioned in sec. \textbackslash ref\{test\}'' and adjust them to ``As mentioned in chap. \textbackslash ref\{test\}''.
%
\section{Highlighting References}\label{sec:highlighting_links}
%
You can highlight references as document-internal links one can click on to jump to the corresponding page of the document. Commonly, the hyperref package is used for that, whereby I found customizing the following package options useful:
\begin{lstlisting}
\usepackage{hyperref}%package options are handled with the hypersetup command
\hypersetup{
colorlinks = true, %Colours links instead of ugly boxes. hidelinks option removes boxes but then does not highlight links at all
% hidelinks, %un-comment to suppress link colors for the print version. Note that this does not have the "option=true/false" syntax.
urlcolor = blue, %Colour for external hyperlinks
linkcolor = blue, %Colour of internal links
citecolor = red, %Colour of citations
plainpages = false,%so that hyperref treats page ii and page 2 as separate pages, https://tex.stackexchange.com/questions/93889/why-does-backref-refer-to-wrong-page
pdfpagelabels,%glossary pagenumbers get offset by 1 per \part, at least when I also mess with clearpage commands. trying solution of https://tex.stackexchange.com/questions/21698/how-to-get-correct-glossary-links-with-frontmatter-pages
}
\end{lstlisting}
Highlighting links is nice for the electronic version, but does not make sense for the printed dissertation. To disable link-colours, you can conveniently use the ``hidelinks'' option. Note that hidelinks is not set to e.g. ``true'' or ``false'', you just write ``hidelinks'' and move on to the next package option.\\
%
The cleveref package should be loaded after any package without specific support for cleveref. It is safest to load it at the very end of the preamble. You may or may not want to use the [nameinlink] option to include/exclude reference types (equation, section etc.) in hyperlink. nameinlink appears to be too recent for the current installation on my office computer (as of 2024-12-17).
\begin{lstlisting}
Example usage:\\
%
Reference a section, cf. \cref{sec:cleveref_simple}. Here is a reference to two figures at once: \cref{fig:binodal-spinodal-phase-diagram,fig:energylevelszeeman-qp1}.\\
%
Here is a reference of two different things (a section and a table) at once: \cref{sec:polym_concentration_dependences,tab:list-of-samples}. And a reference to three subsequent sections \cref{sec:first_cycle,sec:ageing_days,sec:ageing_hours}.
\end{lstlisting}
Example usage:\\
%
Reference a section, cf. \cref{sec:cleveref_simple}. Here is a reference to two figures at once: \cref{fig:binodal-spinodal-phase-diagram,fig:energylevelszeeman-qp1}.\\
%
Here is a reference of two different things (a section and a table) at once: \cref{sec:cleveref,tab:list-of-samples}. And a reference to three subsequent sections \cref{sec:cleveref_simple,sec:highlighting_links,sec:cleveref_advanced}.
%
\section{Advanced Uses of \textbackslash cref}\label{sec:cleveref_advanced}
%
This part stems from a niche use case I was too stubborn to let go of: I wanted to be able to reference a set of subequations (say, equations 1a) and 1b)), whereby the (abbreviated) word for the reference type would signal a plural ``eqs.'' although only the common equation number is displayed, i.e. ``eqs. 1)''. With the default configuration, I could only manage things like ``eqs. 1a) and 1b)''. On the road I also picked up how to change the referencing labels in general, so maybe this helps you:
\begin{lstlisting}
%customize abbreviations of e.g. section and chapter references. You probably don't want to repeat this with the capitalizing version, \Crefname, as abbreviations at the beginning of a sentence apparently are considered bad style.
%crefname command structure: \crefname{type}{singular}{plural}
\crefname{equation}{eq.}{eqs.}
\crefname{section}{sec.}{secs.}
\crefname{chapter}{chap.}{chaps.}
%
%How to make a plural-reference to a set of subequations with a single label.
%Originally I tried the solution from this link: https://tex.stackexchange.com/questions/35772/referencing-subequations-with-cleveref
%unfortunately, Multi-references also require all the other cross-reference formats to be defined, so I redefined those as well. A brief explanation of the command structures:
%crefformat arguments: #1=formatted label counter, #2=start of hyperlink, #3=end of hyperlink
%crefmultiformat arguments: \crefmultiformat{type}{format for the first cross-reference in a list of multiple cross-references}{format for the second cross-reference in a list of two cross-references}{format for any middle (not first or last) cross-reference in a list of more than two cross-references}{format for the last cross-reference in a list of more than two cross-references}
\crefformat{equation}{eq.~(#2#1#3)}
\Crefformat{equation}{Eq.~(#2#1#3)}%
\crefmultiformat{equation}{eqs.~(#2#1#3)}{ and~(#2#1#3)}{, (#2#1#3)}{ and~(#2#1#3)}
\crefformat{section}{sec.~#2#1#3}%crefformat overwrites at least the singular from crefname
\Crefformat{section}{Section~#2#1#3}%explicitly define \Crefformat, instead of using the default (\MakeUppercase together with \crefformat) because abbreviations at the beginning of a sentence are bad style.
%\crefrangeformat{section}{secs.~(#3#1#4) and~(#5#2#6)}
\crefmultiformat{section}{secs.~#2#1#3}{ and~#2#1#3}{, #2#1#3}{ and~#2#1#3}
%Note that there is also \crefrangemultiformat, which I however did not need to specify
\crefformat{chapter}{chap.~#2#1#3}
\Crefformat{chapter}{Chapter~#2#1#3}
\crefmultiformat{chapter}{chaps.~#2#1#3}{ and~#2#1#3}{, #2#1#3}{ and~#2#1#3}
\crefformat{figure}{fig.~#2#1#3}%crefformat overwrites at least the singular from crefname
\Crefformat{figure}{Figure~#2#1#3}%explicitly define \Crefformat, instead of using the default (\MakeUppercase together with \crefformat) because abbreviations at the beginning of a sentence are bad style.
%\crefrangeformat{figure}{figs.~(#3#1#4) and~(#5#2#6)}
\crefmultiformat{figure}{figs.~#2#1#3}{ and~#2#1#3}{, #2#1#3}{ and~#2#1#3}
\end{lstlisting}
%
\chapter{Citations}\label{sec:citations}
%
I used biblatex and found customizing the following package options and additions useful:
\begin{lstlisting}
\usepackage[
style=alphabetic,% with this style citations in the text are based on author names. Other people may prefer the style ``numeric''
maxnames=2,%sets maximum number of names in citations for both intext (maxcitenames) as well as bibliography. If there are more authors, your settings for abbreviating lists of authors in citations, i.e. ``minnames'' kick in
maxalphanames=2,%not sure what max|minalphanames do differently from max|mincitenames, but if I use them it looks like I want it to.
minalphanames=1,
minnames=1,%if number of names in citation is larger than maxnames, cut after minnames-many names and add '+'
maxbibnames=99,%overwrite maximum number of names bevor truncations in bibliography
uniquelist=true,%allows deviations from maxnames to make lists unique
backref,%references the pages where the citation was used
%url=false,%url can be set to false to ignore the url-fields of the .bib file. I did not want to generically throw away urls here, because I want to cite e.g. the grace-website. URLs are handled below.
]{biblatex}
\usepackage{xurl}% load after biblatex. Avoids URLS of references reaching into the margin. see https://tex.stackexchange.com/questions/686510/break-line-in-bibliography-for-doi
%avoid references with (chemicals in) titles reaching into the margins by manually adding discretionary hyphens (\-) in the affected entries of the .bib file. see https://tex.stackexchange.com/questions/381542/article-title-not-linebreaking-correctly-in-bibliography
%failed to have bibliography in two columns, with the title as for a onecolumn page. Contending myself with smaller font to keep required space reasonable. Feel free to try yourself, maybe one of these links help:
%https://tex.stackexchange.com/questions/137100/two-columns-10pt-bibliography-specific-pages-only-in-a-one-column-12pt-text
\appto{\bibfont}{\small}%onecolumn, normal fontsize: 40 pages. small: 32 pages. footnotesize: 28 pages
%\appto{\bibsetup}{\raggedright\twocolumn}
%\AtEndBibliography{\onecolumn}
%https://tex.stackexchange.com/questions/20758/bibliography-in-two-columns-section-title-in-one
%\usepackage{multicol}
%\usepackage{etoolbox}
%\patchcmd{\thebibliography}{\section*{\refname}}
%{\begin{multicols}{2}[\section*{\refname}]}{}{}
%\patchcmd{\endthebibliography}{\endlist}{\endlist\end{multicols}}{}{}
\AtBeginRefsection{\GenRefcontextData{sorting=ynt}}%ensure that (also) a ynt sorted refcontext is created
\AtEveryCite{\localrefcontext[sorting=ynt]}%use the ynt refcontext for sorting within a citation. Did not trust this and sorted references manually, if there were multiple references in a single citation command
\addbibresource{/autohome/saeckech/Seafile/Sync_Seafile/Literatur_Promotion/Library/Promotion_Literatur.bib}%(path for office computer)
%do not cite fields like 'comment' in the bibliography
\AtEveryBibitem{%
\clearfield{note}%
% \clearfield{url}%handled below
\clearfield{eprint}%
\clearfield{isbn}%
\clearfield{issn}%
\clearfield{month}%
\clearfield{abstract}%
\clearfield{creationdate}%
\clearfield{pages}%
\clearfield{file}%
\clearfield{issue}%
\clearfield{number}%
\clearfield{keywords}%
\clearfield{numpages}%
\clearfield{printed}%
\clearfield{ranking}%
\clearfield{readstatus}%
\clearfield{edition}%did not enter edition for every book and want to keep output consistent. Also, output formatting for first editions ("First") is for some reason different from other editions ("2nd ed.")
}
% want to show specific URLs only. Solution stolen from: https://tex.stackexchange.com/questions/152869/show-url-only-for-one-reference, 2024-11-04
%create a new category, for which the URL will be printed in the references
\DeclareBibliographyCategory{needsurl}
\newcommand{\entryneedsurl}[1]{\addtocategory{needsurl}{#1}}
\renewbibmacro*{url+urldate}{%
\ifcategory{needsurl}
{\printfield{url}%
\iffieldundef{urlyear}
{}
{\setunit*{\addspace}%
\printurldate}}
{}}
%manually set bib-entries which should have their URL printed in the references with the new ``entryneedsurl'' command defined above. Example:
\entryneedsurl{PubChem2005NIPAM}
\end{lstlisting}
%
\begin{lstlisting}
Example usage: Basic citation \autocite{Halperin2015}, citation with a page number \autocite[2]{Halperin2015}, multiple basic citations \autocite{Fujishige1989,Halperin2015,Korde2019}, multiple citations with a page number \autocites[1]{Fujishige1989}[1]{Halperin2015}, citations with a mentioned author \textcite{Halperin2015} and multiple citations with mentioned authors each \textcite{Halperin2015,Korde2019}.\\
%
The following citation should keep its URLs in the bibliography \autocite{PubChem2005NIPAM}.
\end{lstlisting}
Example usage: Basic citation \autocite{Halperin2015}, citation with a page number \autocite[2]{Slichter1990}, multiple basic citations \autocite{Fujishige1989,Halperin2015,Korde2019}, multiple citations with a page number \autocites[1]{Fujishige1989}[1]{Halperin2015}, citations with a mentioned author \textcite{Halperin2015} and multiple citations with mentioned authors each \textcite{Halperin2015,Korde2019}.\\
%
The following citation should keep its URLs in the bibliography \autocite{PubChem2005NIPAM}.\\
%
Recall that you may need to compile the bibliography (and potentially the glossary, if you use one) separately from the ``normal'' \LaTeX\space compiling, especially if you want to update the pagenumbers (``backref option'') on which the references were cited. If you use Texstudio as editor, you can compile the bibliography via Tools$\rightarrow$Bibliography (F8 key by default).\\\\
%
%
When talking about the \CPMG pulse sequence, I wanted to make sure that both authors of both publications are explicitly named with the \mbox{\textbackslash textcite} command. The document-wide settings for how many names are to be mentioned may, however, differ. I therefore used a variable ``globalmaxnames'' for the document-wide settings (not included in the example code of \cref{sec:citations}, but you can check the actual source code), then set the number of names to 2 directly before the citations, then set the number of names back to the document default
\begin{lstlisting}
Example usage: The \CPMG sequence, originally devised by \setmaxcitenames{2}\textcite{Carr1954}\setmaxcitenames{\globalmaxnames} %setmaxcitenames to 2 (even though it is the current (2025-04-10) default) to ensure that both Carr and Purcell are mentioned by name
and later improved upon by \setmaxcitenames{2}\textcite{Meiboom1958}\setmaxcitenames{\globalmaxnames}%setmaxcitenames to 2 (even though it is the current (2025-04-10) default) to ensure that both Meiboom and Gill are mentioned by name
, repeatedly refocusses dephasing spins
\end{lstlisting}
Example usage: The \CPMG sequence, originally devised by \setmaxcitenames{2}\textcite{Carr1954}\setmaxcitenames{\globalmaxnames} %setmaxcitenames to 2 (even though it is the current (2025-04-10) default) to ensure that both Carr and Purcell are mentioned by name
and later improved upon by \setmaxcitenames{2}\textcite{Meiboom1958}\setmaxcitenames{\globalmaxnames}%setmaxcitenames to 2 (even though it is the current (2025-04-10) default) to ensure that both Meiboom and Gill are mentioned by name
, repeatedly refocusses dephasing spins.
%
\chapter{Glossary}
%
\glsresetall%
Glossaries are quite some work to get running, but I think they are worth it in the end. I hope this chapter reduces the work you need to put in until it works the ways you want it to. Feel free to simply use my glossary.tex file, but be aware that it contains some customization and editing based on my personal preferences.\\
%
Why should you use a glossary in the first place? Maybe less so for what you classically expect from a glossary (to look up the meanings of words in a list at the end of a book), but rather to make sure that acronyms and symbols are properly introduced. For instance, you want to tell the reader what \gls{pNIPAM} is the first time you mention it, but from there on by default only use the abbreviation \gls{pNIPAM}. But what if you later rearrange your sections? Sure, you can manually search for the text where you originally introduced the abbreviation and edit it, but that is annoying and there is a risk you overlook some such word at some point. If you use the glossary package, it will handle this for you. If required, you can also manually tell \LaTeX\space to use the term as if it had not been used before (example in source code: \fakefirstacr{pNIPAM}). For instance, I wanted to make sure that \fakefirstacr{CPMG} is spelled out when I explain what it is in the experimental details section, even though I might have mentioned it previously. To do so, I used a custom modification of the package-included \mbox{\textbackslash genacrfullformat} command (and similar for grammatical variations):
\begin{lstlisting}
\newcommand{\fakefirstacr}[1]{\ifglsused{#1}{\glsdisp{#1}{\genacrfullformat{#1}}}{\gls{#1}}}%manually set an acronym to be displayed as if it was its first use, in order to have the long forms displayed e.g. in the conclusion to give clarity to readers which only read the conclusion. Dont want to simply reset uses, such that occurrence counts are kept and thus document-wide single-uses do not have a redundant abbreviation introduced
\end{lstlisting}
%
For non-acronyms, there was no need to count how often they occur in total (cf \cref{sec:glossary_occurrence_counts}). To simply reset the glossary's internal tracker for ``did I use this before?'', a glossary-package-included command, \mbox{\textbackslash glsreset}, is available. With it, you can e.g. mention in you abstract which range of \glspl{Larmor frequency} you measured but then have the \glsreset{Larmor frequency}\gls{Larmor frequency} treated as a novel term when you mention it for the first time in your theory section.\\
%
Glossaries can, in principle, also handle symbols with a special symbol-glossary, but I just messed with my existing glossary instead, e.g. for the \gls{Rh}, which I can subsequently use in the text (example: \gls{Rh}) without introducing the symbol again. Note: If you do so, make sure that you use the same symbol, $\Rh$, in actual math environments, e.g. via:
\begin{lstlisting}
\newcommand{\Rh}{\ensuremath{R_\mathrm{h}}}%hydrodynamic radius
\newglossaryentry{Rh}{name=hydrodynamic radius, first=hydrodynamic radius \textnormal{(\Rh)}, prefixfirst={a\ }, prefix={an\ }, plural=hydrodynamic radii, type=unignored, description={}, user1={off}}
\end{lstlisting}
%
You can easily adjust glossary terms for grammar, i.e. plural form and/or capital first letter (for this example I suppress the function that the abbreviation should only be introduced on the first occurrence by resetting any possible prior use of the glossary term ``LCST'' via \mbox{\textbackslash glsreset\{LCST\}}):
\begin{lstlisting}
Example usage: \gls{LCST}\glsreset{LCST}, \Gls{LCST}\glsreset{LCST}, \glspl{LCST}\glsreset{LCST}, \Glspl{LCST}\glsreset{LCST}
\end{lstlisting}
Example usage: \gls{LCST}\glsreset{LCST}, \Gls{LCST}\glsreset{LCST}, \glspl{LCST}\glsreset{LCST}, \Glspl{LCST}\glsreset{LCST}.\\\\
%
%
The default plural form simply appends an ``s'' to the term, but you can set the plural form to something else when you create the glossary entry:
\begin{lstlisting}
\newglossaryentry{spectral density}{name=spectral density, plural=spectral densities, type=ignored, description={}, user1={off}}
Example usage: \glspl{spectral density}\glsreset{spectral density} instead of \gls{spectral density}s
\end{lstlisting}
Example usage: \glspl{spectral density}\glsreset{spectral density} instead of \gls{spectral density}s.\\\\
%
%
Also, the article before the term (``a'' or ``an'') may depend on whether the long or the short form follows, which can also be handled by the glossary. To have this article functionality, you need at least the ``glossaries-prefix'' package, instead of the ``glossaries'' package. I did in fact use the glossaries-prefix package, however, in hindsight, I should have used the ``glossaries-extra'' package, which provides even more useful (professional) functionalities, for which I had to sometimes create messy custom solutions. To use a glossary term with its article, use the \mbox{``\textbackslash pgls''} command or its grammatical variations like \mbox{\textbackslash Pgls}.
\begin{lstlisting}
\newacronym[
prefixfirst={a\ },%prefix used on first use
prefix={an\ }%prefix used on subsequent use
]{LCST}{LCST}{lower critical solution temperature}
Example usage: \glsreset{LCST} first use with article \pgls{LCST} and subsequent use with article \pgls{LCST} and grammatical variation \Pgls{LCST}.
\end{lstlisting}
Example usage: \glsreset{LCST} first use with article \pgls{LCST} and subsequent use with article \pgls{LCST} and grammatical variation \Pgls{LCST}.\\\\
%
%
I created a custom glossary (I called it the ``ignored'' glossary because it does not list the words it contains at the end of the thesis) to get special formatting (here: italic) for uncommon words (which are not acronyms) the first time they occur, for instance when I describe what an \gls{athermal} solvent is. When I speak of an \gls{athermal} solvent the next time, I want normal formatting. Again, you could manually change the font, e.g. to italic (or better: use \mbox{\textbackslash emph} to highlight the word by giving it \emph{italic} typeface in normal cases, \textit{and \emph{roman} typeface if the surrounding text is already italic}), but you run into the same problems as for acronyms when you rearrange your sections.\\
%
Later on, I changed my mind on which words I consider highlight-worthy, but I had already used the glossary-command structure for every occurrence of the word, so I could not simply remove the corresponding glossary entry without heaving to find and replace every occurrence in the code (annoying) -- and what if I later changed my mind again? So I created another, very similar glossary type (I called it the ``unignored'' glossary), which allows me to keep the command structure, but does not apply any special formatting.\\\\
%
%
You can also make \LaTeX\space behave as if it was using the glossary term while displaying something else. This made sense for me as I defined a glossary entry for ``\gls{complexation}''\glsreset{complexation}, but maybe first mention solvent ``\glsdisp{complexation}{complexes}'', which refers to the same idea but is beyond a simple grammar variation. With the ``\textbackslash glsdisp\{complexation\}\{complexes\}'' command, I can let \LaTeX\space know that I refer to the idea of \gls{complexation} without making separate entries for every possible related case.\\\\
%
%
Also, I wanted different formatting (italic long form, roman short form) for acronyms, so I created a custom acronym style which you can see in the glossary.tex file if you are interested.
%
\section{Special Cases Depending on Acronym Occurrence Counts}\label{sec:glossary_occurrence_counts}
%
The basic glossary functions can already handle many cases. Depending on your ambitions, however, it can get complicated: Say you have an acronym, ``\gls{TSUA}'', which you use only once in the entire document, then it neither makes sense to introduce the abbreviation nor to create a link to the list of acronyms at the end of the thesis.\\
%
You can account for such a case by using the flag \mbox{``\textbackslash glsenableentrycount''} (place before \mbox{\textbackslash begin\{document\}}), which counts the occurrences of the corresponding glossary command (may need two compile runs, which you probably do anyways, maybe even without knowing). Then use \mbox{``\textbackslash cgls'' commands instead of \mbox{``\textbackslash gls''}. If you dont feel like typing an extr}a letter in the command, or dont want to replace a bunch of \mbox{\textbackslash gls} commands you already used, you can redefine the \textbackslash gls commands to function like the \textbackslash cgls commands via \mbox{``\textbackslash let\textbackslash gls\textbackslash cgls''} and similarly for the other grammatical versions like the plural \mbox{\textbackslash glspl} command.
%
\subsection{Extra Special Cases Depending on Acronym Occurrence Counts}\label{sec:glossary_occurrence_counts_resets}
%
For even more complexity, counting occurrences gets messed up by glossary resets. I initially wanted to reset all the glossaries after the abstracts (both after the German and the English abstract each) and prior to the conclusion. This way, the acronyms would be re-introduced together with their long forms in the main part and in the conclusion, which readers may find helpful if they skip the abstract and/or only read the conclusion. But what happens when, say, an acronym occurs several times in the main part, but only once in the conclusion? If you aren't careful with the glossary reset, this will be considered as a single occurrence in the conclusion and thus not get an abbreviation or link to the list of acronyms at the end of the thesis. Catching such cases apparently can be done automatically, but seemed to be more effort than I wanted to invest for these fringe cases. Instead, I wrote code which forces a like-first-use style when applied to an acronym and manually applied it to relevant occurrences of acronyms in the conclusion when it was close to the final version.\\
%
To test it, here is more than one mention of \gls{TMUSC}, \gls{TMUSC} in the main text. See also \cref{sec:conclusion}.\\
%
In theory, similar issues arise if an acronym is mentioned exactly once in the abstract(s) and exactly once in the rest of the document (main part and conclusion combined), but I just hoped that this would never be the case.\\\\
%
%
Recall that you may need to compile the glossary (and potentially the bibliography, especially if you use the ``backref'' option) separately from the ``normal'' \LaTeX\space compiling, especially if you want to update the pagenumbers (``backref option'') on which the references were cited or when you care about occurrence counts. If you use Texstudio as editor, you can compile the glossary via Tools$\rightarrow$Glossary (F9 key by default).
%
\chapter{Macros}
%
``Macros'' may sound more complex than it needs to be. Sure, you can make it very elaborate, but you can also get a lot of value without getting too involved. You can think of macros as commands, which tell \LaTeX\space to do some specific thing you previously defined. For a very simple example, this can save you some typing for long words or annoying commands, i.e. I can define a command \mbox{``\textbackslash ctg''} which makes \LaTeX\space spell out ``coil-to-globule transition'' in the pdf wherever I type \mbox{``\textbackslash ctg''} in the code. To do so, I would create the command via:
\newcommand*{\ctg}{coil-to-globule transition}%actually need to define the command now.
\begin{lstlisting}
\newcommand*{\ctg}{coil-to-globule transition}
Example usage: From then on, \mbox{\textbackslash ctg} is available: \ctg
\end{lstlisting}
Example usage: From then on, \mbox{\textbackslash ctg} is available: \ctg.\\\\
%
%
These macros may also contain other \LaTeX\space commands, i.e. just like above I can define a command \mbox{``\textbackslash pNIPAM''} which triggers the corresponding glossary entry:
\begin{lstlisting}
\newcommand{\pNIPAM}{\gls{pNIPAM}\xspace}
\end{lstlisting}
Although with such very simple macros, I can only make use of one of the glossary grammar cases (here the basic \mbox{\textbackslash gls} for singular and non-capitalized first letter)\\
%
It is considered good practice (which I myself did rarely adhere to) to use the ``starred version'' of the \mbox{\textbackslash newcommand} command.\\
%
Be aware that \LaTeX\space usually does not print the whitespace after a command in the code. For instance, using the \mbox{\textbackslash ctg} command mentioned above, I might want to have it followed directly (without a whitespace) by the character ``s'' to make the word a plural. To do so, I would write as code
\begin{lstlisting}
\ctg s
Example usage: \ctg s
\end{lstlisting}
Example usage: \ctg s.\\
%
If I mistakenly wrote as code ``\mbox{\textbackslash ctgs}'', \LaTeX\space would try to find my definition of the command ``\mbox{\textbackslash ctgs}'' which probably does not exist or has a different function.\\
%
Alternatively, I might want to write a separate word next. To do so, I could write as code
\begin{lstlisting}
Example usage: \ctg\space is a series of words
\end{lstlisting}
Example usage: \ctg\space is a series of words.\\
%
This works but it is clunky. People are lazy and invented the xspace package which provides the \mbox{\textbackslash xspace} command, which automatically decides whether a whitespace should be printed. This way I could simply append \mbox{\textbackslash xspace} to most of my custom commands. If you want to get rid of this automatic whitespace for a given use, you can use the \mbox{\textbackslash unskip} command, i.e.
\newcommand*{\ctgnew}{coil-to-globule transition\xspace}%actually need to define the command now.
\begin{lstlisting}
\newcommand*{\ctgnew}{coil-to-globule transition\xspace}
Example usage: \ctgnew say something \ctgnew\unskip s \ctgnew \ctgnew, (mind the non-whitespace between commands and before interpunctation) \ctgnew1
\end{lstlisting}
Example usage: \ctgnew say something \ctgnew\unskip s \ctgnew \ctgnew, (mind the non-whitespace between commands and before interpunctation) \ctgnew1.\\
%
\section{Typesetting}
%
\subsection{Actual Notes on Typesetting}
%
\subsubsection{Indices}
%
Although it is not what this section is meant to be about, you can read up on the use of italic vs roman font in scientific context here: \url{https://iupac.org/wp-content/uploads/2016/01/ICTNS-On-the-use-of-italic-and-roman-fonts-for-symbols-in-scientific-text.pdf}.
%
\subsubsection{Units}
%
Most readers of this template will already know the siunitx package. Therefore I just briefly mention here that custom units can be defined and options to style the expression to your liking exist, e.g.
\begin{lstlisting}
\DeclareSIUnit{\wtpercent}{wt\%}
Example usage: \SI{1}{\wtpercent}, \si{\wtpercent}, $\leq\SI[per-mode=reciprocal-positive-first]{1}{\mole\square\meter\per\second\per\kilogram}$
\end{lstlisting}
Example usage: \SI{1}{\wtpercent}, \si{\wtpercent}, $\leq\SI[per-mode=reciprocal-positive-first]{1}{\mole\square\meter\per\second\per\kilogram}$.\\
%
It seems to be considered better practice to use the \mbox{\textbackslash qty} commands, because the command name ``SI'' is awkward if you use a non-SI unit, see \url{https://tex.stackexchange.com/questions/603217/should-i-use-qty-or-si-for-siunitx}. However, as of this writing, the \mbox{\textbackslash qty} behaves weirdly (maybe it clashes with the physics package?), so I cannot provide examples. Curiously, while \mbox{\textbackslash SIrange} does not work, \mbox{\textbackslash qtyrange} does:
\begin{lstlisting}
Example usage: \qtyrange{1}{2}{\wtpercent}
\end{lstlisting}
Example usage: \qtyrange{1}{2}{\wtpercent}.\\
%
I did not know until now that the \mbox{\textbackslash SIrange} or \mbox{\textbackslash qtyrange} commands exist and they would have come in handy for me while writing the dissertation. You can probably also customize package options of the qtyrange commands to your linking, i.e. e.g. to either use a format like \mbox{``1\,wt\% to 2\,wt\%''} or like \mbox{``1 -- 2\,wt\%''}.
%
\subsubsection{Dashes and Space Between ``e.g.''}
%
A few somewhat out-of-context remarks which I didn't yet find a better place to mention:\\
%
You may also want to be aware of the difference of a single minus - in the latex text environment vs double minus -- which looks slightly different.\\
%
Thin spaces in the German ``z.\,B.'' apparently aren't a thing in English. Depending on your language and setup, you may want to add
\begin{lstlisting}
\frenchspacing%avoid double whitespace after ``.'', usefull in abbreviations e.g. ``e.g.''
\end{lstlisting}
to your preamble.
%
\subsubsection{Odds and Ends}\label{sec:linebreak_packages}
%
\begin{lstlisting}
%avoid single empty lines (called widows and orphans) on paragraph- or pagestart and -end
\clubpenalty=10000% penalizes orphans
\widowpenalty=10000% penalizes widows
\displaywidowpenalty=10000% penalizes widows that are immediately followed by a formula \[ ... \]
\usepackage{microtype}%supposedly more visually appealing borders of the textblocks%needs scalable fonts, therefore may not work on all machines. However, it deals well with (avoiding) line breaks and respecting the margins e.g. for macros
\usepackage[parfill]{parskip}%controls indentation after linebreak and todonotes. https://tex.stackexchange.com/questions/74170/have-new-line-between-paragraphs-no-indentation
\end{lstlisting}
%
\subsubsection{Textsuperscript \textsuperscript{2}H vs Math Mode $^2$H}
%
In section titles, you probably want to use \textbackslash textsuperscript\{2\}H to type $^2$H in order to keep the section-header font. Similar for subscripts.
%
\subsection{Macros for Typesetting}
%
More towards the purpose of this template, in this section I wanted to suggest you think about the use of macros to keep your options open about typesetting and naming. Of course, this cannot reasonably be done for every word you ever type, but makes sense in some cases: For instance, if you are not yet sure which symbol to use for the \glsunset{Larmor frequency}\gls{Larmor frequency} (maybe $\omega_L$, $\omega_\mathrm{L}$ or $\omega_0$) and whether or not the possible ``L'' in the index should be italic or roman (maybe you know this one, but what about italic vs roman regarding the axis of a spin $\hat{I}_\AxisTypeface{z}$ or rank and order of a spherical harmonic $Y_l^m$?), you could use
\begin{lstlisting}
\newcommand{\wL}{\ensuremath{\omega_\mathrm{L}}}
\end{lstlisting}
and, if you or a higher power have a change of mind, you can later change what the command does to
\begin{lstlisting}
\newcommand{\wL}{\ensuremath{\omega_0}}
\end{lstlisting}
%
As another example, you could use
\begin{lstlisting}
\newcommand{\qpAsym}{\ensuremath{\eta}}
\end{lstlisting}
for the asymmetry parameter of quadrupolar coupling. If you later find that you also want to speak of viscosity or other coupling asymmetry parameters (maybe chemical shift), which conventionally go with the the same symbol, $\eta$, you can simply change what the command \mbox{\textbackslash qpAsym} does to e.g.
\begin{lstlisting}
\newcommand{\qpAsym}{\ensuremath{\eta_$\mathrm{Q}$}}
\end{lstlisting}
%
Third example: there are packages (mchem or chemformula) to write chemistry-stuff with \LaTeX. For the little chemistry we usually need to write in the physics department, a simple macro will do
\begin{lstlisting}
\newcommand*\chem[1]{\ensuremath{\mathrm{#1}}}%math mode to allow subscripts as in $H_2O$. Could also have used \textsubscript instead. Use a macro to penaltize hyphenation and easily unify (and possibly change) typesetting. Big packages like mchem or chemformula are a bit overkill for me.
%
Example usage: Here is a chemical: \chem{NaNO_3^-}
\end{lstlisting}
Example usage: Here is a chemical: \chem{NaNO_3^-}.\\
%
%
You cannot define the same command twice, i.e.
\begin{lstlisting}
\newcommand{\qpAsym}{\ensuremath{\eta}}
%possibly write a lot of text with a lot of uses of \qpAsym which you don't want to find and edit.
\newcommand{\qpAsym}{\ensuremath{\eta_$\mathrm{Q}$}}
\end{lstlisting}
would give you an error. However, you can change what a command does mid-document with the \mbox{\textbackslash renewcommand} command:
\begin{lstlisting}
Example usage:\\
\newcommand{\qpAsym}{\ensuremath{\eta}\xspace}%
This \qpAsym is \qpAsym a \qpAsym line \qpAsym of \qpAsym text \qpAsym.\\
\renewcommand{\qpAsym}{\ensuremath{\eta}\xspace}%
This \qpAsym is \qpAsym a \qpAsym line \qpAsym of \qpAsym text \qpAsym
\end{lstlisting}
Example usage:\\
\newcommand{\qpAsym}{\ensuremath{\eta}\xspace}%
This \qpAsym is \qpAsym a \qpAsym line \qpAsym of \qpAsym text \qpAsym.\\
\renewcommand{\qpAsym}{\ensuremath{\eta_\mathrm{Q}}\xspace}%
This \qpAsym is \qpAsym a \qpAsym line \qpAsym of \qpAsym text \qpAsym.\\
%
In this example it does not make much sense to change what \mbox{\textbackslash qpAsym} does in the middle of your thesis, but your use case might well be different. Admittedly, most of the time I used \mbox{\textbackslash renewcommand}, it was in order to mess with predefined functionalities of other packages. For instance, to avoid pagebreaks between the headings of a part and the first chapter in it, see \cref{sec:part-nopagebreak-chapter}.
%
\subsubsection{Row Vectors}
%
If you want to save vertical space while writing a vector, you could use a (transposed) row vector. To be honest, I don't understand the code myself (it seems to require the xparse package), but here is where I got it from and what it is:\\
\url{https://tex.stackexchange.com/questions/39051/typesetting-a-row-vector} as of 2024-10-22\\
\begin{lstlisting}
\ExplSyntaxOn
\NewDocumentCommand{\Rowvec}{ O{,} m }
{
\vector_main:nnnn { p } { & } { #1 } { #2 }
}
\NewDocumentCommand{\Colvec}{ O{,} m }
{
\vector_main:nnnn { p } { \\ } { #1 } { #2 }
}
\seq_new:N \l__vector_arg_seq
\cs_new_protected:Npn \vector_main:nnnn #1 #2 #3 #4
{
\seq_set_split:Nnn \l__vector_arg_seq { #3 } { #4 }
\begin{#1matrix}
\seq_use:Nnnn \l__vector_arg_seq { #2 } { #2 } { #2 }
\end{#1matrix}
}
\ExplSyntaxOff
%Optional transpose macro:
\newcommand{\Transpose}{\ensuremath{^\mathrm{T}}\xspace}
\end{lstlisting}
You can then use this as follows
\begin{lstlisting}
Example usage:
\begin{equation}\label{eq:b1-rotating}
\bm{B}_1(t) = B_1 \Rowvec[;]{\cos(\omega_\mathrm{rf} t + \varphi_\mathrm{rf}), -\sin(\omega_\mathrm{rf} t + \varphi_\mathrm{rf}), 0}\Transpose\eqend{.}
\end{equation}
which is even more handy for footnotes\footnote{$\bm{B}_1^\text{lin} = 2B_1 \Rowvec[;]{\cos(x),0,0}\Transpose = B_1\cdot \left[ \Rowvec[;]{\cos(x),\sin(x),0}\Transpose + \Rowvec[;]{\cos(x),-\sin(x),0}\Transpose \right]$.} %
where otherwise a lot of whitespace would be above and/or below the line with a column vector.
\end{lstlisting}
Example usage:
\begin{equation}\label{eq:b1-rotating}
\bm{B}_1(t) = B_1 \Rowvec[;]{\cos(\omega_\mathrm{rf} t + \varphi_\mathrm{rf}), -\sin(\omega_\mathrm{rf} t + \varphi_\mathrm{rf}), 0}\Transpose\eqend{.}
\end{equation}
which is even more handy for footnotes\footnote{$\bm{B}_1^\text{lin} = 2B_1 \Rowvec[;]{\cos(x),0,0}\Transpose = B_1\cdot \left[ \Rowvec[;]{\cos(x),\sin(x),0}\Transpose + \Rowvec[;]{\cos(x),-\sin(x),0}\Transpose \right]$.} %
where otherwise a lot of whitespace would be wasted above and/or below the line with a column vector.
%
\subsection{Macros with Arguments}
%
Sometimes you may want to be able to influence what a command does without creating a new command. For instance, if I want to stay consistent with how I denote mixtures (e.g. ``pNIPAM-something mixture'' vs ``pNIPAM/something mixture''), I can create a macro which still needs me to tell it what the second part of the mixture is:
\begin{lstlisting}
\newcommand{\pNIPAMbinary}[1]{\mbox{\pNIPAM/}\allowbreak#1\unskip\xspace}%pNIPAM in binary mixtures such as ``pNIPAM/water''
\end{lstlisting}
and also use the macro for any such mixture, e.g. for both \pNIPAMbinary{water} and \pNIPAMbinary{ethanol}.\\\\
%
%
In this example, the argument is mandatory, i.e. will complain if you don't specify what the second part of the mixture is. You can also create commands with optional arguments (note the second set of square brackets) like
\begin{lstlisting}
\newcommand{\TOne}[1][]{\ensuremath{{T_1^\textrm{#1}}}\xspace}%spin-lattice relaxation time T1
%need braces around T_1 macros to avoid ``double superscript error'' when writing something like \TOne^{-1}
Example usage: To then either use as \TOne without any argument or as \TOne[scaled] or \TOne[s, $^{17}$O] where needed
\end{lstlisting}
Example usage: To then either use as \TOne without any argument or as \TOne[scaled] or \TOne[s, $^{17}$O] where needed.\\\\
%
%
Yet another example in support of using macros: How much space do you allow between an equation and e.g. a comma? Say you introduce
\begin{equation}\label{eq:magnetic_moment}
\hat{\bm{\mu}} = \gamma \hat{\bm{I}}\eqend{,}
\end{equation}
which you want to follow by ``whereby $\gamma$ is the gyromagnetic ratio''. You need to place a comma somewhere. If you like, you could keep your options open by defining a macro
\begin{lstlisting}
\newcommand{\eqend}[1]{\text{\quad#1}}%argrument is intended for punctuation in math environment after an equation.
\end{lstlisting}
which currently leaves one ``quad'' of space and can be changed if you feel like it. You only have to consistently use it in the equations, e.g. the code for \cref{eq:magnetic_moment} is
\begin{lstlisting}
\begin{equation}\label{eq:magnetic_moment}
\hat{\bm{\mu}} = \gamma \hat{\bm{I}}\eqend{,}
\end{equation}
\end{lstlisting}
%
%
\paragraph{More Complicated Macro Example}\label{sec:samplename_macros} The probably most complex thing I used macros for was sample naming. For the following example, you would also need packages which handle simple calculations and allow the use of if-then-else code structure
\begin{lstlisting}
\usepackage{calculator}%For simple calculations of e.g. automatically determine water fraction part of sample name when etoh fraction is known. Package suggested here https://tex.stackexchange.com/questions/453454/calculations-on-variables-using-latex
%documentation here: https://mirrors.ibiblio.org/CTAN/macros/latex/contrib/calculator/calculator.pdf
\usepackage{xifthen}%check if either component is 100%, and if so, suppress label of absent component
%documentation here: https://mirror.funkfreundelandshut.de/latex/macros/latex/contrib/xifthen/xifthen.pdf
%naming of samples with linear pNIPAM
\newcommand{\pLinSample}[2][O]{\mbox{%mbox to prevent linebreaks in sample name
\ifthenelse{\cnttest{#2}{=}{100}}%if (outer)
{\textrm{Lin-E#2\xspace}}%then (outer)
{\ifthenelse{\cnttest{#2}{=}{0}}%if (inner)
{\textrm{Lin-W\ensuremath{_\text{#1}}\SUBTRACT{100}{#2}{\wfrac}\wfrac}\xspace}%then (inner)
{\textrm{Lin-E#2W\ensuremath{_\text{#1}}\SUBTRACT{100}{#2}{\wfrac}\wfrac}\xspace}%else (inner)
}%else (outer)
}%close mbox
}%linear pNIPAM samples. Arg1=EtOH Concentration, Arg2=deviations from ``O'' (oxygen) index for water labelling (e.g. \pLinSample[D]{0}). Syntax: \newcommand{\commandname}[total number of arguments][default value of optional arguments, which are numbered from 1 to the total number of arguments]{code}
%Example usage: \pLinSample{10}, \pLinSample{100}, \pLinSample[D]{30}, \pLinSample[D]{0}.
\end{lstlisting}
%
Example usage: \pLinSample{10}, \pLinSample{100}, \pLinSample[D]{30}, \pLinSample[D]{0}.
%
\section{Hyphenation}\label{sec:hyphenation_explanation}
%
Hyphenation on linebreaks fails in some cases and this is not necessary your fault, see \url{https://tex.stackexchange.com/questions/171084/why-does-usepackagebritishbabel-hyphenate-the-word-alternate-incorrectly}.\\
%
You can fix this by manually defining the hyphenation of words you notice being wrongly hyphenated in (the close to final version of) your thesis with commands like (assuming you use the british language babel package)
\begin{lstlisting}
\babelhyphenation[british]{be-yond}
\end{lstlisting}
To check how to hyphenate a word, I sometimes used this website: \url{https://www.hyphenator.net/en/word/beyond}.
%
\subsection{Controlling Linebreaks}
%
Usually, \LaTeX\space is good at finding good spots for linebreaks (not so good at hyphenation though, see \cref{sec:hyphenation_explanation}), but may be pressed for options if there are very few very long words without hyphenation options in one or in two subsequent lines.\\
%
You can avoid linebreaks by placing whatever you want to write inside an \mbox{\textbackslash mbox} environment. If you overdo it and a long linebreak-protected word happens to be at the end of a line, the word will reach into the margin. Also, you can designate spots where you find it okay for \LaTeX\space to insert a linebreak, even if it is normally hesitant to do so, via the \mbox{\textbackslash allowbreak} command. I.e.
\begin{lstlisting}
\newcommand{\pNIPAMternary}[2]{\mbox{\pNIPAM/}\allowbreak \mbox{#1\unskip/}\allowbreak #2\unskip\xspace}%pNIPAM in ternary mixtures such as ``pNIPAM/ethanol/water''
Example usages:\\
Latex Does Not Always Find A Good Spot To Place A Linebreak On Its Own \pNIPAMternary{water}{ethanol}\\%allows linebreaks in the long expression at certain places if necessary.
\newcommand{\pNIPAMbadTernary}[2]{\pNIPAM/#1/#2}%
Latex Does Not Always Find A Good Spot To Place A Linebreak On Its Own \pNIPAMbadTernary{wtr}{thnl}\\% reaches into the margin. Avoid hyphention-triggering characters (vowels) in the arguments for demonstration purposes
Latex Does Not Always Find A Good Spot To Place A Linebreak On On Its Own \textbackslash allowbreak\\%linebreak inside the ``command''
Latex Does Not Always Find A Good Spot To Place A Linebreak On On Its Own \mbox{\textbackslash allowbreak}\\%backslash and ``command'' are forced to stay together
\end{lstlisting}
Example usages:\\
Latex Does Not Always Find A Good Spot To Place A Linebreak On Its Own \pNIPAMternary{water}{ethanol}\\%allows linebreaks in the long expression at certain places if necessary.
\newcommand{\pNIPAMbadTernary}[2]{\pNIPAM/#1/#2}%
Latex Does Not Always Find A Good Spot To Place A Linebreak On Its Own \pNIPAMbadTernary{wtr}{thnl}\\% reaches into the margin. Avoid hyphention-triggering characters in the arguments for demonstration purposes
Latex Does Not Always Find A Good Spot To Place A Linebreak On On Its Own \textbackslash allowbreak\\%linebreak inside the ``command''
Latex Does Not Always Find A Good Spot To Place A Linebreak On On Its Own \mbox{\textbackslash allowbreak}\\%backslash and ``command'' are forced to stay together
%
\chapter{Variables}
%
\section{Booleans}
%
Booleans are a special type of variables which can either have the value ``true'' or the value ``false''. In \LaTeX, you can setup a boolean variable like this:
\begin{lstlisting}
\newif\ifshownotes%created a variable "shownotes" which I could then set to be true or false. I used this to show or hide a sections of text
\shownotesfalse% sets the value of this variable to false. change the ending from "false" to "true" to set it to true. I.e.: \shownotesfalse or \shownotestrue
%https://tex.stackexchange.com/questions/61933/best-practice-for-getting-if-not-foo-conditionals
\end{lstlisting}
You can then e.g. toggle whether to show or hide a section of text by
\begin{lstlisting}
Example usage:\\
\shownotesfalse%make sure that shownotes is false in this example
\ifshownotes%
this is a comment which is only shown if the variable ``shownotes'' has the value ``true''.\\
\fi%end of the shownotes conditional
Here is some text which is shown regardless of the shownotes variable\xspace%
\ifshownotes%
and this is another comment which is only shown if the variable ``shownotes'' has the value ``true''%
\fi%end of the shownotes conditional
.
\end{lstlisting}
Example usage:\\
\shownotesfalse%make sure that shownotes is false in this example
\ifshownotes%
this is a comment which is only shown if the variable ``shownotes'' has the value ``true''.\\
\fi%end of the shownotes conditional
Here is some text which is shown regardless of the shownotes variable\xspace%
\ifshownotes%
and this is another comment which is only shown if the variable ``shownotes'' has the value ``true''%
\fi%end of the shownotes conditional
.
\begin{lstlisting}
Example usage:\\
\shownotestrue%make sure that shownotes is true in this example
\ifshownotes%
this is a comment which is only shown if the variable ``shownotes'' has the value ``true''.\\
\fi%end of the shownotes conditional
Here is some text which is shown regardless of the shownotes variable\xspace%
\ifshownotes%
and this is another comment which is only shown if the variable ``shownotes'' has the value ``true''%
\fi%end of the shownotes conditional
.
\end{lstlisting}
Example usage:\\
\shownotestrue%make sure that shownotes is false in this example
\ifshownotes%
this is a comment which is only shown if the variable ``shownotes'' has the value ``true''.\\
\fi%end of the shownotes conditional
Here is some text which is shown regardless of the shownotes variable\xspace%
\ifshownotes%
and this is another comment which is only shown if the variable ``shownotes'' has the value ``true''%
\fi%end of the shownotes conditional
.
%
\subsection{Todonotes}
%
Using a boolean variable in this way only makes sense if it is a large section of text, or if the text needs to be adjusted in multiple places. For simple, short comments, I would recommend you use the todonotes package instead. Note that I used the parskip package in combination with todonotes, see \cref{sec:linebreak_packages}.\\
%
You can create notes in the margin or in between textlines with the commands
\begin{lstlisting}
Example usage: \todo{text displayed in the margin} and a bit more text \todo[inline]{this goes into the main text area} and yet more text.
\end{lstlisting}
Example usage: \todo{text displayed in the margin} and a bit more text \todo[inline]{this goes into the main text area} and yet more text.\\
%
You can also print a list of your todo notes with \mbox{\textbackslash listoftodos} or hide your todonotes by using the package option ``disable''.\\
%
You can also set the background colour of a todo note, which I used to mark e.g. how crucial it is that I take care of it, or which proofreader made which comments. For dark colours, you will want to adjust the colour saturation so you can still read (black) text:
\begin{lstlisting}
Example usage: \todo[inline, color=blue!20]{This background is blue with only 20 percent saturation.}
\end{lstlisting}
Example usage: \todo[inline, color=blue!20]{This background is blue with only 20 percent saturation.}
%
\section{Other Types of Variables}
%
Other variables can take continuous values rather than true/false. For example, you can define a variable for the horizontal space your figures should occupy.
\begin{lstlisting}
\def\defaultfigurewidth{0.95\linewidth}%used as the default value for how much of the linewidth a figure with a single panel should occupy
\def\defaulttwosubfigwidth{0.49\linewidth}%used as the default value for how much of the linewidth a subfigure of a figure with two panels should occupy
\end{lstlisting}

211
Diss_OrdinaryPackages.tex Normal file
View File

@@ -0,0 +1,211 @@
%Main language styles and foreign characters
\usepackage[T1]{fontenc}
\usepackage[utf8]{inputenc}
\usepackage[ngerman,british]{babel}%default language of the document is the last language in the options. Can change this for a single section (e.g. abstract) with \begin{otherlanguage}{ngerman}
\frenchspacing%avoid double whitespace after ``.'', usefull in abbreviations e.g. ``e.g.''
\usepackage[english=british]{csquotes}
%Layout
%control pagebeaks around \part and \chapter
%https://tex.stackexchange.com/questions/419404/scrbook-part-and-chapter-on-same-page
\RedeclareSectionCommand[
beforeskip=\dimexpr-3.3\baselineskip-\parskip\relax,
afterskip=\dimexpr3.3\baselineskip+\parskip\relax,
style=chapter% no part page
]{part}
\renewcommand\partformat{\partname\ \thepart\autodot\enskip}
%\DeclareNewSectionCommand[
%beforeskip=-1sp,
%afterskip=1.725\baselineskip plus .115\baselineskip minus .192\baselineskip,
%style=section,% no page break before \firstchapterinpart
%level=\chapternumdepth,
%indent=0pt,
%tocindent=0pt,
%tocnumwidth=1.5em,
%font=\usekomafont{chapter},
%tocstyle=chapter
%]{firstchapterinpart}
%\makeatletter
%\let\c@firstchapterinpart\c@chapter% use the same counter for both chapter and firstchapterinpart
%\def\cl@firstchapterinpart{\cl@chapter}% use the same reset list as chapter
%\makeatother
%having trouble with the texstudio structure view for \firstchapterinpart. Output, including TOC, is okay, but hyperlinks (\cref) also fail, so it is not simply just an inconvenience. May be related to: https://github.com/texstudio-org/texstudio/issues/3086. Found a workaround by combining normal \chapter commands with relaxing of pagebreaks for the first chapter in a part, see https://tex.stackexchange.com/questions/131460/remove-pagebreak-after-a-chapter-only-for-one-chapter
%
%%(too) heavy-hitting customization of section formatting
%%https://tex.stackexchange.com/questions/42526/how-to-remove-page-break-after-part-in-report-book
%%in combination with
%%https://ctan.math.washington.edu/tex-archive/macros/latex/contrib/standardsectioning/standardsectioning.pdf
\usepackage{layout}%print layout dimensions (see example). Nice to know when creating figures
\usepackage{layouts}%use preferred units when printing layout dimensions. Example: %\printinunitsof{mm}\prntlen{\textwidth}. Use after begin{document}
\usepackage[showframe=false, outer=2.78cm, inner=3.52cm]{geometry}%draw lines around the important areas of each page. Good to check for overfull horizontal boxes.
%get margins
%https://tex.stackexchange.com/questions/537078/how-to-access-geometry-length
\usepackage{ifoddpage}% subsequent commands need the siunitx package. If you use the code from the steckexchange link, be sure not to keep the siunitx package options given there for your final version, otherwise all values of the \SI command will be given with the specified (two-decimal) precision, which sucks if you cannot make such a precise statement or only wanted to get a consistently formatted order of magnitude. Made this mistake and got over-precise polymer content (\SI{4}{\wtpercent} yielded "4.00 wt%" instead of "4 wt%") or completely wrong output (\SI{e7}{\hertz} yielded ".0010^7 Hz" instead of "10^7 Hz").
\makeatletter
% Macro for nicely printing a length in centimeters. You don't need it to *use* the lengths.
\newcommand*{\convertToCm}[1]{%
\begingroup
\edef\tmp{\strip@pt\dimexpr(#1)/7227*254\relax}%
\SI{\tmp}{\centi\meter}%
\endgroup
}
\makeatother
\newlength{\myLeftMargin}
\newlength{\myRightMargin}
\newcommand*{\myComputeMargins}{% To be called just after \checkoddpage
\setlength{\myLeftMargin}{%
\dimexpr 1in + \ifoddpage\oddsidemargin\else\evensidemargin\fi \relax}%
\setlength{\myRightMargin}{%
\dimexpr \paperwidth - \textwidth - \myLeftMargin \relax}%
}
\newcommand*{\myMarginCheck}{%this command did not differentiate between even and odd page for me, but was nonetheless useful to figure out how large the margin is
\checkoddpage\myComputeMargins
This is an \ifoddpage odd\else even\fi\ page. The left margin is thus an
\ifoddpage inner\else outer\fi\ one and its width is
\the\myLeftMargin, that is \convertToCm{\myLeftMargin}. The right margin is
\the\myRightMargin, that is \convertToCm{\myRightMargin}.\par
}
\usepackage[grid=false,gridBG=true]{eso-pic}%draw a grid to precisely place elements. I think I didn't use it in the end
%avoid single empty lines (called widows and orphans) on paragraph- or pagestart and -end
\clubpenalty=10000% penalizes orphans
\widowpenalty=10000% penalizes widows
\displaywidowpenalty=10000% penalizes widows that are immediately followed by a formula \[ ... \]
\usepackage{microtype}%supposedly more visually appealing borders of the textblocks%needs scalable fonts, therefore may not work on all machines. However, it deals well with (avoiding) line breaks and keeping the margins e.g. for macros like \EtOHDTwoChemHighlight
\usepackage[parfill]{parskip}%controls indentation after linebreak and todonotes. https://tex.stackexchange.com/questions/74170/have-new-line-between-paragraphs-no-indentation
%Figures and Images
\usepackage{chngpage}%wide images
%if you want to mess with defaults:
%\hfuzz=100pt % suppress warnings
%\begin{adjustwidth}{-\evensidemargin-0.8in}{-\rightmargin}%or \oddsidemargin and \leftmargin
% \includegraphics[width=0.92\paperwidth]{path}
%\end{adjustwidth}
%\hfuzz=0pt
\usepackage{floatpag}%full page images. Package provides commad \thisfloatpagestyle to remove header and footer. Use this command after \begin{figure}.
\usepackage{placeins}%provides command \FloatBarrier. Prevents floats from moving past the command and can therefore force latex to place (multiple) figures where you want them
\usepackage{wrapfig}%figure surrounded by text. Ended up not using it.
\usepackage{graphicx}%showframe option can be usedto visualize e.g. spacing between images in a \subfloat. The showframe option should be removed in the final version. Moreover, includegraphics options 'trim=left bottom right top' and 'clip' can be used to crop an image (see https://texblog.org/2012/02/23/crop-figures-with-includegraphics/), e.g. \includegraphics[trim=1200 400 1500 1500,clip,width=\textwidth]{crab}. see also: https://tex.stackexchange.com/questions/57418/crop-an-inserted-image. trim option can be complemented by the adjustbox package to access relative units of the image such as "\width". In this case, replace \includegraphics by \adjincludegraphics.
\usepackage{caption}
\DeclareCaptionStyle{wrapfigcapstyle}{format=plain, indention=0pt}
\usepackage{subcaption}%\usepackage[caption=false]{subfig}%provides \subfloat. use for composite figures
%get subreferences with braces. Subreference means e.g. the "a)" in Figure "1.1 a)" where Figure 1.1 also has a panel "b)". Useful to refer to the subplots in the caption of the entire figure.
\DeclareCaptionSubType[alph]{figure}%see https://tex.stackexchange.com/questions/125849/change-ref-format-for-subfigures
\captionsetup[subfigure]{labelformat=simple,justification=centerlast}%strip original brace from subfigure two avoid having two after
\renewcommand\thesubfigure{\alph{subfigure})}%braces after referencing subfigure
\makeatletter
\renewcommand\p@subfigure{\thefigure\,}%protected space(~) or protected half space (\,) between figure number and subfigure "number"
\makeatother
\usepackage[export]{adjustbox}%useful to trim images, similar to \includegraphics trim, but with acces to image-relative units such as "\width". Note that braces around relative trim units are required while braces around the set of all four trim units are optional, e.g. {{0.1\width} {0.2\height} 0 0}.% Also useful to vertically arrange (sub)figures with different heights. Example:
%\begin{figure}
% \centering
% \subfloat[Bla 1.]
% {%
% \includegraphics[width=0.45\textwidth,valign=m]{subfigure1}%
% \vphantom{\includegraphics[width=0.45\textwidth,valign=m]{subfigure2}}%
% }
% \hfill
% \subfloat[Bla 2.]
% {\includegraphics[width=0.45\textwidth,valign=m]{subfigure2}}
% \caption{Bla.}
%\end{figure}%
%Tables (see also https://people.inf.ethz.ch/markusp/teaching/guides/guide-tables.pdf)
\usepackage{longtable}%for tables which are longer than one page
\usepackage{booktabs}%rules in tables
\usepackage{multirow}
%Example with repeating header (per page) in longtable
%\begin{longtable}{p{2cm}p{11.8cm}}
% \toprule % you need the package 'booktabs' for this
% A & B\\
% \midrule
% \endhead
% 1 & 2\\
% 1 & 2\\
% 1 & 2\\
% 1 & 2\\
% \bottomrule
%\end{longtable}
%symbols
\usepackage{amsmath}
\usepackage{xparse}%required for the rowvector command defined in the convenience commands .tex file
\usepackage{amssymb}%for e.g. \lesssim
\usepackage{bm}%supplies the \bm command, recommended for bold math symbols. \boldsymbol{} from amsmath is considered obsolete
\usepackage{siunitx}%handles recommended typesetting of values and units. I think there exist package options which could be used to keep value and unit formatting consistent throughout the document, i.e. either always "10" or "1e1" for values or "ms^{-1}" or "m/s" for units. I only used the package in its default configuration though.
%\usepackage[version=4]{mhchem}%for chemistry typesetting, e.g. \ce{SO4^2-} or \ce{^{32}_{16}S+}. More examples can be found at https://www.namsu.de/Extra/pakete/Mhchem.html %package wants you to specify a version as the output for the same input may change in future versions %Ended up not using this package (overkill for me) and instead defined the macro ``\newcommand*\chem[1]{\ensuremath{\mathrm{#1}}}'' in the Diss_ConvenienceCommands .tex file.
\usepackage{physics}%provides symbols commonly used in physics-related work
\newcommand*\diff{\mathop{}\!\mathrm{d}} % differential-d in math-mode with different typeface than the rest
\usepackage{xspace}% correct(?) spacing after macros
\usepackage{bbold} % used for unit matrix symbol
\usepackage{mathrsfs} % more font options if you run out of symbols. I was especially short on "t"s for various waiting times, correlation times, relaxation times, pulse lenghts, temperature etc.
\usepackage{stackrel} % additional options to \stackrel command, such as \stackrel[...]{}{} to place ... underneath something
%add notes to work in progress
\usepackage{todonotes}%can print a list of todonotes with \listoftodos. can disable todonotes by package option [disable].
%sketches. Not sure if I used these packages in the end.
\usepackage{tikz}
\usepackage{chemfig}
\usepackage{calculator}%For simple calculations of e.g. automatically determine water fraction part of sample name when etoh fraction is known, see convenience commands .tex file. Package suggested here https://tex.stackexchange.com/questions/453454/calculations-on-variables-using-latex
%documentation here: https://mirrors.ibiblio.org/CTAN/macros/latex/contrib/calculator/calculator.pdf
\usepackage{xifthen}%check if either component is 100%, and if so, suppress label of absent component
%documentation here: https://mirror.funkfreundelandshut.de/latex/macros/latex/contrib/xifthen/xifthen.pdf
%internal links
\usepackage{fnpct}%nicely distinguish multiple successive footnotes, i.e. to not confuse footnotes 1 and 2 with footnote 12 (https://tex.stackexchange.com/questions/28465/multiple-footnotes-at-one-point)
%\numberwithin{equation}{chapter}%https://tex.stackexchange.com/questions/65926/hyperlinking-problems-when-using-subequations-hyperref-and-cleveref
\usepackage{hyperref}
\hypersetup{
colorlinks = true, %Colours links instead of ugly boxes. hidelinks option removes boxes but then does not highlight links at all
% hidelinks, %un-comment to suppress link colors for the print version. Note that this does not have the "option=true/false" syntax.
urlcolor = blue, %Colour for external hyperlinks
linkcolor = blue,%\mylinkcolor, %Colour of internal links
citecolor = red, %Colour of citations
plainpages = false,%so that hyperref treats page ii and page 2 as separate pages, https://tex.stackexchange.com/questions/93889/why-does-backref-refer-to-wrong-page
pdfpagelabels,%glossary pagenumbers get offset by 1 per \part, at least when I also mess with clearpage commands. trying solution of https://tex.stackexchange.com/questions/21698/how-to-get-correct-glossary-links-with-frontmatter-pages
}
%cleveref should be loaded after any package without specific support for cleveref. Safest to load it at the very end of the preamble
\usepackage{cleveref}%myou ay want to use the [nameinlink] option to include/exclude reference types (equation, section etc.) in hyperlink. nameinlink appears to be too recent for the current (2024-12-17) installation on my office computer
%customize abbreviations of e.g. section and chapter references. Do not repeat with \Crefname as abbreviations at the beginning of a sentence apparently count as bad style.
\crefname{equation}{eq.}{eqs.}%crefname command: \crefname{type}{singular}{plural}
\crefname{section}{sec.}{secs.}
\crefname{chapter}{chap.}{chaps.}
%to make a plural-reference to a set of subequations with a single label. Originally tried the solution from this link: https://tex.stackexchange.com/questions/35772/referencing-subequations-with-cleveref
\crefformat{equation}{eq.~(#2#1#3)}% crefformat arguments: #1=formatted label counter, #2=start of hyperlink, #3=end of hyperlink
\Crefformat{equation}{Eq.~(#2#1#3)}%
\crefmultiformat{equation}{eqs.~(#2#1#3)}{ and~(#2#1#3)}{, (#2#1#3)}{ and~(#2#1#3)}
\crefformat{section}{sec.~#2#1#3}%crefformat overwrites at least the singular from crefname
\Crefformat{section}{Section~#2#1#3}%explicitly define \Crefformat, instead of using the default (\MakeUppercase together with \crefformat) because abbreviations at the beginning of a sentence are bad style.
%\crefrangeformat{section}{secs.~(#3#1#4) and~(#5#2#6)}
\crefmultiformat{section}{secs.~#2#1#3}{ and~#2#1#3}{, #2#1#3}{ and~#2#1#3}
%Note that there is also \crefrangemultiformat, which I however did not need to specify
\crefformat{chapter}{chap.~#2#1#3}
\Crefformat{chapter}{Chapter~#2#1#3}
\crefmultiformat{chapter}{chaps.~#2#1#3}{ and~#2#1#3}{, #2#1#3}{ and~#2#1#3}
\crefformat{figure}{fig.~#2#1#3}%crefformat overwrites at least the singular from crefname
\Crefformat{figure}{Figure~#2#1#3}%explicitly define \Crefformat, instead of using the default (\MakeUppercase together with \crefformat) because abbreviations at the beginning of a sentence are bad style.
%\crefrangeformat{figure}{figs.~(#3#1#4) and~(#5#2#6)}
\crefmultiformat{figure}{figs.~#2#1#3}{ and~#2#1#3}{, #2#1#3}{ and~#2#1#3}
%added specifically for the latex template
\usepackage{listings}%used to display larger sections of code
\lstset{%
basicstyle=\ttfamily\small,
commentstyle=\itshape\ttfamily\small,
showspaces=false,
showstringspaces=false,
breaklines=true,
breakautoindent=true,
frame=single
captionpos=t
language=TeX
}

263
Diss_Theory.tex Normal file
View File

@@ -0,0 +1,263 @@
%\part{Theoretical Background}\label{sec:theory}
%\begingroup
%\renewcommand{\cleardoublepage}{}%only necessary if the openright option is used. Otherwise only acting on \clearpage is sufficient, but keeping \cleardoublepage does no harm.
%\renewcommand{\clearpage}{}
%\chapter{}\label{sec:}
%\endgroup
%
\chapter{Referencing Equations}\label{sec:referencing_equations}
%
You can use a subequations environment to label equations of e.g. an ``align'' environment as 1a, 1b, 1c etc. Each line can have a label, in case you want to refer to ``eq. (1a)''. To refer to ``eq. (1)'', the label needs to be placed after the start of subequations (before the align environment). For short text passages in between subequations, use \mbox{\textbackslash intertext}.
\begin{lstlisting}
Example usage of subequation referencing. Example code is also intended for the parent-equation referencing which is described next:
\begin{subequations}\label{eqs:hamiltonian_QP_EFG}
\begin{align}
&\HamOpQP = \frac{e\QMoment}{I(2I-1)} \frac{1}{4} \left[3\hat{I}_\AxisTypeface{z}^2 - I(I+1)\right] V_\AxisTypeface{zz}\label{eq:hamiltonian_qp}
\intertext{with}
&V_\AxisTypeface{zz} = \frac{eq}{2}\left[3\cos[2](\theta) - 1 + \etaQ \sin[2](\theta) \cos(2\phi)\right]\label{eq:efg_lab} \eqend{.}
\end{align}
\end{subequations}
Refer to a subequation by \cref{eq:hamiltonian_qp}, or to a number of specific subequations by \cref{eq:hamiltonian_qp,eq:efg_lab} without a whitespace after the comma separator of the labels
\end{lstlisting}
Example usage of subequation referencing. Example code is also intended for the parent-equation referencing which is described next:
\begin{subequations}\label{eqs:hamiltonian_QP_EFG}
\begin{align}
&\HamOpQP = \frac{e\QMoment}{I(2I-1)} \frac{1}{4} \left[3\hat{I}_\AxisTypeface{z}^2 - I(I+1)\right] V_\AxisTypeface{zz}\label{eq:hamiltonian_qp}
\intertext{with}
&V_\AxisTypeface{zz} = \frac{eq}{2}\left[3\cos[2](\theta) - 1 + \etaQ \sin[2](\theta) \cos(2\phi)\right]\label{eq:efg_lab} \eqend{.}
\end{align}
\end{subequations}
Refer to a subequation by \cref{eq:hamiltonian_qp}, or to a number of specific subequations by \cref{eq:hamiltonian_qp,eq:efg_lab} without a whitespace after the comma separator of the labels.\\\\
%
%
You can suppress a (sub)equation number with the \mbox{``\textbackslash nonumber''} tag, i.e.
\begin{lstlisting}
Example usage:
\begin{align}
\overline{\expval{\hat{O}}} &= \overline{\bra{\psi}\hat{O}\ket{\psi}}\nonumber\\
&=\sum_{\psi}p_\psi\sum_{m,n}{c_{\psi,m}}^*c_{\psi,n}\bra{\psi_{I,m}}\hat{O}\ket{\psi_{I,n}}\eqend{,}
\end{align}
\end{lstlisting}
Example usage:
\begin{align}\label{eq:nonumber_example}
\overline{\expval{\hat{O}}} &= \overline{\bra{\psi}\hat{O}\ket{\psi}}\nonumber\\
&=\sum_{\psi}p_\psi\sum_{m,n}{c_{\psi,m}}^*c_{\psi,n}\bra{\psi_{I,m}}\hat{O}\ket{\psi_{I,n}}\eqend{,}
\end{align}
%
I also set up the cleveref package (cf \cref{sec:cleveref_advanced}) such that I can use a custom command to refer to such a set as \eqpl{eqs:hamiltonian_QP_EFG}, i.e. with a plural ``s'' in the reference type (``eqs'') even though there is only one label in the reference command. I recommend to label sets of equations differently, i.e. \mbox{\textbackslash label\{eqs:hamiltonian\_QP\_EFG\}} rather than \mbox{\textbackslash label\{eq:hamiltonian\_QP\_EFG\}} (note ``eqs:\dots'' vs ``eq:\dots''), such that it will be apparent to you from the autocomplete suggestions that there are subequations. You can of course also use this label in a standard reference command \mbox{\textbackslash cref\{eqs:hamiltonian\_QP\_EFG\}}: \cref{eqs:hamiltonian_QP_EFG}.
%
\section{Repeating an Equation while Referring to the Original}
%
If you want to refresh the reader's memory of an equation which appeared a while ago or only use the result of something which is derived in detail in the appendix, you should not use a formally new equation. I think it is better to signal in the equation number that the original equation appears in a different context, which can be done with the \mbox{\textbackslash tag} command:
\begin{lstlisting}
Example usage:
\begin{equation*}\label{dummytag}
\correlationfunctiondef{} \eqend{.} \tag{\cref{eq:autocorrelation} (repeated)}
\end{equation*}
Here is a reference to the appendix \cref{sec:appdx_relaxation-specdens-sto} and an equation that is repeated from there
\end{lstlisting}
Example usage:
\begin{equation*}\label{dummytag}
\correlationfunctiondef{} \eqend{.} \tag{\cref{eq:autocorrelation} (repeated)}
\end{equation*}
Here is a reference to an equation which is derived in the appendix: \cref{eqs:autocorrelation-specdens}.
%
\section{Equations with Cases}
%
\begin{lstlisting}
Example usage:
\begin{subequations}\label{eq:cases}\label{eqs:qcc_anisotropy}
\begin{align}
&\QCC \equiv \frac{eqe\QMoment}{h} \label{eq:qcc}
\intertext{and}
&\QCC \equiv \deltaQ \frac{4I(2I-1)}{3(2k-1)} \eqend{where }k=
\begin{cases}
1&\text{for $^2$H}\\%more general, m=1 for integer spin. Not sure about fully general validity though
3/2&\text{for $^{17}$O}%more general, m=3/2 for half-integer spin. Not sure about fully general validity though
\end{cases}\label{eq:anisotropy}\eqend{.}
\end{align}
\end{subequations}
\end{lstlisting}
Example usage:
\begin{subequations}\label{eq:cases}\label{eqs:qcc_anisotropy}
\begin{align}
&\QCC \equiv \frac{eqe\QMoment}{h} \label{eq:qcc}
\intertext{and}
&\QCC \equiv \deltaQ \frac{4I(2I-1)}{3(2k-1)} \eqend{where }k=
\begin{cases}
1&\text{for $^2$H}\\%more general, m=1 for integer spin. Not sure about fully general validity though
3/2&\text{for $^{17}$O}%more general, m=3/2 for half-integer spin. Not sure about fully general validity though
\end{cases}\label{eq:anisotropy}\eqend{.}
\end{align}
\end{subequations}
%
\section{Multiline Equation}
%
For long mathematical expressions you will need to have a linebreak somewhere. With the multiline environment, you can place the linebreak of an equation like \cref{eq:diff_two-step-decay} where it does not disrupt the mathematics too much, or maybe even helps compare expressions:
%
\begin{lstlisting}
Example usage:
\begin{multline}\label{eq:diff_two-step-decay}
S(t_\mathrm{m}) = \left[ A_\mathrm{w} \exp(- \left(\gamma_\mathrm{^1H} G t_\mathrm{e}\right)^2 D_\mathrm{w} \left(\frac{2}{3}t_\mathrm{e} + t_\mathrm{m}\right)) +\right. \\%need to close/open \left\right pair on linebreak. use vphantom{highest expression} to match sizes
\left. A_\mathrm{p} \exp(- \left(\gamma_\mathrm{^1H} G t_\mathrm{e}\right)^2 D_\mathrm{p} \left(\frac{2}{3}t_\mathrm{e} + t_\mathrm{m}\right)) \vphantom{\exp(\frac{2}{3})} \right]
* \exp(-\left(\frac{2t_\mathrm{e} + t_\mathrm{m}}{\TOne}\right)^\beta) \eqend{.}
\end{multline}
\end{lstlisting}
Example usage:
\begin{multline}\label{eq:diff_two-step-decay}
S(t_\mathrm{m}) = \left[ A_\mathrm{w} \exp(- \left(\gamma_\mathrm{^1H} G t_\mathrm{e}\right)^2 D_\mathrm{w} \left(\frac{2}{3}t_\mathrm{e} + t_\mathrm{m}\right)) +\right. \\%need to close/open \left\right pair on linebreak. use vphantom{highest expression} to match sizes
\left. A_\mathrm{p} \exp(- \left(\gamma_\mathrm{^1H} G t_\mathrm{e}\right)^2 D_\mathrm{p} \left(\frac{2}{3}t_\mathrm{e} + t_\mathrm{m}\right)) \vphantom{\exp(\frac{2}{3})} \right]
* \exp(-\left(\frac{2t_\mathrm{e} + t_\mathrm{m}}{\TOne}\right)^\beta) \eqend{.}
\end{multline}
%
I suppose using multiline for this is cleaner than suppressing the equation number as in \cref{eq:nonumber_example}.
%
\chapter{Figures}
%
\section{Placement}
%
Have a simple figure, \cref{fig:energylevelszeeman-qp1}.\\
\begin{figure}
\centering
\includegraphics[width=\defaultfigurewidth]{Figures/EnergyLevels_Zeeman-QP1}
\caption{Sketch of the shift in terms of angular frequency of initially degenerate energy levels of a spin $I=1$ nucleus due to Zeeman and quadrupolar interaction (first order, not to scale).}%vaguely based on \autocite[586]{Webb2006}
\label{fig:energylevelszeeman-qp1}
\end{figure}%
%
To avoid wasting (horizontal) space with small figures, you can find two small figures and place them side by side. Alignment is easier if you surround the figures with a minipage, cf \cref{fig:binodal-spinodal-phase-diagram}.
%https://tex.stackexchange.com/questions/37581/latex-figures-side-by-side
\begin{lstlisting}
Example usage: \cref{fig:binodal-spinodal-phase-diagram}
\begin{figure}
\centering
\begin{minipage}[t]{0.4\textwidth}
\centering
\includegraphics[width=\linewidth]{Figures/FloryHugginsLattice_GeddeEtAl_Springer2019}
\captionof{figure}{Distribution of a polymer and a low molecular mass solvent on a (2-dimensional) lattice as per the Flory-Huggins theory. Figure reproduced from \autocite{Gedde2019}.}
\label{fig:floryhugginslattice}
\end{minipage}\hfill%
\begin{minipage}[t]{0.55\textwidth}
\centering
\includegraphics[width=\linewidth]{Figures/PhaseDiagram_LCST_Rubinstein_OxfordUnivPress2004}
\captionof{figure}{Top: (Scaled) change in free energy due to mixing for a symmetric mixture. The minima are marked as $\phi^\prime$ and $\phi^{\prime\prime}$ and the inflection points as $\phi_\mathrm{sp1}$ and $\phi_\mathrm{sp2}$. Bottom: Phase diagram of the mixture. The thick dashed and solid lines represent the spinodal and binodal, respectively. From the top panel, values of the binodal (minima) and spinodal (inflection points) at a given value of $N\chi$ can be derived. Figure reproduced from \autocite{Rubinstein2004}.}
\label{fig:binodal-spinodal-phase-diagram}
\end{minipage}
\end{figure}
\end{lstlisting}
Example usage: \cref{fig:binodal-spinodal-phase-diagram}.\\
\begin{figure}
\centering
\begin{minipage}[t]{0.4\textwidth}
\centering
\includegraphics[width=\linewidth]{Figures/FloryHugginsLattice_GeddeEtAl_Springer2019}
\captionof{figure}{Distribution of a polymer and a low molecular mass solvent on a (2-dimensional) lattice as per the Flory-Huggins theory. Figure reproduced from \autocite{Gedde2019}.}
\label{fig:floryhugginslattice}
\end{minipage}\hfill%
\begin{minipage}[t]{0.55\textwidth}
\centering
\includegraphics[width=\linewidth]{Figures/PhaseDiagram_LCST_Rubinstein_OxfordUnivPress2004}
\captionof{figure}{Top: (Scaled) change in free energy due to mixing for a symmetric mixture. The minima are marked as $\phi^\prime$ and $\phi^{\prime\prime}$ and the inflection points as $\phi_\mathrm{sp1}$ and $\phi_\mathrm{sp2}$. Bottom: Phase diagram of the mixture. The thick dashed and solid lines represent the spinodal and binodal, respectively. From the top panel, values of the binodal (minima) and spinodal (inflection points) at a given value of $N\chi$ can be derived. Figure reproduced from \autocite{Rubinstein2004}.}
\label{fig:binodal-spinodal-phase-diagram}
\end{minipage}
\end{figure}%
%
To give you another idea: mosaic plots offer some more advanced placement options for, e.g. a large panel on the left and two smaller panels on the right with the (combined) same height. I, however, ended up creating such a plot with python and -- as far as \LaTeX\space is concerned -- include it as a single image.\\
%
Alternatively, wrapping text around a figure could be desired. If so, see commented lines in the source code.\\
%wrapfig replaced by minipage with both (separate) figures of this section side by side
%\begin{wrapfigure}{O}{0.3\textwidth}%capitalized position O (outside edge of a twopage document) will allow some floating of the wrapfigure. Other Options are r, l, i or the capitalized versions thereof.
% \captionsetup{style=wrapfigcapstyle, width=\wrapfigscaling}
% \centering
% \includegraphics[width=\wrapfigscaling]{Figures/FloryHugginsLattice_GeddeEtAl_Springer2019}%
% \caption{Distribution of a polymer and a low molecular mass solvent on a (2-dimensional) lattice as per the Flory-Huggins theory. Figure reproduced from \autocite{Gedde2019}.}
% \label{fig:floryhugginslattice}
%\end{wrapfigure}
%
\section{Subplot Labelling}
%
Here is a figure \cref{fig:pNIPAM-CN0E_MonoExp_Proof} with a faked second subfigure (width=0, \textbackslash phantomcaption, \textbackslash label) in order to simulate the desired subplot labelling. This is useful if the image you want to show already contains the labels in the panels and you don't want a caption to repeat it and/or use up space.\\
%
\begin{figure}
\begin{subfigure}{\defaultfigurewidth}
\centering
\includegraphics[width=\linewidth]{Figures/pNIPAM-CN0E_MonoExp_Proof.png}
\phantomcaption
\label{fig:pNIPAM-CN0E_MonoExp_Proof_buildUp}
\end{subfigure}%\hfil
\begin{subfigure}{0\linewidth}
\phantomcaption
\label{fig:pNIPAM-CN0E_MonoExp_Proof_beta}
\end{subfigure}
\caption{Normalized build-up of $^2$H magnetization from inversion-recovery experiments at $\wL/(2\pi) \approx \SI{46}{\mega\hertz}$ for various temperatures, together with fits with a stretched exponential function \subref{fig:pNIPAM-CN0E_MonoExp_Proof_buildUp}. Resulting stretching parameters $\beta$ are shown in a narrow range in \subref{fig:pNIPAM-CN0E_MonoExp_Proof_beta}, the vertical line in \subref{fig:pNIPAM-CN0E_MonoExp_Proof_beta} at \SI{305}{\kelvin} marks the \Tdem for \pNIPAM in water \autocite{Costa2002, Bischofberger2014}.}
\label{fig:pNIPAM-CN0E_MonoExp_Proof}
\end{figure}%
%
\begin{lstlisting}
\begin{figure}
\begin{subfigure}{\defaultfigurewidth}
\centering
\includegraphics[width=\linewidth]{Figures/Complete_Figure.png}
\phantomcaption
\label{fig:label_for_first_subfigure}
\end{subfigure}%\hfil
\begin{subfigure}{0\linewidth}
\phantomcaption
\label{fig:label_for_second_subfigure}
\end{subfigure}
\caption{Caption for complete figure.}
\label{fig:label_for_complete_figure}
\end{figure}
\end{lstlisting}
%
\section{Cropping}
%
Here are two multi-subfigure figures with special layout \cref{fig:pnipam-cn3e_uncertainties,fig:pnipam5a_oven40c}. Subfigure vertical alignment for different aspect ratios is cumbersome. You can either write many lines of code, or you can obtain the image heights the figure requests by looking at the log file of an initial compile run, where no fixed heights are set, and then manually set the heights of the subfigures (in combination with the keepaspectratio option) to an appropriate value (cf \url{https://tex.stackexchange.com/questions/389797/fill-textwidth-with-equal-height-subfigures-of-different-aspect-ratios}). You will need to have a look in the log file for this, but opening the log with a text editor of your choice and a simple keyword search for the filename will point you to the right place.
\begin{figure}
\begin{subfigure}[t]{\defaulttwosubfigwidth}
\centering
\includegraphics[height=118.28448pt, keepaspectratio]{Figures/Uncertainties-CN3E_Abs_2H_FullX}
\phantomcaption
\label{sfig:pnipam-cn3e_uncertainties-2h_absfullx}
\end{subfigure}\hfil
\begin{subfigure}[t]{\defaulttwosubfigwidth}
\centering
\includegraphics[height=118.28448pt, keepaspectratio]{Figures/Uncertainties-CN3E_Abs_2H_ZoomX}
\phantomcaption
\label{sfig:pnipam-cn3e_uncertainties-2h_abszoomx}
\end{subfigure}\\
\begin{subfigure}[t]{\defaulttwosubfigwidth}
\centering
\includegraphics[height=118.28448pt, keepaspectratio]{Figures/Uncertainties-CN3E_Abs_17O_FullX}
\phantomcaption
\label{sfig:pnipam-cn3e_uncertainties-17o_absfullx}
\end{subfigure}\hfil
\begin{subfigure}[t]{\defaulttwosubfigwidth}
\centering
\includegraphics[height=118.28448pt, keepaspectratio]{Figures/Uncertainties-CN3E_Abs_17O_ZoomX}
\phantomcaption
\label{sfig:pnipam-cn3e_uncertainties-17o_abszoomx}
\end{subfigure}
\caption{$^2$H \subref{sfig:pnipam-cn3e_uncertainties-2h_absfullx}, \subref{sfig:pnipam-cn3e_uncertainties-2h_abszoomx} and $^{17}$O \subref{sfig:pnipam-cn3e_uncertainties-17o_absfullx}, \subref{sfig:pnipam-cn3e_uncertainties-17o_abszoomx} relaxation times of \pLinSample{30} from the original (Run 1) and a repeat (Run 2) series of measurements to test reproducibility. The scales on the ordinates of \subref{sfig:pnipam-cn3e_uncertainties-2h_absfullx} and \subref{sfig:pnipam-cn3e_uncertainties-17o_absfullx} capture the variation of the relaxation times across all of the investigated temperatures, while \subref{sfig:pnipam-cn3e_uncertainties-2h_abszoomx} and \subref{sfig:pnipam-cn3e_uncertainties-17o_abszoomx} provide magnified views on the region up to the \Tdem. Relaxation times of \BulkSample{30} are shown for reference. The vertical line marks the \Tdem. The data in this figure has been published in the supplementary information to \autocite{Saeckel2025}.}
\label{fig:pnipam-cn3e_uncertainties}
\end{figure}
%
%subfigure vertical alignment for different aspect ratios is cumbersome. either many lines of code, or: https://tex.stackexchange.com/questions/389797/fill-textwidth-with-equal-height-subfigures-of-different-aspect-ratios
%can obtain requested image heights from log file of an initial compile where no fixed heights are set, then manually set height to an appropriate value
\begin{figure}
\centering
\subfloat[\SI{0}{\hour}]{\includegraphics[%width=0.14\linewidth,
height=64pt, keepaspectratio]{Figures/pNIPAM-5A_ImOfen40C_Cropped-1_000h}}\hfill
\subfloat[\SI{16}{\hour}]{\includegraphics[%width=0.14\linewidth,
height=64pt, keepaspectratio]{Figures/pNIPAM-5A_ImOfen40C_Cropped-2_016h}}\hfill
\subfloat[\SI{23}{\hour}]{\includegraphics[%width=0.14\linewidth,
height=64pt, keepaspectratio]{Figures/pNIPAM-5A_ImOfen40C_Cropped-3_023h}}\hfill
\subfloat[\SI{46}{\hour}]{\includegraphics[%width=0.14\linewidth,
height=64pt, keepaspectratio]{Figures/pNIPAM-5A_ImOfen40C_Cropped-4_046h}}\hfill
\subfloat[\SI{95}{\hour}]{\includegraphics[%width=0.14\linewidth,
height=64pt, keepaspectratio]{Figures/pNIPAM-5A_ImOfen40C_Cropped-5_095h}}\hfill
\subfloat[\SI{136}{\hour}]{\includegraphics[%width=0.14\linewidth,
height=64pt, keepaspectratio]{Figures/pNIPAM-5A_ImOfen40C_Cropped-6_136h}}\hfill
\subfloat[\SI{161}{\hour}]{\includegraphics[height=64pt, keepaspectratio]{Figures/pNIPAM-5A_ImOfen40C_Cropped-7_161h}}\hfill
\caption{Photographs of a solution of linear \pNIPAM (\SI{10}{\wtpercent}) in \DTwoO taken at the indicated times through the glass pane of an oven maintaining a temperature of $\sim\SI{40}{\degreeCelsius}$ for several days.}
\label{fig:pnipam5a_oven40c}
\end{figure}

11
Diss_main-blx.bib Normal file
View File

@@ -0,0 +1,11 @@
@Comment{$ biblatex control file $}
@Comment{$ biblatex bcf format version 3.9 $}
% Do not modify this file!
%
% This is an auxiliary file used by the 'biblatex' package.
% This file may safely be deleted. It will be recreated as
% required.
@Control{biblatex-control,
options = {3.9:0:0:1:0:1:1:0:1:0:0:12:2:1:99:1:0:0:2:1:79:+:+:anyt},
}

24
Diss_main.acn Normal file
View File

@@ -0,0 +1,24 @@
\glossaryentry{CPMG?\glossentry{CPMG}|setentrycounter[]{page}"\glsnumberformat}{10}
\glossaryentry{CPMG?\glossentry{CPMG}|setentrycounter[]{page}"\glsnumberformat}{11}
\glossaryentry{pNIPAM?\glossentry{pNIPAM}|setentrycounter[]{page}"\glsnumberformat}{12}
\glossaryentry{pNIPAM?\glossentry{pNIPAM}|setentrycounter[]{page}"\glsnumberformat}{12}
\glossaryentry{pNIPAM?\glossentry{pNIPAM}|setentrycounter[]{page}"\glsnumberformat}{12}
\glossaryentry{CPMG?\glossentry{CPMG}|setentrycounter[]{page}"\glsnumberformat}{12}
\glossaryentry{LCST?\glossentry{LCST}|setentrycounter[]{page}"\glsnumberformat}{13}
\glossaryentry{LCST?\glossentry{LCST}|setentrycounter[]{page}"\glsnumberformat}{13}
\glossaryentry{LCST?\glossentry{LCST}|setentrycounter[]{page}"\glsnumberformat}{13}
\glossaryentry{LCST?\glossentry{LCST}|setentrycounter[]{page}"\glsnumberformat}{13}
\glossaryentry{LCST?\glossentry{LCST}|setentrycounter[]{page}"\glsnumberformat}{14}
\glossaryentry{LCST?\glossentry{LCST}|setentrycounter[]{page}"\glsnumberformat}{14}
\glossaryentry{LCST?\glossentry{LCST}|setentrycounter[]{page}"\glsnumberformat}{14}
\glossaryentry{TMUSC?\glossentry{TMUSC}|setentrycounter[]{page}"\glsnumberformat}{15}
\glossaryentry{TMUSC?\glossentry{TMUSC}|setentrycounter[]{page}"\glsnumberformat}{15}
\glossaryentry{pNIPAM?\glossentry{pNIPAM}|setentrycounter[]{page}"\glsnumberformat}{21}
\glossaryentry{pNIPAM?\glossentry{pNIPAM}|setentrycounter[]{page}"\glsnumberformat}{21}
\glossaryentry{pNIPAM?\glossentry{pNIPAM}|setentrycounter[]{page}"\glsnumberformat}{24}
\glossaryentry{pNIPAM?\glossentry{pNIPAM}|setentrycounter[]{page}"\glsnumberformat}{24}
\glossaryentry{pNIPAM?\glossentry{pNIPAM}|setentrycounter[]{page}"\glsnumberformat}{35}
\glossaryentry{pNIPAM?\glossentry{pNIPAM}|setentrycounter[]{page}"\glsnumberformat}{37}
\glossaryentry{pNIPAM?\glossentry{pNIPAM}|setentrycounter[]{page}"\glsnumberformat}{40}
\glossaryentry{pNIPAM?\glossentry{pNIPAM}|setentrycounter[]{page}"\glsnumberformat}{40}
\glossaryentry{TMUSC?\glossentry{TMUSC}|setentrycounter[]{page}"\glsnumberformat}{40}

21
Diss_main.acr Normal file
View File

@@ -0,0 +1,21 @@
\glossarysection[\glossarytoctitle]{\glossarytitle}\glossarypreamble
\begin{theglossary}\glossaryheader
\glsgroupheading{C}\relax \glsresetentrylist %
\glossentry{CPMG}{\glossaryentrynumbers{\relax
\setentrycounter[]{page}\glsnumberformat{10\delimR 12}}}\glsgroupskip
\glsgroupheading{L}\relax \glsresetentrylist %
\glossentry{LCST}{\glossaryentrynumbers{\relax
\setentrycounter[]{page}\glsnumberformat{13\delimN 14}}}\glsgroupskip
\glsgroupheading{P}\relax \glsresetentrylist %
\glossentry{pNIPAM}{\glossaryentrynumbers{\relax
\setentrycounter[]{page}\glsnumberformat{12}\delimN
\setentrycounter[]{page}\glsnumberformat{21}\delimN
\setentrycounter[]{page}\glsnumberformat{24}\delimN
\setentrycounter[]{page}\glsnumberformat{35}\delimN
\setentrycounter[]{page}\glsnumberformat{37}\delimN
\setentrycounter[]{page}\glsnumberformat{40}}}\glsgroupskip
\glsgroupheading{T}\relax \glsresetentrylist %
\glossentry{TMUSC}{\glossaryentrynumbers{\relax
\setentrycounter[]{page}\glsnumberformat{15}\delimN
\setentrycounter[]{page}\glsnumberformat{40}}}%
\end{theglossary}\glossarypostamble

7
Diss_main.alg Normal file
View File

@@ -0,0 +1,7 @@
This is makeindex, version 2.16 [TeX Live 2022] (kpathsea + Thai support).
Scanning style file ./Diss_main.ist...........................done (27 attributes redefined, 0 ignored).
Scanning input file Diss_main.acn....done (24 entries accepted, 0 rejected).
Sorting entries....done (112 comparisons).
Generating output file Diss_main.acr....done (21 lines written, 0 warnings).
Output written in Diss_main.acr.
Transcript written in Diss_main.alg.

547
Diss_main.aux Normal file
View File

@@ -0,0 +1,547 @@
\relax
\providecommand*\new@tpo@label[2]{}
\providecommand\hyper@newdestlabel[2]{}
\providecommand\HyperFirstAtBeginDocument{\AtBeginDocument}
\HyperFirstAtBeginDocument{\ifx\hyper@anchor\@undefined
\global\let\oldnewlabel\newlabel
\gdef\newlabel#1#2{\newlabelxx{#1}#2}
\gdef\newlabelxx#1#2#3#4#5#6{\oldnewlabel{#1}{{#2}{#3}}}
\AtEndDocument{\ifx\hyper@anchor\@undefined
\let\newlabel\oldnewlabel
\fi}
\fi}
\global\let\hyper@last\relax
\gdef\HyperFirstAtBeginDocument#1{#1}
\providecommand\HyField@AuxAddToFields[1]{}
\providecommand\HyField@AuxAddToCoFields[2]{}
\providecommand\BKM@entry[2]{}
\providecommand\babel@aux[2]{}
\@nameuse{bbl@beforestart}
\catcode `"\active
\bibstyle{biblatex}
\bibdata{Diss_main-blx,Promotion_Literatur}
\citation{biblatex-control}
\abx@aux@refcontext{anyt/global//global/global}
\abx@aux@category{needsurl}{PubChem2005NIPAM}
\abx@aux@category{needsurl}{PubChem2005NIPPA}
\abx@aux@category{needsurl}{grace1991}
\abx@aux@category{needsurl}{Demuth2023}
\abx@aux@category{needsurl}{MarvinDemo}
\providecommand \oddpage@label [2]{}
\providecommand\@newglossary[4]{}
\@newglossary{acronym}{alg}{acr}{acn}
\@newglossary{ignored}{glignoredl}{glignored}{glignoredin}
\@newglossary{unignored}{glunignoredl}{glunignored}{glunignoredin}
\providecommand\@glsorder[1]{}
\providecommand\@istfilename[1]{}
\@istfilename{Diss_main.ist}
\@glsorder{word}
\babel@aux{british}{}
\babel@aux{ngerman}{}
\BKM@entry{id=1,dest={636861707465722A2E31},srcline={2}}{5A7573616D6D656E66617373756E67}
\BKM@entry{id=2,dest={636861707465722A2E32},srcline={13}}{4162737472616374}
\@writefile{toc}{\contentsline {chapter}{\nonumberline Zusammenfassung}{iv}{chapter*.1}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\nonumberline Zusammenfassung}{iv}{chapter*.1}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\nonumberline Zusammenfassung}{iv}{chapter*.1}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\nonumberline Zusammenfassung}{iv}{chapter*.1}\protected@file@percent }
\babel@aux{british}{}
\@writefile{toc}{\contentsline {chapter}{\nonumberline Abstract}{iv}{chapter*.2}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\nonumberline Abstract}{iv}{chapter*.2}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\nonumberline Abstract}{iv}{chapter*.2}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\nonumberline Abstract}{iv}{chapter*.2}\protected@file@percent }
\BKM@entry{id=3,dest={636861707465722A2E33},srcline={74}}{5461626C655C3034306F665C303430436F6E74656E7473}
\@writefile{toc}{\contentsline {chapter}{\nonumberline Table of Contents}{vi}{chapter*.3}\protected@file@percent }
\BKM@entry{id=4,dest={706172742E31},srcline={1}}{50617274735C3034304F6E6C795C30343053657276655C30343044656D6F6E7374726174696F6E5C303430507572706F7365735C30343048657265}
\BKM@entry{id=5,dest={636861707465722E31},srcline={6}}{53706163696E67}
\BKM@entry{id=6,dest={73656374696F6E2E312E31},srcline={9}}{5370656369616C5C30343053706163696E675C303430666F725C3034305468655C30343046697273745C303430436861707465725C303430696E5C303430615C303430476976656E5C30343050617274}
\BKM@entry{id=7,dest={73656374696F6E2E312E32},srcline={21}}{4D617267696E73}
\@writefile{toc}{\contentsline {part}{\numberline {I}Parts Only Serve Demonstration Purposes Here}{1}{part.1}\protected@file@percent }
\@writefile{toc}{\contentsline {chapter}{\numberline {1}Spacing}{1}{chapter.1}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\numberline {1}Spacing}{1}{chapter.1}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\numberline {1}Spacing}{1}{chapter.1}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\numberline {1}Spacing}{1}{chapter.1}\protected@file@percent }
\@writefile{toc}{\contentsline {section}{\numberline {1.1}Special Spacing for The First Chapter in a Given Part}{1}{section.1.1}\protected@file@percent }
\newlabel{sec:part-nopagebreak-chapter}{{1.1}{1}{Special Spacing for The First Chapter in a Given Part}{section.1.1}{}}
\newlabel{sec:part-nopagebreak-chapter@cref}{{[section][1][1]1.1}{[1][1][]1}}
\@writefile{toc}{\contentsline {section}{\numberline {1.2}Margins}{1}{section.1.2}\protected@file@percent }
\newcplabel{^_1}{3}
\newcplabel{^_2}{4}
\BKM@entry{id=8,dest={636861707465722E32},srcline={66}}{5265666572656E6365735C303430776974685C3034305C5C63726566}
\BKM@entry{id=9,dest={73656374696F6E2E322E31},srcline={68}}{53696D706C655C303430557365735C3034306F665C3034305C5C63726566}
\BKM@entry{id=10,dest={73656374696F6E2E322E32},srcline={72}}{486967686C69676874696E675C3034305265666572656E636573}
\@writefile{toc}{\contentsline {chapter}{\numberline {2}References with \textbackslash cref}{5}{chapter.2}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\numberline {2}References with \textbackslash cref}{5}{chapter.2}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\numberline {2}References with \textbackslash cref}{5}{chapter.2}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\numberline {2}References with \textbackslash cref}{5}{chapter.2}\protected@file@percent }
\newlabel{sec:cleveref}{{2}{5}{References with \textbackslash cref}{chapter.2}{}}
\newlabel{sec:cleveref@cref}{{[chapter][2][]2}{[1][5][]5}}
\@writefile{toc}{\contentsline {section}{\numberline {2.1}Simple Uses of \textbackslash cref}{5}{section.2.1}\protected@file@percent }
\newlabel{sec:cleveref_simple}{{2.1}{5}{Simple Uses of \textbackslash cref}{section.2.1}{}}
\newlabel{sec:cleveref_simple@cref}{{[section][1][2]2.1}{[1][5][]5}}
\@writefile{toc}{\contentsline {section}{\numberline {2.2}Highlighting References}{5}{section.2.2}\protected@file@percent }
\newlabel{sec:highlighting_links}{{2.2}{5}{Highlighting References}{section.2.2}{}}
\newlabel{sec:highlighting_links@cref}{{[section][2][2]2.2}{[1][5][]5}}
\BKM@entry{id=11,dest={73656374696F6E2E322E33},srcline={103}}{416476616E6365645C303430557365735C3034306F665C3034305C5C63726566}
\@writefile{toc}{\contentsline {section}{\numberline {2.3}Advanced Uses of \textbackslash cref}{6}{section.2.3}\protected@file@percent }
\newlabel{sec:cleveref_advanced}{{2.3}{6}{Advanced Uses of \textbackslash cref}{section.2.3}{}}
\newlabel{sec:cleveref_advanced@cref}{{[section][3][2]2.3}{[1][6][]6}}
\BKM@entry{id=12,dest={636861707465722E33},srcline={135}}{4369746174696F6E73}
\@writefile{toc}{\contentsline {chapter}{\numberline {3}Citations}{8}{chapter.3}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\numberline {3}Citations}{8}{chapter.3}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\numberline {3}Citations}{8}{chapter.3}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\numberline {3}Citations}{8}{chapter.3}\protected@file@percent }
\newlabel{sec:citations}{{3}{8}{Citations}{chapter.3}{}}
\newlabel{sec:citations@cref}{{[chapter][3][]3}{[1][8][]8}}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Halperin2015}
\abx@aux@cite{0}{Halperin2015}
\abx@aux@segm{0}{0}{Halperin2015}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Slichter1990}
\abx@aux@cite{0}{Slichter1990}
\abx@aux@segm{0}{0}{Slichter1990}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Fujishige1989}
\abx@aux@cite{0}{Fujishige1989}
\abx@aux@segm{0}{0}{Fujishige1989}
\citation{Halperin2015}
\abx@aux@cite{0}{Halperin2015}
\abx@aux@segm{0}{0}{Halperin2015}
\citation{Korde2019}
\abx@aux@cite{0}{Korde2019}
\abx@aux@segm{0}{0}{Korde2019}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Fujishige1989}
\abx@aux@cite{0}{Fujishige1989}
\abx@aux@segm{0}{0}{Fujishige1989}
\citation{Halperin2015}
\abx@aux@cite{0}{Halperin2015}
\abx@aux@segm{0}{0}{Halperin2015}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Halperin2015}
\abx@aux@cite{0}{Halperin2015}
\abx@aux@segm{0}{0}{Halperin2015}
\citation{Halperin2015}
\abx@aux@cite{0}{Halperin2015}
\abx@aux@segm{0}{0}{Halperin2015}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Halperin2015}
\abx@aux@cite{0}{Halperin2015}
\abx@aux@segm{0}{0}{Halperin2015}
\citation{Korde2019}
\abx@aux@cite{0}{Korde2019}
\abx@aux@segm{0}{0}{Korde2019}
\citation{Halperin2015}
\abx@aux@cite{0}{Halperin2015}
\abx@aux@segm{0}{0}{Halperin2015}
\citation{Korde2019}
\abx@aux@cite{0}{Korde2019}
\abx@aux@segm{0}{0}{Korde2019}
\abx@aux@refcontext{anyt/global//global/global}
\citation{PubChem2005NIPAM}
\abx@aux@cite{0}{PubChem2005NIPAM}
\abx@aux@segm{0}{0}{PubChem2005NIPAM}
\abx@aux@backref{1}{Halperin2015}{0}{10}{10}
\abx@aux@backref{2}{Slichter1990}{0}{10}{10}
\abx@aux@backref{3}{Fujishige1989}{0}{10}{10}
\abx@aux@backref{4}{Halperin2015}{0}{10}{10}
\abx@aux@backref{5}{Korde2019}{0}{10}{10}
\abx@aux@backref{6}{Fujishige1989}{0}{10}{10}
\abx@aux@backref{7}{Halperin2015}{0}{10}{10}
\abx@aux@backref{8}{Halperin2015}{0}{10}{10}
\abx@aux@backref{9}{Halperin2015}{0}{10}{10}
\abx@aux@backref{10}{Halperin2015}{0}{10}{10}
\abx@aux@backref{11}{Korde2019}{0}{10}{10}
\abx@aux@backref{12}{Halperin2015}{0}{10}{10}
\abx@aux@backref{13}{Korde2019}{0}{10}{10}
\abx@aux@backref{14}{PubChem2005NIPAM}{0}{10}{10}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Carr1954}
\abx@aux@cite{0}{Carr1954}
\abx@aux@segm{0}{0}{Carr1954}
\citation{Carr1954}
\abx@aux@cite{0}{Carr1954}
\abx@aux@segm{0}{0}{Carr1954}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Meiboom1958}
\abx@aux@cite{0}{Meiboom1958}
\abx@aux@segm{0}{0}{Meiboom1958}
\citation{Meiboom1958}
\abx@aux@cite{0}{Meiboom1958}
\abx@aux@segm{0}{0}{Meiboom1958}
\abx@aux@backref{15}{Carr1954}{0}{11}{11}
\abx@aux@backref{16}{Carr1954}{0}{11}{11}
\abx@aux@backref{17}{Meiboom1958}{0}{11}{11}
\abx@aux@backref{18}{Meiboom1958}{0}{11}{11}
\BKM@entry{id=13,dest={636861707465722E34},srcline={231}}{476C6F7373617279}
\@writefile{toc}{\contentsline {chapter}{\numberline {4}Glossary}{12}{chapter.4}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\numberline {4}Glossary}{12}{chapter.4}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\numberline {4}Glossary}{12}{chapter.4}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\numberline {4}Glossary}{12}{chapter.4}\protected@file@percent }
\BKM@entry{id=14,dest={73656374696F6E2E342E31},srcline={285}}{5370656369616C5C30343043617365735C303430446570656E64696E675C3034306F6E5C3034304163726F6E796D5C3034304F6363757272656E63655C303430436F756E7473}
\@writefile{toc}{\contentsline {section}{\numberline {4.1}Special Cases Depending on Acronym Occurrence Counts}{14}{section.4.1}\protected@file@percent }
\newlabel{sec:glossary_occurrence_counts}{{4.1}{14}{Special Cases Depending on Acronym Occurrence Counts}{section.4.1}{}}
\newlabel{sec:glossary_occurrence_counts@cref}{{[section][1][4]4.1}{[1][14][]14}}
\BKM@entry{id=15,dest={73756273656374696F6E2E342E312E31},srcline={291}}{45787472615C3034305370656369616C5C30343043617365735C303430446570656E64696E675C3034306F6E5C3034304163726F6E796D5C3034304F6363757272656E63655C303430436F756E7473}
\@writefile{toc}{\contentsline {subsection}{\numberline {4.1.1}Extra Special Cases Depending on Acronym Occurrence Counts}{15}{subsection.4.1.1}\protected@file@percent }
\newlabel{sec:glossary_occurrence_counts_resets}{{4.1.1}{15}{Extra Special Cases Depending on Acronym Occurrence Counts}{subsection.4.1.1}{}}
\newlabel{sec:glossary_occurrence_counts_resets@cref}{{[subsection][1][4,1]4.1.1}{[1][15][]15}}
\BKM@entry{id=16,dest={636861707465722E35},srcline={302}}{4D6163726F73}
\@writefile{toc}{\contentsline {chapter}{\numberline {5}Macros}{16}{chapter.5}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\numberline {5}Macros}{16}{chapter.5}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\numberline {5}Macros}{16}{chapter.5}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\numberline {5}Macros}{16}{chapter.5}\protected@file@percent }
\BKM@entry{id=17,dest={73656374696F6E2E352E31},srcline={344}}{5479706573657474696E67}
\BKM@entry{id=18,dest={73756273656374696F6E2E352E312E31},srcline={346}}{41637475616C5C3034304E6F7465735C3034306F6E5C3034305479706573657474696E67}
\@writefile{toc}{\contentsline {section}{\numberline {5.1}Typesetting}{17}{section.5.1}\protected@file@percent }
\@writefile{toc}{\contentsline {subsection}{\numberline {5.1.1}Actual Notes on Typesetting}{17}{subsection.5.1.1}\protected@file@percent }
\@writefile{toc}{\contentsline {subsubsection}{\nonumberline Indices}{17}{subsubsection*.5}\protected@file@percent }
\@writefile{toc}{\contentsline {subsubsection}{\nonumberline Units}{17}{subsubsection*.7}\protected@file@percent }
\BKM@entry{id=19,dest={73756273656374696F6E2E352E312E32},srcline={396}}{4D6163726F735C303430666F725C3034305479706573657474696E67}
\@writefile{toc}{\contentsline {subsubsection}{\nonumberline Dashes and Space Between ``e.g.''}{18}{subsubsection*.9}\protected@file@percent }
\@writefile{toc}{\contentsline {subsubsection}{\nonumberline Odds and Ends}{18}{subsubsection*.11}\protected@file@percent }
\newlabel{sec:linebreak_packages}{{5.1.1}{18}{Odds and Ends}{subsubsection*.11}{}}
\newlabel{sec:linebreak_packages@cref}{{[subsection][1][5,1]5.1.1}{[1][18][]18}}
\@writefile{toc}{\contentsline {subsubsection}{\nonumberline Textsuperscript \textsuperscript {2}H vs Math Mode $^2$H}{18}{subsubsection*.13}\protected@file@percent }
\@writefile{toc}{\contentsline {subsection}{\numberline {5.1.2}Macros for Typesetting}{19}{subsection.5.1.2}\protected@file@percent }
\@writefile{toc}{\contentsline {subsubsection}{\nonumberline Row Vectors}{20}{subsubsection*.15}\protected@file@percent }
\BKM@entry{id=20,dest={73756273656374696F6E2E352E312E33},srcline={490}}{4D6163726F735C303430776974685C303430417267756D656E7473}
\newlabel{eq:b1-rotating}{{5.1}{21}{Row Vectors}{equation.5.1.1}{}}
\newlabel{eq:b1-rotating@cref}{{[equation][1][5]5.1}{[1][21][]21}}
\@writefile{toc}{\contentsline {subsection}{\numberline {5.1.3}Macros with Arguments}{21}{subsection.5.1.3}\protected@file@percent }
\newlabel{eq:magnetic_moment}{{5.2}{22}{Macros with Arguments}{equation.5.1.2}{}}
\newlabel{eq:magnetic_moment@cref}{{[equation][2][5]5.2}{[1][22][]22}}
\newlabel{sec:samplename_macros}{{5.1.3}{22}{More Complicated Macro Example}{paragraph*.17}{}}
\newlabel{sec:samplename_macros@cref}{{[subsection][3][5,1]5.1.3}{[1][22][]22}}
\@writefile{toc}{\contentsline {paragraph}{\nonumberline More Complicated Macro Example}{22}{paragraph*.17}\protected@file@percent }
\BKM@entry{id=21,dest={73656374696F6E2E352E32},srcline={546}}{48797068656E6174696F6E}
\BKM@entry{id=22,dest={73756273656374696F6E2E352E322E31},srcline={556}}{436F6E74726F6C6C696E675C3034304C696E65627265616B73}
\@writefile{toc}{\contentsline {section}{\numberline {5.2}Hyphenation}{23}{section.5.2}\protected@file@percent }
\newlabel{sec:hyphenation_explanation}{{5.2}{23}{Hyphenation}{section.5.2}{}}
\newlabel{sec:hyphenation_explanation@cref}{{[section][2][5]5.2}{[1][23][]23}}
\@writefile{toc}{\contentsline {subsection}{\numberline {5.2.1}Controlling Linebreaks}{23}{subsection.5.2.1}\protected@file@percent }
\BKM@entry{id=23,dest={636861707465722E36},srcline={577}}{5661726961626C6573}
\BKM@entry{id=24,dest={73656374696F6E2E362E31},srcline={579}}{426F6F6C65616E73}
\@writefile{toc}{\contentsline {chapter}{\numberline {6}Variables}{25}{chapter.6}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\numberline {6}Variables}{25}{chapter.6}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\numberline {6}Variables}{25}{chapter.6}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\numberline {6}Variables}{25}{chapter.6}\protected@file@percent }
\@writefile{toc}{\contentsline {section}{\numberline {6.1}Booleans}{25}{section.6.1}\protected@file@percent }
\BKM@entry{id=25,dest={73756273656374696F6E2E362E312E31},srcline={633}}{546F646F6E6F746573}
\BKM@entry{id=26,dest={73656374696F6E2E362E32},srcline={651}}{4F746865725C30343054797065735C3034306F665C3034305661726961626C6573}
\@writefile{toc}{\contentsline {subsection}{\numberline {6.1.1}Todonotes}{26}{subsection.6.1.1}\protected@file@percent }
\@writefile{tdo}{\contentsline {todo}{text displayed in the margin}{26}{section*.18}\protected@file@percent }
\pgfsyspdfmark {pgfid1}{10291690}{29214102}
\@writefile{tdo}{\contentsline {todo}{this goes into the main text area}{26}{section*.19}\protected@file@percent }
\pgfsyspdfmark {pgfid2}{1389063}{29229548}
\pgfsyspdfmark {pgfid3}{4309550}{28982429}
\pgfsyspdfmark {pgfid6}{18872819}{27751373}
\@writefile{tdo}{\contentsline {todo}{This background is blue with only 20 percent saturation.}{26}{section*.20}\protected@file@percent }
\pgfsyspdfmark {pgfid7}{18872819}{15702397}
\@writefile{toc}{\contentsline {section}{\numberline {6.2}Other Types of Variables}{26}{section.6.2}\protected@file@percent }
\BKM@entry{id=27,dest={636861707465722E37},srcline={8}}{5265666572656E63696E675C3034304571756174696F6E73}
\@writefile{toc}{\contentsline {chapter}{\numberline {7}Referencing Equations}{28}{chapter.7}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\numberline {7}Referencing Equations}{28}{chapter.7}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\numberline {7}Referencing Equations}{28}{chapter.7}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\numberline {7}Referencing Equations}{28}{chapter.7}\protected@file@percent }
\newlabel{sec:referencing_equations}{{7}{28}{Referencing Equations}{chapter.7}{}}
\newlabel{sec:referencing_equations@cref}{{[chapter][7][]7}{[1][28][]28}}
\newlabel{eqs:hamiltonian_QP_EFG}{{7.1}{28}{Referencing Equations}{equation.7.0.1}{}}
\newlabel{eqs:hamiltonian_QP_EFG@cref}{{[subequation][1][7]7.1}{[1][28][]28}}
\newlabel{eq:hamiltonian_qp}{{7.1a}{28}{Referencing Equations}{equation.7.0.1}{}}
\newlabel{eq:hamiltonian_qp@cref}{{[subequation][1][7,1]7.1a}{[1][28][]28}}
\newlabel{eq:efg_lab}{{7.1b}{28}{Referencing Equations}{equation.7.0.2}{}}
\newlabel{eq:efg_lab@cref}{{[subequation][2][7,1]7.1b}{[1][28][]28}}
\BKM@entry{id=28,dest={73656374696F6E2E372E31},srcline={49}}{526570656174696E675C303430616E5C3034304571756174696F6E5C3034307768696C655C303430526566657272696E675C303430746F5C3034307468655C3034304F726967696E616C}
\BKM@entry{id=29,dest={73656374696F6E2E372E32},srcline={65}}{4571756174696F6E735C303430776974685C3034304361736573}
\newlabel{eq:nonumber_example}{{7.2}{29}{Referencing Equations}{equation.7.0.2}{}}
\newlabel{eq:nonumber_example@cref}{{[equation][2][7]7.2}{[1][29][]29}}
\@writefile{toc}{\contentsline {section}{\numberline {7.1}Repeating an Equation while Referring to the Original}{29}{section.7.1}\protected@file@percent }
\newlabel{dummytag}{{{\cref {eq:autocorrelation} (repeated)}}{29}{Repeating an Equation while Referring to the Original}{lstnumber.-48.5}{}}
\newlabel{dummytag@cref}{{[equation][2147483647][]{\cref {eq:autocorrelation} (repeated)}}{[1][29][]29}}
\BKM@entry{id=30,dest={73656374696F6E2E372E33},srcline={94}}{4D756C74696C696E655C3034304571756174696F6E}
\@writefile{toc}{\contentsline {section}{\numberline {7.2}Equations with Cases}{30}{section.7.2}\protected@file@percent }
\newlabel{eq:cases}{{7.3}{30}{Equations with Cases}{equation.7.2.3}{}}
\newlabel{eq:cases@cref}{{[subequation][3][7]7.3}{[1][30][]30}}
\newlabel{eqs:qcc_anisotropy}{{7.3}{30}{Equations with Cases}{equation.7.2.3}{}}
\newlabel{eqs:qcc_anisotropy@cref}{{[subequation][3][7]7.3}{[1][30][]30}}
\newlabel{eq:qcc}{{7.3a}{30}{Equations with Cases}{equation.7.2.1}{}}
\newlabel{eq:qcc@cref}{{[subequation][1][7,3]7.3a}{[1][30][]30}}
\newlabel{eq:anisotropy}{{7.3b}{30}{Equations with Cases}{equation.7.2.2}{}}
\newlabel{eq:anisotropy@cref}{{[subequation][2][7,3]7.3b}{[1][30][]30}}
\@writefile{toc}{\contentsline {section}{\numberline {7.3}Multiline Equation}{30}{section.7.3}\protected@file@percent }
\newlabel{eq:diff_two-step-decay}{{7.4}{31}{Multiline Equation}{equation.7.3.4}{}}
\newlabel{eq:diff_two-step-decay@cref}{{[equation][4][7]7.4}{[1][31][]31}}
\BKM@entry{id=31,dest={636861707465722E38},srcline={115}}{46696775726573}
\BKM@entry{id=32,dest={73656374696F6E2E382E31},srcline={117}}{506C6163656D656E74}
\@writefile{toc}{\contentsline {chapter}{\numberline {8}Figures}{32}{chapter.8}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\numberline {8}Figures}{32}{chapter.8}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\numberline {8}Figures}{32}{chapter.8}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\numberline {8}Figures}{32}{chapter.8}\protected@file@percent }
\@writefile{toc}{\contentsline {section}{\numberline {8.1}Placement}{32}{section.8.1}\protected@file@percent }
\abx@aux@refcontext{anyt/global//global/global}
\citation{Gedde2019}
\abx@aux@cite{0}{Gedde2019}
\abx@aux@segm{0}{0}{Gedde2019}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Gedde2019}
\abx@aux@cite{0}{Gedde2019}
\abx@aux@segm{0}{0}{Gedde2019}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Rubinstein2004}
\abx@aux@cite{0}{Rubinstein2004}
\abx@aux@segm{0}{0}{Rubinstein2004}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Rubinstein2004}
\abx@aux@cite{0}{Rubinstein2004}
\abx@aux@segm{0}{0}{Rubinstein2004}
\BKM@entry{id=33,dest={73656374696F6E2E382E32},srcline={176}}{537562706C6F745C3034304C6162656C6C696E67}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Costa2002}
\abx@aux@cite{0}{Costa2002}
\abx@aux@segm{0}{0}{Costa2002}
\citation{Bischofberger2014}
\abx@aux@cite{0}{Bischofberger2014}
\abx@aux@segm{0}{0}{Bischofberger2014}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Costa2002}
\abx@aux@cite{0}{Costa2002}
\abx@aux@segm{0}{0}{Costa2002}
\citation{Bischofberger2014}
\abx@aux@cite{0}{Bischofberger2014}
\abx@aux@segm{0}{0}{Bischofberger2014}
\@writefile{lof}{\contentsline {figure}{\numberline {8.1}{\ignorespaces Sketch of the shift in terms of angular frequency of initially degenerate energy levels of a spin $I=1$ nucleus due to Zeeman and quadrupolar interaction (first order, not to scale).\relax }}{33}{figure.caption.21}\protected@file@percent }
\providecommand*\caption@xref[2]{\@setref\relax\@undefined{#1}}
\newlabel{fig:energylevelszeeman-qp1}{{8.1}{33}{Sketch of the shift in terms of angular frequency of initially degenerate energy levels of a spin $I=1$ nucleus due to Zeeman and quadrupolar interaction (first order, not to scale).\relax }{figure.caption.21}{}}
\newlabel{fig:energylevelszeeman-qp1@cref}{{[figure][1][8]8.1}{[1][32][]33}}
\@writefile{toc}{\contentsline {section}{\numberline {8.2}Subplot Labelling}{33}{section.8.2}\protected@file@percent }
\@writefile{lof}{\contentsline {figure}{\numberline {8.2}{\ignorespaces Distribution of a polymer and a low molecular mass solvent on a (2-dimensional) lattice as per the Flory-Huggins theory. Figure reproduced from \blx@tocontentsinit {0}\autocite {Gedde2019}.\relax }}{34}{figure.caption.22}\protected@file@percent }
\abx@aux@backref{20}{Gedde2019}{0}{34}{34}
\newlabel{fig:floryhugginslattice}{{8.2}{34}{Distribution of a polymer and a low molecular mass solvent on a (2-dimensional) lattice as per the Flory-Huggins theory. Figure reproduced from \autocite {Gedde2019}.\relax }{figure.caption.22}{}}
\newlabel{fig:floryhugginslattice@cref}{{[figure][2][8]8.2}{[1][33][]34}}
\@writefile{lof}{\contentsline {figure}{\numberline {8.3}{\ignorespaces Top: (Scaled) change in free energy due to mixing for a symmetric mixture. The minima are marked as $\phi ^\prime $ and $\phi ^{\prime \prime }$ and the inflection points as $\phi _\mathrm {sp1}$ and $\phi _\mathrm {sp2}$. Bottom: Phase diagram of the mixture. The thick dashed and solid lines represent the spinodal and binodal, respectively. From the top panel, values of the binodal (minima) and spinodal (inflection points) at a given value of $N\chi $ can be derived. Figure reproduced from \blx@tocontentsinit {0}\autocite {Rubinstein2004}.\relax }}{34}{figure.caption.22}\protected@file@percent }
\abx@aux@backref{22}{Rubinstein2004}{0}{34}{34}
\newlabel{fig:binodal-spinodal-phase-diagram}{{8.3}{34}{Top: (Scaled) change in free energy due to mixing for a symmetric mixture. The minima are marked as $\phi ^\prime $ and $\phi ^{\prime \prime }$ and the inflection points as $\phi _\mathrm {sp1}$ and $\phi _\mathrm {sp2}$. Bottom: Phase diagram of the mixture. The thick dashed and solid lines represent the spinodal and binodal, respectively. From the top panel, values of the binodal (minima) and spinodal (inflection points) at a given value of $N\chi $ can be derived. Figure reproduced from \autocite {Rubinstein2004}.\relax }{figure.caption.22}{}}
\newlabel{fig:binodal-spinodal-phase-diagram@cref}{{[figure][3][8]8.3}{[1][33][]34}}
\newlabel{fig:pNIPAM-CN0E_MonoExp_Proof_buildUp}{{8.4\,a)}{35}{Subplot Labelling}{figure.caption.23}{}}
\newlabel{fig:pNIPAM-CN0E_MonoExp_Proof_buildUp@cref}{{[subfigure][1][8,4]8.4\,a)}{[1][33][]35}}
\newlabel{sub@fig:pNIPAM-CN0E_MonoExp_Proof_buildUp}{{a)}{35}{Subplot Labelling}{figure.caption.23}{}}
\newlabel{sub@fig:pNIPAM-CN0E_MonoExp_Proof_buildUp@cref}{{[subfigure][1][8,4]8.4\,a)}{[1][33][]35}}
\newlabel{fig:pNIPAM-CN0E_MonoExp_Proof_beta}{{8.4\,b)}{35}{Subplot Labelling}{figure.caption.23}{}}
\newlabel{fig:pNIPAM-CN0E_MonoExp_Proof_beta@cref}{{[subfigure][2][8,4]8.4\,b)}{[1][33][]35}}
\newlabel{sub@fig:pNIPAM-CN0E_MonoExp_Proof_beta}{{b)}{35}{Subplot Labelling}{figure.caption.23}{}}
\newlabel{sub@fig:pNIPAM-CN0E_MonoExp_Proof_beta@cref}{{[subfigure][2][8,4]8.4\,b)}{[1][33][]35}}
\@writefile{lof}{\contentsline {figure}{\numberline {8.4}{\ignorespaces Normalized build-up of $^2$H magnetization from inversion-recovery experiments at $\ensuremath {\omega _\mathrm {L}}\xspace /(2\pi ) \approx \SI {46}{\mega \hertz }$ for various temperatures, together with fits with a stretched exponential function \subref {fig:pNIPAM-CN0E_MonoExp_Proof_buildUp}. Resulting stretching parameters $\beta $ are shown in a narrow range in \subref {fig:pNIPAM-CN0E_MonoExp_Proof_beta}, the vertical line in \subref {fig:pNIPAM-CN0E_MonoExp_Proof_beta} at \SI {305}{\kelvin } marks the \gls *{Tdem}\xspace for \gls {pNIPAM}\xspace in water \blx@tocontentsinit {0}\autocite {Costa2002, Bischofberger2014}.\relax }}{35}{figure.caption.23}\protected@file@percent }
\abx@aux@backref{25}{Costa2002}{0}{35}{35}
\abx@aux@backref{26}{Bischofberger2014}{0}{35}{35}
\newlabel{fig:pNIPAM-CN0E_MonoExp_Proof}{{8.4}{35}{Normalized build-up of $^2$H magnetization from inversion-recovery experiments at $\wL /(2\pi ) \approx \SI {46}{\mega \hertz }$ for various temperatures, together with fits with a stretched exponential function \subref {fig:pNIPAM-CN0E_MonoExp_Proof_buildUp}. Resulting stretching parameters $\beta $ are shown in a narrow range in \subref {fig:pNIPAM-CN0E_MonoExp_Proof_beta}, the vertical line in \subref {fig:pNIPAM-CN0E_MonoExp_Proof_beta} at \SI {305}{\kelvin } marks the \Tdem for \pNIPAM in water \autocite {Costa2002, Bischofberger2014}.\relax }{figure.caption.23}{}}
\newlabel{fig:pNIPAM-CN0E_MonoExp_Proof@cref}{{[figure][4][8]8.4}{[1][33][]35}}
\BKM@entry{id=34,dest={73656374696F6E2E382E33},srcline={212}}{43726F7070696E67}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2025}
\abx@aux@cite{0}{Saeckel2025}
\abx@aux@segm{0}{0}{Saeckel2025}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2025}
\abx@aux@cite{0}{Saeckel2025}
\abx@aux@segm{0}{0}{Saeckel2025}
\@writefile{toc}{\contentsline {section}{\numberline {8.3}Cropping}{36}{section.8.3}\protected@file@percent }
\newlabel{sfig:pnipam-cn3e_uncertainties-2h_absfullx}{{8.5\,a)}{37}{Cropping}{figure.caption.24}{}}
\newlabel{sfig:pnipam-cn3e_uncertainties-2h_absfullx@cref}{{[subfigure][1][8,5]8.5\,a)}{[1][36][]37}}
\newlabel{sub@sfig:pnipam-cn3e_uncertainties-2h_absfullx}{{a)}{37}{Cropping}{figure.caption.24}{}}
\newlabel{sub@sfig:pnipam-cn3e_uncertainties-2h_absfullx@cref}{{[subfigure][1][8,5]8.5\,a)}{[1][36][]37}}
\newlabel{sfig:pnipam-cn3e_uncertainties-2h_abszoomx}{{8.5\,b)}{37}{Cropping}{figure.caption.24}{}}
\newlabel{sfig:pnipam-cn3e_uncertainties-2h_abszoomx@cref}{{[subfigure][2][8,5]8.5\,b)}{[1][36][]37}}
\newlabel{sub@sfig:pnipam-cn3e_uncertainties-2h_abszoomx}{{b)}{37}{Cropping}{figure.caption.24}{}}
\newlabel{sub@sfig:pnipam-cn3e_uncertainties-2h_abszoomx@cref}{{[subfigure][2][8,5]8.5\,b)}{[1][36][]37}}
\newlabel{sfig:pnipam-cn3e_uncertainties-17o_absfullx}{{8.5\,c)}{37}{Cropping}{figure.caption.24}{}}
\newlabel{sfig:pnipam-cn3e_uncertainties-17o_absfullx@cref}{{[subfigure][3][8,5]8.5\,c)}{[1][36][]37}}
\newlabel{sub@sfig:pnipam-cn3e_uncertainties-17o_absfullx}{{c)}{37}{Cropping}{figure.caption.24}{}}
\newlabel{sub@sfig:pnipam-cn3e_uncertainties-17o_absfullx@cref}{{[subfigure][3][8,5]8.5\,c)}{[1][36][]37}}
\newlabel{sfig:pnipam-cn3e_uncertainties-17o_abszoomx}{{8.5\,d)}{37}{Cropping}{figure.caption.24}{}}
\newlabel{sfig:pnipam-cn3e_uncertainties-17o_abszoomx@cref}{{[subfigure][4][8,5]8.5\,d)}{[1][36][]37}}
\newlabel{sub@sfig:pnipam-cn3e_uncertainties-17o_abszoomx}{{d)}{37}{Cropping}{figure.caption.24}{}}
\newlabel{sub@sfig:pnipam-cn3e_uncertainties-17o_abszoomx@cref}{{[subfigure][4][8,5]8.5\,d)}{[1][36][]37}}
\@writefile{lof}{\contentsline {figure}{\numberline {8.5}{\ignorespaces $^2$H \subref {sfig:pnipam-cn3e_uncertainties-2h_absfullx}, \subref {sfig:pnipam-cn3e_uncertainties-2h_abszoomx} and $^{17}$O \subref {sfig:pnipam-cn3e_uncertainties-17o_absfullx}, \subref {sfig:pnipam-cn3e_uncertainties-17o_abszoomx} relaxation times of \pLinSample {30} from the original (Run 1) and a repeat (Run 2) series of measurements to test reproducibility. The scales on the ordinates of \subref {sfig:pnipam-cn3e_uncertainties-2h_absfullx} and \subref {sfig:pnipam-cn3e_uncertainties-17o_absfullx} capture the variation of the relaxation times across all of the investigated temperatures, while \subref {sfig:pnipam-cn3e_uncertainties-2h_abszoomx} and \subref {sfig:pnipam-cn3e_uncertainties-17o_abszoomx} provide magnified views on the region up to the \gls *{Tdem}\xspace . Relaxation times of \BulkSample {30} are shown for reference. The vertical line marks the \gls *{Tdem}\xspace . The data in this figure has been published in the supplementary information to \blx@tocontentsinit {0}\autocite {Saeckel2025}.\relax }}{37}{figure.caption.24}\protected@file@percent }
\abx@aux@backref{28}{Saeckel2025}{0}{37}{37}
\newlabel{fig:pnipam-cn3e_uncertainties}{{8.5}{37}{$^2$H \subref {sfig:pnipam-cn3e_uncertainties-2h_absfullx}, \subref {sfig:pnipam-cn3e_uncertainties-2h_abszoomx} and $^{17}$O \subref {sfig:pnipam-cn3e_uncertainties-17o_absfullx}, \subref {sfig:pnipam-cn3e_uncertainties-17o_abszoomx} relaxation times of \pLinSample {30} from the original (Run 1) and a repeat (Run 2) series of measurements to test reproducibility. The scales on the ordinates of \subref {sfig:pnipam-cn3e_uncertainties-2h_absfullx} and \subref {sfig:pnipam-cn3e_uncertainties-17o_absfullx} capture the variation of the relaxation times across all of the investigated temperatures, while \subref {sfig:pnipam-cn3e_uncertainties-2h_abszoomx} and \subref {sfig:pnipam-cn3e_uncertainties-17o_abszoomx} provide magnified views on the region up to the \Tdem . Relaxation times of \BulkSample {30} are shown for reference. The vertical line marks the \Tdem . The data in this figure has been published in the supplementary information to \autocite {Saeckel2025}.\relax }{figure.caption.24}{}}
\newlabel{fig:pnipam-cn3e_uncertainties@cref}{{[figure][5][8]8.5}{[1][36][]37}}
\@writefile{lof}{\contentsline {figure}{\numberline {8.6}{\ignorespaces Photographs of a solution of linear \gls {pNIPAM}\xspace (\SI {10}{\wtpercent }) in \ensuremath {\mathrm {D_2O}}\xspace taken at the indicated times through the glass pane of an oven maintaining a temperature of $\sim \SI {40}{\degreeCelsius }$ for several days.\relax }}{37}{figure.caption.25}\protected@file@percent }
\newlabel{fig:pnipam5a_oven40c}{{8.6}{37}{Photographs of a solution of linear \pNIPAM (\SI {10}{\wtpercent }) in \DTwoO taken at the indicated times through the glass pane of an oven maintaining a temperature of $\sim \SI {40}{\degreeCelsius }$ for several days.\relax }{figure.caption.25}{}}
\newlabel{fig:pnipam5a_oven40c@cref}{{[figure][6][8]8.6}{[1][36][]37}}
\BKM@entry{id=35,dest={636861707465722E39},srcline={2}}{5461626C655C303430616E645C30343053616D706C655C3034304D6163726F73}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2024}
\abx@aux@cite{0}{Saeckel2024}
\abx@aux@segm{0}{0}{Saeckel2024}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2024}
\abx@aux@cite{0}{Saeckel2024}
\abx@aux@segm{0}{0}{Saeckel2024}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2025}
\abx@aux@cite{0}{Saeckel2025}
\abx@aux@segm{0}{0}{Saeckel2025}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2025}
\abx@aux@cite{0}{Saeckel2025}
\abx@aux@segm{0}{0}{Saeckel2025}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2025}
\abx@aux@cite{0}{Saeckel2025}
\abx@aux@segm{0}{0}{Saeckel2025}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2025}
\abx@aux@cite{0}{Saeckel2025}
\abx@aux@segm{0}{0}{Saeckel2025}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2025}
\abx@aux@cite{0}{Saeckel2025}
\abx@aux@segm{0}{0}{Saeckel2025}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2025}
\abx@aux@cite{0}{Saeckel2025}
\abx@aux@segm{0}{0}{Saeckel2025}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2025}
\abx@aux@cite{0}{Saeckel2025}
\abx@aux@segm{0}{0}{Saeckel2025}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2025}
\abx@aux@cite{0}{Saeckel2025}
\abx@aux@segm{0}{0}{Saeckel2025}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2025}
\abx@aux@cite{0}{Saeckel2025}
\abx@aux@segm{0}{0}{Saeckel2025}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2025}
\abx@aux@cite{0}{Saeckel2025}
\abx@aux@segm{0}{0}{Saeckel2025}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2025}
\abx@aux@cite{0}{Saeckel2025}
\abx@aux@segm{0}{0}{Saeckel2025}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Saeckel2024}
\abx@aux@cite{0}{Saeckel2024}
\abx@aux@segm{0}{0}{Saeckel2024}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Hindman1971}
\abx@aux@cite{0}{Hindman1971}
\abx@aux@segm{0}{0}{Hindman1971}
\abx@aux@refcontext{anyt/global//global/global}
\citation{Hindman1971}
\abx@aux@cite{0}{Hindman1971}
\abx@aux@segm{0}{0}{Hindman1971}
\@writefile{toc}{\contentsline {chapter}{\numberline {9}Table and Sample Macros}{38}{chapter.9}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\numberline {9}Table and Sample Macros}{38}{chapter.9}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\numberline {9}Table and Sample Macros}{38}{chapter.9}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\numberline {9}Table and Sample Macros}{38}{chapter.9}\protected@file@percent }
\abx@aux@backref{29}{Saeckel2024}{0}{39}{39}
\abx@aux@backref{30}{Saeckel2024}{0}{39}{39}
\abx@aux@backref{31}{Saeckel2025}{0}{39}{39}
\abx@aux@backref{32}{Saeckel2025}{0}{39}{39}
\abx@aux@backref{33}{Saeckel2025}{0}{39}{39}
\abx@aux@backref{34}{Saeckel2025}{0}{39}{39}
\abx@aux@backref{35}{Saeckel2025}{0}{39}{39}
\abx@aux@backref{36}{Saeckel2025}{0}{39}{39}
\abx@aux@backref{37}{Saeckel2025}{0}{39}{39}
\abx@aux@backref{38}{Saeckel2025}{0}{39}{39}
\abx@aux@backref{39}{Saeckel2025}{0}{39}{39}
\abx@aux@backref{40}{Saeckel2025}{0}{39}{39}
\abx@aux@backref{41}{Saeckel2025}{0}{39}{39}
\abx@aux@backref{42}{Saeckel2024}{0}{39}{39}
\@writefile{lot}{\contentsline {table}{\numberline {9.1}{\ignorespaces List of samples, introducing abbreviations and corresponding solvent concentrations and labelling. Abbreviations denote polymer type (\textbf {Lin}ear, \textbf {M}icro\textbf {G}el, polymer-\textbf {F}ree), \textbf {E}thanol and \textbf {W}ater concentrations (in \si {\volpercent }) and a subscript to indicate which isotope labelling was used for the water component. Thereby the shorthand notation also implicitly gives the labelling of ethanol (W\textsubscript {O} $\rightarrow $ ethanol-d\textsubscript {2}, W\textsubscript {D} $\rightarrow $ natural abundance ethanol). Samples prepared for experiments in the \SI {1}{\giga \hertz }-AEON spectrometer\xspace are marked with a star, e.g. \BayreuthSample [D]{00}. All polymer samples listed here contain \SI {4}{\wtpercent } polymer. Note that for neat \ensuremath {\mathrm {D_2O}}\xspace , data from literature \blx@tocontentsinit {0}\autocite {Hindman1971} was used. Note further that hydrogen exchange leads to a distribution of $^2$H between water and ethanol in samples such as \BulkSample [D]{30}, whereby it is to be expected that $\gtrsim \SI {90}{\percent }$ of $^2$H is located in water molecules.\relax }}{39}{table.caption.26}\protected@file@percent }
\abx@aux@backref{44}{Hindman1971}{0}{39}{39}
\newlabel{tab:list-of-samples}{{9.1}{39}{List of samples, introducing abbreviations and corresponding solvent concentrations and labelling. Abbreviations denote polymer type (\textbf {Lin}ear, \textbf {M}icro\textbf {G}el, polymer-\textbf {F}ree), \textbf {E}thanol and \textbf {W}ater concentrations (in \si {\volpercent }) and a subscript to indicate which isotope labelling was used for the water component. Thereby the shorthand notation also implicitly gives the labelling of ethanol (W\textsubscript {O} $\rightarrow $ ethanol-d\textsubscript {2}, W\textsubscript {D} $\rightarrow $ natural abundance ethanol). Samples prepared for experiments in the \AEON are marked with a star, e.g. \BayreuthSample [D]{00}. All polymer samples listed here contain \SI {4}{\wtpercent } polymer. Note that for neat \DTwoO , data from literature \autocite {Hindman1971} was used. Note further that hydrogen exchange leads to a distribution of $^2$H between water and ethanol in samples such as \BulkSample [D]{30}, whereby it is to be expected that $\gtrsim \SI {90}{\percent }$ of $^2$H is located in water molecules.\relax }{table.caption.26}{}}
\newlabel{tab:list-of-samples@cref}{{[table][1][9]9.1}{[1][38][]39}}
\BKM@entry{id=36,dest={706172742E32},srcline={1}}{436F6E636C7573696F6E}
\@writefile{toc}{\contentsline {part}{\numberline {II}Conclusion}{40}{part.2}\protected@file@percent }
\newlabel{sec:conclusion}{{II}{40}{Conclusion}{part.2}{}}
\newlabel{sec:conclusion@cref}{{[part][2][]II}{[1][40][]40}}
\BKM@entry{id=37,dest={706172742E33},srcline={1}}{417070656E646978}
\BKM@entry{id=38,dest={617070656E6469782E41},srcline={6}}{496E636C7564696E675C3034307468655C303430417070656E6469785C303430696E5C303430796F75725C3034304D61696E5C30343046696C65}
\BKM@entry{id=39,dest={617070656E6469782E42},srcline={15}}{52657573696E675C3034305C2850617274735C3034306F665C295C303430616E5C3034304571756174696F6E}
\@writefile{toc}{\contentsline {part}{\numberline {III}Appendix}{41}{part.3}\protected@file@percent }
\newlabel{sec:appendix}{{III}{41}{Appendix}{part.3}{}}
\newlabel{sec:appendix@cref}{{[part][3][2147483647]III}{[1][41][]41}}
\@writefile{toc}{\contentsline {chapter}{\numberline {A}Including the Appendix in your Main File}{41}{appendix.A}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\numberline {A}Including the Appendix in your Main File}{41}{appendix.A}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\numberline {A}Including the Appendix in your Main File}{41}{appendix.A}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\numberline {A}Including the Appendix in your Main File}{41}{appendix.A}\protected@file@percent }
\@writefile{toc}{\contentsline {chapter}{\numberline {B}Reusing (Parts of) an Equation}{41}{appendix.B}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\numberline {B}Reusing (Parts of) an Equation}{41}{appendix.B}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\numberline {B}Reusing (Parts of) an Equation}{41}{appendix.B}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\numberline {B}Reusing (Parts of) an Equation}{41}{appendix.B}\protected@file@percent }
\newlabel{sec:appdx_relaxation-specdens-sto}{{B}{41}{Reusing (Parts of) an Equation}{appendix.B}{}}
\newlabel{sec:appdx_relaxation-specdens-sto@cref}{{[appendix][2][2147483647]B}{[1][41][]41}}
\newlabel{eqs:autocorrelation-specdens}{{B.1}{41}{Appendix}{equation.B.0.1}{}}
\newlabel{eqs:autocorrelation-specdens@cref}{{[subequation][1][2147483647,2]B.1}{[1][41][]41}}
\newlabel{eq:autocorrelation}{{B.1a}{41}{Appendix}{equation.B.0.1}{}}
\newlabel{eq:autocorrelation@cref}{{[subequation][1][2147483647,2,1]B.1a}{[1][41][]41}}
\newlabel{eq:specdens_tilde}{{B.1b}{41}{Appendix}{equation.B.0.2}{}}
\newlabel{eq:specdens_tilde@cref}{{[subequation][2][2147483647,2,1]B.1b}{[1][41][]41}}
\BKM@entry{id=40,dest={636861707465722A2E3237},srcline={1}}{41636B6E6F776C656467656D656E7473}
\@writefile{toc}{\contentsline {chapter}{\nonumberline Acknowledgements}{42}{chapter*.27}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\nonumberline Acknowledgements}{42}{chapter*.27}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\nonumberline Acknowledgements}{42}{chapter*.27}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\nonumberline Acknowledgements}{42}{chapter*.27}\protected@file@percent }
\BKM@entry{id=41,dest={73656374696F6E2A2E3238},srcline={1}}{416262726576696174696F6E73}
\@writefile{toc}{\contentsline {chapter}{Abbreviations}{43}{section*.28}\protected@file@percent }
\BKM@entry{id=42,dest={73656374696F6E2A2E3330},srcline={102}}{4269626C696F677261706879}
\@writefile{toc}{\contentsline {chapter}{Bibliography}{44}{section*.30}\protected@file@percent }
\BKM@entry{id=43,dest={636861707465722A2E3332},srcline={14}}{41636164656D69635C3034304356}
\@writefile{toc}{\contentsline {chapter}{\nonumberline Academic CV}{47}{chapter*.32}\protected@file@percent }
\@writefile{lof}{\contentsline {chapteratlist}{\nonumberline Academic CV}{47}{chapter*.32}\protected@file@percent }
\@writefile{lot}{\contentsline {chapteratlist}{\nonumberline Academic CV}{47}{chapter*.32}\protected@file@percent }
\@writefile{lol}{\contentsline {chapteratlist}{\nonumberline Academic CV}{47}{chapter*.32}\protected@file@percent }
\providecommand*{\@gls@entry@count}[2]{}
\@gls@entry@count{CPMG}{3}
\@gls@entry@count{LCST}{7}
\@gls@entry@count{pNIPAM}{11}
\@gls@entry@count{TSUA}{1}
\@gls@entry@count{TMUSC}{3}
\@gls@entry@count{TSUC}{1}
\@gls@entry@count{athermal}{3}
\@gls@entry@count{complexation}{3}
\@gls@entry@count{Larmor frequency}{4}
\@gls@entry@count{spectral density}{2}
\@gls@entry@count{Tdem}{3}
\@gls@entry@count{Rh}{2}
\global\csname @altsecnumformattrue\endcsname
\abx@aux@read@bbl@mdfivesum{CFEFF55C48197F8B6D4CB931699152D5}
\abx@aux@defaultrefcontext{0}{Bischofberger2014}{anyt/global//global/global}
\abx@aux@defaultrefcontext{0}{Costa2002}{anyt/global//global/global}
\abx@aux@defaultrefcontext{0}{Carr1954}{anyt/global//global/global}
\abx@aux@defaultrefcontext{0}{Fujishige1989}{anyt/global//global/global}
\abx@aux@defaultrefcontext{0}{Gedde2019}{anyt/global//global/global}
\abx@aux@defaultrefcontext{0}{Halperin2015}{anyt/global//global/global}
\abx@aux@defaultrefcontext{0}{Hindman1971}{anyt/global//global/global}
\abx@aux@defaultrefcontext{0}{Korde2019}{anyt/global//global/global}
\abx@aux@defaultrefcontext{0}{Meiboom1958}{anyt/global//global/global}
\abx@aux@defaultrefcontext{0}{PubChem2005NIPAM}{anyt/global//global/global}
\abx@aux@defaultrefcontext{0}{Rubinstein2004}{anyt/global//global/global}
\abx@aux@defaultrefcontext{0}{Slichter1990}{anyt/global//global/global}
\abx@aux@defaultrefcontext{0}{Saeckel2024}{anyt/global//global/global}
\abx@aux@defaultrefcontext{0}{Saeckel2025}{anyt/global//global/global}
\abx@aux@defaultlabelprefix{0}{Bischofberger2014}{}
\abx@aux@defaultlabelprefix{0}{Costa2002}{}
\abx@aux@defaultlabelprefix{0}{Carr1954}{}
\abx@aux@defaultlabelprefix{0}{Fujishige1989}{}
\abx@aux@defaultlabelprefix{0}{Gedde2019}{}
\abx@aux@defaultlabelprefix{0}{Halperin2015}{}
\abx@aux@defaultlabelprefix{0}{Hindman1971}{}
\abx@aux@defaultlabelprefix{0}{Korde2019}{}
\abx@aux@defaultlabelprefix{0}{Meiboom1958}{}
\abx@aux@defaultlabelprefix{0}{PubChem2005NIPAM}{}
\abx@aux@defaultlabelprefix{0}{Rubinstein2004}{}
\abx@aux@defaultlabelprefix{0}{Slichter1990}{}
\abx@aux@defaultlabelprefix{0}{Saeckel2024}{}
\abx@aux@defaultlabelprefix{0}{Saeckel2025}{}
\global\@namedef{scr@dte@chapter@lastmaxnumwidth}{16.19429pt}
\global\@namedef{scr@dte@section@lastmaxnumwidth}{21.29514pt}
\global\@namedef{scr@dte@part@lastmaxnumwidth}{20.8948pt}
\global\@namedef{scr@dte@subsection@lastmaxnumwidth}{29.76517pt}
\@writefile{toc}{\providecommand\tocbasic@end@toc@file{}\tocbasic@end@toc@file}
\gdef \@abspage@last{55}

771
Diss_main.bbl Normal file
View File

@@ -0,0 +1,771 @@
% $ biblatex auxiliary file $
% $ biblatex bbl format version 3.2 $
% Do not modify the above lines!
%
% This is an auxiliary file used by the 'biblatex' package.
% This file may safely be deleted. It will be recreated as
% required.
%
\begingroup
\makeatletter
\@ifundefined{ver@biblatex.sty}
{\@latex@error
{Missing 'biblatex' package}
{The bibliography requires the 'biblatex' package.}
\aftergroup\endinput}
{}
\endgroup
\datalist[entry]{anyt/global//global/global}
\entry{Bischofberger2014}{article}{}
\name{author}{3}{}{%
{{hash=BI}{%
family={Bischofberger},
familyi={B\bibinitperiod},
given={I.},
giveni={I\bibinitperiod},
}}%
{{hash=CDCE}{%
family={Calzolari},
familyi={C\bibinitperiod},
given={D.\bibnamedelima C.\bibnamedelima E.},
giveni={D\bibinitperiod\bibinitdelim C\bibinitperiod\bibinitdelim
E\bibinitperiod},
}}%
{{hash=TV}{%
family={Trappe},
familyi={T\bibinitperiod},
given={V.},
giveni={V\bibinitperiod},
}}%
}
\list{publisher}{1}{%
{The Royal Society of Chemistry}%
}
\keyw{pNIPAM,linear,microgel,cononsolvency,methanol,ethanol,propanol,SLS,radius
of gyration,hydrodynamic radius,aqueous alcohol,excess enthalpy}
\strng{namehash}{BI+1}
\strng{fullhash}{BICDCETV1}
\field{labelnamesource}{author}
\field{labeltitlesource}{title}
\field{labelalpha}{Bis+14}
\field{sortinit}{B}
\field{sortinithash}{B}
\field{abstract}{%
We investigate the co-nonsolvency of poly-N-isopropyl acrylamide (PNiPAM)
in different water–alcohol mixtures and show that this phenomenon is due to
two distinct solvation contributions governing the phase behavior of PNiPAM
in the water-rich and alcohol-rich regime respectively. While hydrophobic
hydration is the predominant contribution governing the phase behavior of
PNiPAM in the water-rich regime{,} the mixing contributions governing the
phase behavior of classical polymer solutions determine the phase behavior of
PNiPAM in the alcohol-rich regime. This is evidenced by distinct scaling
relations denoting the energetic state of the aqueous medium as a key
parameter for the phase behavior of PNiPAM in the water-rich regime{,} while
the volume fractions of respectively water{,} alcohol and PNiPAM become
relevant parameters in the alcohol-rich regime. Adding alcohol to water
decreases the energetics of the aqueous medium{,} which gradually suppresses
hydrophobic hydration{,} while adding water to alcohol decreases the solvent
quality. Consequently{,} PNiPAM is insoluble in the intermediate range of
solvent composition{,} where neither hydrophobic hydration nor the mixing
contributions prevail. This accounts for the co-nonsolvency phenomenon
observed for PNiPAM in water–alcohol mixtures.%
}
\verb{doi}
\verb 10.1039/C4SM01345J
\endverb
\field{issue}{41}
\field{pages}{8288\bibrangedash 8295}
\field{title}{Co-nonsolvency of PNiPAM at the transition between solvation
mechanisms}
\verb{url}
\verb http://dx.doi.org/10.1039/C4SM01345J
\endverb
\field{volume}{10}
\verb{file}
\verb :Bischofberger2014 - Co Nonsolvency of PNiPAM at the Transition betwe
\verb en Solvation Mechanisms.pdf:PDF;:CononsolvencyOfPNIPAMAtTheTransition
\verb BetweenSolvationMechanisms-Corrections_BischofbergerEtAl_SoftMatter20
\verb 14.pdf:PDF
\endverb
\field{journaltitle}{Soft Matter}
\field{year}{2014}
\endentry
\entry{Costa2002}{article}{}
\name{author}{2}{}{%
{{hash=CROR}{%
family={Costa},
familyi={C\bibinitperiod},
given={Ricardo O.\bibnamedelima R.},
giveni={R\bibinitperiod\bibinitdelim O\bibinitperiod\bibinitdelim
R\bibinitperiod},
}}%
{{hash=FRFS}{%
family={Freitas},
familyi={F\bibinitperiod},
given={Roberto F.\bibnamedelima S.},
giveni={R\bibinitperiod\bibinitdelim F\bibinitperiod\bibinitdelim
S\bibinitperiod},
}}%
}
\keyw{Hydrophobic hydration, Lower critical solution temperature, LCST,
Thermoreversible hydrogel, thermosensitive, PNIPAM, aqueous alcohol, UCST,
cloud point, cononsolvency, chain length, hydrophobic hydration OR hydration
shell, hydrophobic hydration OR hydration shell OR hydration water,
hydrophobic hydration OR hydration shell OR hydration water OR clathrate}
\strng{namehash}{CRORFRFS1}
\strng{fullhash}{CRORFRFS1}
\field{labelnamesource}{author}
\field{labeltitlesource}{title}
\field{labelalpha}{CF02}
\field{sortinit}{C}
\field{sortinithash}{C}
\field{abstract}{%
In this work, the phase behavior of linear poly(N-isopropylacrylamide)
(PNIPA) in water--solvent mixtures was investigated. Several solvents,
including low molecular weight alcohols, were selected and phase separation
temperatures were determined through cloud point measurements. All the
studied systems exhibited the cononsolvency effect, i.e. lower PNIPA
compatibility within definite ranges of composition in water-rich mixtures.
However, it was first detected that the coexistence of phase separation
temperatures---a lower critical solution temperature (LCST) with an upper
critical solution temperature (UCST)---at higher solvent concentrations in
most systems, depend on the hydrophobic nature of the solvent. The change
from a LCST to a UCST was correlated with the competition between
polymer--water and polymer--solvent interactions mediated by compositional
factors. The effects produced by the different solvents tested were
qualitatively compared, considering aspects related to their particular
molecular structures, such as the potential to form hydrogen bonds and the
implications of the size and shape of non-polar groups for hydrophobic
hydration.%
}
\verb{doi}
\verb https://doi.org/10.1016/S0032-3861(02)00507-4
\endverb
\field{issn}{0032-3861}
\field{number}{22}
\field{pages}{5879\bibrangedash 5885}
\field{title}{Phase behavior of poly(N-iso\-propyl\-acryl\-amide) in binary
aqueous solutions}
\verb{url}
\verb https://www.sciencedirect.com/science/article/pii/S0032386102005074
\endverb
\field{volume}{43}
\verb{file}
\verb :Costa2002 - Phase Behavior of Poly(N Isopropylacrylamide) in Binary
\verb Aqueous Solutions.pdf:PDF
\endverb
\field{journaltitle}{Polymer}
\field{year}{2002}
\endentry
\entry{Carr1954}{article}{}
\name{author}{2}{}{%
{{hash=CHY}{%
family={Carr},
familyi={C\bibinitperiod},
given={H.\bibnamedelima Y.},
giveni={H\bibinitperiod\bibinitdelim Y\bibinitperiod},
}}%
{{hash=PEM}{%
family={Purcell},
familyi={P\bibinitperiod},
given={E.\bibnamedelima M.},
giveni={E\bibinitperiod\bibinitdelim M\bibinitperiod},
}}%
}
\list{publisher}{1}{%
{American Physical Society}%
}
\keyw{NMR, CPMG, Spin Echoes}
\strng{namehash}{CHYPEM1}
\strng{fullhash}{CHYPEM1}
\field{labelnamesource}{author}
\field{labeltitlesource}{title}
\field{labelalpha}{CP54}
\field{sortinit}{C}
\field{sortinithash}{C}
\verb{doi}
\verb 10.1103/PhysRev.94.630
\endverb
\field{issue}{3}
\field{pages}{630\bibrangedash 638}
\field{title}{Effects of Diffusion on Free Precession in Nuclear Magnetic
Resonance Experiments}
\verb{url}
\verb https://link.aps.org/doi/10.1103/PhysRev.94.630
\endverb
\field{volume}{94}
\verb{file}
\verb :Carr1954 - Effects of Diffusion on Free Precession in Nuclear Magnet
\verb ic Resonance Experiments.pdf:PDF
\endverb
\field{journaltitle}{Physical Review}
\field{month}{05}
\field{year}{1954}
\endentry
\entry{Fujishige1989}{article}{}
\name{author}{3}{}{%
{{hash=FS}{%
family={Fujishige},
familyi={F\bibinitperiod},
given={Shouei},
giveni={S\bibinitperiod},
}}%
{{hash=KK}{%
family={Kubota},
familyi={K\bibinitperiod},
given={K.},
giveni={K\bibinitperiod},
}}%
{{hash=AI}{%
family={Ando},
familyi={A\bibinitperiod},
given={I.},
giveni={I\bibinitperiod},
}}%
}
\keyw{PNIPAM, molecular weight, concentration-dependent, light scattering,
DLS, SLS, thermoresponsive}
\strng{namehash}{FS+1}
\strng{fullhash}{FSKKAI1}
\field{labelnamesource}{author}
\field{labeltitlesource}{title}
\field{labelalpha}{Fuj+89}
\field{sortinit}{F}
\field{sortinithash}{F}
\field{abstract}{%
When aqueous solutions of well-fractionated poly(N-isopropylacrylamide)
samples are heated, the polymer molecular dimensions change abruptly at a
critical temperature (~32{$^{\circ}$}C), followed by aggregation of
individual polymer chains dispersed in a state of globular particles to give
an optically detectable phase transition. The transition occurs independently
of either the molecular weight of the polymer (5x10^4 to 840x10^4) or its
concentration (0.01 to 1wt%). This behavior is reminiscent of the thermal
denaturation of proteins in aqueous medium.%
}
\verb{doi}
\verb 10.1021/j100345a085
\endverb
\verb{eprint}
\verb https://doi.org/10.1021/j100345a085
\endverb
\field{number}{8}
\field{pages}{3311\bibrangedash 3313}
\field{title}{Phase transition of aqueous solutions of
poly(N-isopropylacrylamide) and poly(N-isopropylmethacrylamide)}
\verb{url}
\verb https://doi.org/10.1021/j100345a085
\endverb
\field{volume}{93}
\verb{file}
\verb :Fujishige1989 - Phase Transition of Aqueous Solutions of Poly(N Isop
\verb ropylacrylamide) and Poly(N Isopropylmethacrylamide).pdf:PDF
\endverb
\field{journaltitle}{Journal of Physical Chemistry}
\field{year}{1989}
\endentry
\entry{Gedde2019}{book}{}
\name{author}{2}{}{%
{{hash=GUW}{%
family={Gedde},
familyi={G\bibinitperiod},
given={Ulf\bibnamedelima W.},
giveni={U\bibinitperiod\bibinitdelim W\bibinitperiod},
}}%
{{hash=HMS}{%
family={Hedenqvist},
familyi={H\bibinitperiod},
given={Mikael\bibnamedelima S.},
giveni={M\bibinitperiod\bibinitdelim S\bibinitperiod},
}}%
}
\list{publisher}{1}{%
{Springer Cham}%
}
\keyw{book, polymers}
\strng{namehash}{GUWHMS1}
\strng{fullhash}{GUWHMS1}
\field{labelnamesource}{author}
\field{labeltitlesource}{title}
\field{labelalpha}{GH19}
\field{sortinit}{G}
\field{sortinithash}{G}
\verb{doi}
\verb doi.org/10.1007/978-3-030-29794-7
\endverb
\field{edition}{2}
\field{isbn}{978-3-030-29794-7}
\field{series}{Graduate Texts in Physics}
\field{title}{Fundamental Polymer Science}
\verb{file}
\verb :Gedde2019 - Fundamental Polymer Science.pdf:PDF
\endverb
\field{year}{2019}
\endentry
\entry{Halperin2015}{article}{}
\name{author}{3}{}{%
{{hash=HA}{%
family={Halperin},
familyi={H\bibinitperiod},
given={Avraham},
giveni={A\bibinitperiod},
}}%
{{hash=KM}{%
family={Kr{\"{o}}ger},
familyi={K\bibinitperiod},
given={Martin},
giveni={M\bibinitperiod},
}}%
{{hash=WFM}{%
family={Winnik},
familyi={W\bibinitperiod},
given={Fran{\c{c}}oise\bibnamedelima M.},
giveni={F\bibinitperiod\bibinitdelim M\bibinitperiod},
}}%
}
\keyw{lower critical solution temperature, mesoglobules, metastability,
tacticity, type II phase behavior, PNIPAM, review}
\strng{namehash}{HA+1}
\strng{fullhash}{HAKMWFM1}
\field{labelnamesource}{author}
\field{labeltitlesource}{title}
\field{labelalpha}{Hal+15}
\field{sortinit}{H}
\field{sortinithash}{H}
\field{abstract}{%
In 1968, Heskins and Guillet published the first systematic study of the
phase diagram of poly(N-isopropylacrylamide) (PNIPAM), at the time a
{\textquotedblleft}young polymer{\textquotedblright} first synthesized in
1956. Since then, PNIPAM became the leading member of the growing families of
thermoresponsive polymers and of stimuli-responsive,
{\textquotedblleft}smart{\textquotedblright} polymers in general. Its thermal
response is unanimously attributed to its phase behavior. Yet, in spite of
50\hspace{0.25em}years of research, a coherent quantitative picture remains
elusive. In this Review we survey the reported phase diagrams, discuss the
differences and comment on theoretical ideas regarding their possible
origins. We aim to alert the PNIPAM community to open questions in this
reputably mature domain.%
}
\verb{doi}
\verb 10.1002/anie.201506663
\endverb
\verb{eprint}
\verb https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201506663
\endverb
\field{number}{51}
\field{pages}{15342\bibrangedash 15367}
\field{title}{Poly(N-isopropyl\-acrylamide) Phase Diagrams: Fifty Years of
Research}
\verb{url}
\verb https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201506663
\endverb
\field{volume}{54}
\verb{file}
\verb :Halperin2015 - Poly(N Isopropylacrylamide) Phase Diagrams_ Fifty Yea
\verb rs of Research.pdf:PDF
\endverb
\field{journaltitle}{Angewandte Chemie - International Edition}
\field{year}{2015}
\endentry
\entry{Hindman1971}{article}{}
\name{author}{4}{}{%
{{hash=HJC}{%
family={Hindman},
familyi={H\bibinitperiod},
given={J.\bibnamedelima C.},
giveni={J\bibinitperiod\bibinitdelim C\bibinitperiod},
}}%
{{hash=ZAJ}{%
family={Zielen},
familyi={Z\bibinitperiod},
given={A.\bibnamedelima J.},
giveni={A\bibinitperiod\bibinitdelim J\bibinitperiod},
}}%
{{hash=SA}{%
family={Svirmickas},
familyi={S\bibinitperiod},
given={A.},
giveni={A\bibinitperiod},
}}%
{{hash=WM}{%
family={Wood},
familyi={W\bibinitperiod},
given={M.},
giveni={M\bibinitperiod},
}}%
}
\keyw{2h-nmr,17o-nmr,water,d2o,h217o,t1,spin-lattice
relaxation,thermodynamics,entropy,enthalpy,SED,quadrupole coupling
constant,qcc,H2O,nmr}
\strng{namehash}{HJC+1}
\strng{fullhash}{HJCZAJSAWM1}
\field{labelnamesource}{author}
\field{labeltitlesource}{title}
\field{labelalpha}{Hin+71}
\field{sortinit}{H}
\field{sortinithash}{H}
\verb{doi}
\verb 10.1063/1.1674887
\endverb
\verb{eprint}
\verb https://doi.org/10.1063/1.1674887
\endverb
\field{number}{2}
\field{pages}{621\bibrangedash 634}
\field{title}{Relaxation Processes in Water. The Spin–Lattice Relaxation
of the Deuteron in D2O and Oxygen‐17 in H217O}
\verb{url}
\verb https://doi.org/10.1063/1.1674887
\endverb
\field{volume}{54}
\verb{file}
\verb :Hindman1971 - Relaxation Processes in Water. the Spin–Lattice Rela
\verb xation of the Deuteron in D2O and Oxygen‐17 in H217O.pdf:PDF
\endverb
\field{journaltitle}{The Journal of Chemical Physics}
\field{year}{1971}
\endentry
\entry{Korde2019}{article}{}
\name{author}{2}{}{%
{{hash=KJM}{%
family={Korde},
familyi={K\bibinitperiod},
given={Jay\bibnamedelima M.},
giveni={J\bibinitperiod\bibinitdelim M\bibinitperiod},
}}%
{{hash=KB}{%
family={Kandasubramanian},
familyi={K\bibinitperiod},
given={Balasubramanian},
giveni={B\bibinitperiod},
}}%
}
\keyw{review, application focused, drug delivery, smart interfaces,
application-focused}
\strng{namehash}{KJMKB1}
\strng{fullhash}{KJMKB1}
\field{labelnamesource}{author}
\field{labeltitlesource}{title}
\field{labelalpha}{KK19}
\field{sortinit}{K}
\field{sortinithash}{K}
\field{abstract}{%
Over the past few decades, reversible responsive polymer materials have
received interest conjointly from academia as well as industry owing to their
ability to adapt to the surrounding environment, change adhesion and
wettability of copious species upon extraneous stimulus, and regulate
transportation of molecules and ions. Stimuli-responsive polymers or
macromolecules also exhibit the ability to convert biochemical and chemical
signals into mechanical, thermal, optical, and electrical signals, and vice
versa, for which they are utilized in an array of applications like
{\textquotedblleft}smart{\textquotedblright} optical systems, drug delivery,
diagnostics, and tissue engineering, in conjunction with coatings, textiles,
biosensors, and microelectromechanical systems. Extensive exploration on
reversible responsive polymeric systems for a variety of engineering
functionalities has been done; however, no collection of all the information
is available as such. This Review consolidates profuse studies of reversible
responsive polymers utilized in an assorted array of functions, inclusive of
sensors, drug delivery, smart and self-healing coatings, etc.%
}
\verb{doi}
\verb 10.1021/acs.iecr.9b00683
\endverb
\verb{eprint}
\verb https://doi.org/10.1021/acs.iecr.9b00683
\endverb
\field{number}{23}
\field{pages}{9709\bibrangedash 9757}
\field{title}{Fundamentals and Effects of Biomimicking Stimuli-Responsive
Polymers for Engineering Functions}
\verb{url}
\verb https://doi.org/10.1021/acs.iecr.9b00683
\endverb
\field{volume}{58}
\verb{file}
\verb :Korde2019 - Fundamentals and Effects of Biomimicking Stimuli Respons
\verb ive Polymers for Engineering Functions.pdf:PDF;:FundamentalsAndEffect
\verb sOfBiomimickingStimuliResponsivePolymersForEngineeringFunctions-Corre
\verb ction_KordeEtAl_IndustrEngineerChemistryResearch2020.pdf:PDF
\endverb
\field{journaltitle}{Industrial and Engineering Chemistry Research}
\field{year}{2019}
\endentry
\entry{Meiboom1958}{article}{}
\name{author}{2}{}{%
{{hash=MS}{%
family={Meiboom},
familyi={M\bibinitperiod},
given={S.},
giveni={S\bibinitperiod},
}}%
{{hash=GD}{%
family={Gill},
familyi={G\bibinitperiod},
given={D.},
giveni={D\bibinitperiod},
}}%
}
\keyw{NMR, CPMG, Spin Echoes}
\strng{namehash}{MSGD1}
\strng{fullhash}{MSGD1}
\field{labelnamesource}{author}
\field{labeltitlesource}{title}
\field{labelalpha}{MG58}
\field{sortinit}{M}
\field{sortinithash}{M}
\verb{doi}
\verb 10.1063/1.1716296
\endverb
\verb{eprint}
\verb https://doi.org/10.1063/1.1716296
\endverb
\field{number}{8}
\field{pages}{688\bibrangedash 691}
\field{title}{Modified Spin-Echo Method for Measuring Nuclear Relaxation
Times}
\verb{url}
\verb https://doi.org/10.1063/1.1716296
\endverb
\field{volume}{29}
\field{journaltitle}{Review of Scientific Instruments}
\field{year}{1958}
\endentry
\entry{PubChem2005NIPAM}{misc}{}
\keyw{synthesis,molecular weights,NIPPA}
\field{labelalpha}{Pub}
\field{sortinit}{P}
\field{sortinithash}{P}
\verb{url}
\verb https://pubchem.ncbi.nlm.nih.gov/compound/Propanamide_-N-isopropyl
\endverb
\field{urlday}{11}
\field{urlmonth}{11}
\field{urlyear}{2024}
\endentry
\entry{Rubinstein2004}{book}{}
\name{author}{2}{}{%
{{hash=RM}{%
family={Rubinstein},
familyi={R\bibinitperiod},
given={Michael},
giveni={M\bibinitperiod},
}}%
{{hash=CRH}{%
family={Colby},
familyi={C\bibinitperiod},
given={Ralph\bibnamedelima H.},
giveni={R\bibinitperiod\bibinitdelim H\bibinitperiod},
}}%
}
\list{publisher}{1}{%
{Oxford University Press}%
}
\strng{namehash}{RMCRH1}
\strng{fullhash}{RMCRH1}
\field{labelnamesource}{author}
\field{labeltitlesource}{title}
\field{labelalpha}{RC04}
\field{sortinit}{R}
\field{sortinithash}{R}
\field{isbn}{019852059x}
\field{title}{Polymer Physics}
\field{year}{2004}
\endentry
\entry{Slichter1990}{book}{}
\name{author}{1}{}{%
{{hash=SCP}{%
family={Slichter},
familyi={S\bibinitperiod},
given={Charles\bibnamedelima P.},
giveni={C\bibinitperiod\bibinitdelim P\bibinitperiod},
}}%
}
\name{editor}{1}{}{%
{{hash=LHKV}{%
family={Lotsch},
familyi={L\bibinitperiod},
given={Helmut K.\bibnamedelima V.},
giveni={H\bibinitperiod\bibinitdelim K\bibinitperiod\bibinitdelim
V\bibinitperiod},
}}%
}
\list{publisher}{1}{%
{Springer Berlin-Heidelberg}%
}
\keyw{NMR,theory,book}
\strng{namehash}{SCP1}
\strng{fullhash}{SCP1}
\field{labelnamesource}{author}
\field{labeltitlesource}{title}
\field{labelalpha}{Sli90}
\field{sortinit}{S}
\field{sortinithash}{S}
\verb{doi}
\verb 10.1007/978-3-662-09441-9
\endverb
\field{edition}{Third}
\field{isbn}{978-3-662-09441-9}
\field{series}{Springer series in solid-state sciences}
\field{title}{Principles of Magnetic Resonance}
\verb{file}
\verb :Slichter1963 - Principles of Magnetic Resonance_ with Examples from
\verb Solid State Physics.pdf:PDF
\endverb
\field{year}{1990}
\endentry
\entry{Saeckel2024}{article}{}
\name{author}{5}{}{%
{{hash=SC}{%
family={Säckel},
familyi={S\bibinitperiod},
given={Christoph},
giveni={C\bibinitperiod},
}}%
{{hash=vKR}{%
prefix={von},
prefixi={v\bibinitperiod},
family={Klitzing},
familyi={K\bibinitperiod},
given={Regine},
giveni={R\bibinitperiod},
}}%
{{hash=SR}{%
family={Siegel},
familyi={S\bibinitperiod},
given={Renée},
giveni={R\bibinitperiod},
}}%
{{hash=SJ}{%
family={Senker},
familyi={S\bibinitperiod},
given={Jürgen},
giveni={J\bibinitperiod},
}}%
{{hash=VM}{%
family={Vogel},
familyi={V\bibinitperiod},
given={Michael},
giveni={M\bibinitperiod},
}}%
}
\keyw{NMR,pNIPAM,2H-NMR,spin-lattice relaxation,T1,spin-spin
relaxation,D2O,spectral density,field cycling,confinement,lcst}
\strng{namehash}{SC+1}
\strng{fullhash}{SCKRvSRSJVM1}
\field{labelnamesource}{author}
\field{labeltitlesource}{title}
\field{labelalpha}{Sä+24}
\field{sortinit}{S}
\field{sortinithash}{S}
\field{abstract}{%
We use <sup>2</sup>H nuclear magnetic resonance to study the dynamics of
deuterated water in a solution of linear poly (N-isopropyl acrylamide)
(pNIPAM, 4 wt%) across its coil-to-globule transition at a lower critical
solubility temperature (LCST) around 32°C. In agreement with previous
studies, we find that the <sup>2</sup>H spin-lattice (T<sub>1</sub>) and, in
particular, spin-spin (T<sub>2</sub>) relaxation times abruptly decrease when
heating through the LCST, indicating that the polymer collapse causes an
emergence of a water fraction with strongly reduced mobility. To quantify the
dynamics of this slow water fraction, we exploit the fact that <sup>2</sup>H
field-cycling relaxometry allows us to measure the spectral density of the
water reorientation in a broad frequency range. We find that the slow water
fraction is characterised by a broad logarithmic Gaussian distribution of
correlation times (σ<sub>LG</sub> = 2.3), which is centred about
τ<sub>LG</sub> ≈ 10<sup>–9</sup> s near the LCST. Hence, the common
assumption of a Debye spectral density does not apply. We argue that a minor
water fraction, which is located inside the pNIPAM globules and shows
dynamics governed by the disordered polymer matrix, accompanies a major water
fraction with bulk-like dynamics above the LCST. The former fraction amounts
to about 0.4 water molecules per NIPAM monomer. Several findings indicate
fast exchange between these bound and free water fractions on the
T<sub>1</sub> and T<sub>2</sub> time scales.%
}
\verb{doi}
\verb 10.3389/frsfm.2024.1379816
\endverb
\field{issn}{2813-0499}
\field{title}{Water dynamics in solutions of linear poly (N-isopropyl
acrylamide) studied by 2H NMR field-cycling relaxometry}
\verb{url}
\verb https://www.frontiersin.org/articles/10.3389/frsfm.2024.1379816
\endverb
\field{volume}{4}
\verb{file}
\verb :Saeckel2024 - Water Dynamics in Solutions of Linear Poly (N Isopropy
\verb l Acrylamide) Studied by 2H NMR Field Cycling Relaxometry.pdf:PDF;:Fr
\verb ontiers_2024_Jan_Published-2024-03-21-SI.PDF:PDF
\endverb
\field{journaltitle}{Frontiers in Soft Matter}
\field{year}{2024}
\endentry
\entry{Saeckel2025}{article}{}
\name{author}{3}{}{%
{{hash=SC}{%
family={Säckel},
familyi={S\bibinitperiod},
given={Christoph},
giveni={C\bibinitperiod},
}}%
{{hash=vKR}{%
prefix={von},
prefixi={v\bibinitperiod},
family={Klitzing},
familyi={K\bibinitperiod},
given={Regine},
giveni={R\bibinitperiod},
}}%
{{hash=VM}{%
family={Vogel},
familyi={V\bibinitperiod},
given={Michael},
giveni={M\bibinitperiod},
}}%
}
\list{publisher}{1}{%
{The Royal Society of Chemistry}%
}
\keyw{NMR,pNIPAM,2H-NMR,spin-lattice relaxation,T1,spin-spin
relaxation,D2O,cononsolvency,field cycling,confinement,aqueous
alcohol,ethanol,h217o,T2,lcst,ucst}
\strng{namehash}{SC+1}
\strng{fullhash}{SCKRvVM1}
\field{labelnamesource}{author}
\field{labeltitlesource}{title}
\field{labelalpha}{Sä+25}
\field{sortinit}{S}
\field{sortinithash}{S}
\verb{doi}
\verb 10.1039/d5sm00055f
\endverb
\field{title}{$^2$H and$^{17}$O NMR studies of solvent dynamics related to
the cononsolvency of poly(N-isopropyl acrylamide) in ethanol-water mixtures}
\verb{url}
\verb http://dx.doi.org/10.1039/D5SM00055F
\endverb
\verb{file}
\verb :/autohome/saeckech/Promotion/Papers/2024_Cononsolvency/Published/2HA
\verb nd17ONMRStudiesOfSolventDynamicsRelatedToTheCononsolvencyOfPolyNIsopr
\verb opylacrylamideInEthanolWaterMixtures_SaeckelEtAl_SoftMatter2025.pdf:P
\verb DF;:/autohome/saeckech/Promotion/Papers/2024_Cononsolvency/Published/
\verb 2HAnd17ONMRStudiesOfSolventDynamicsRelatedToTheCononsolvencyOfPolyNIs
\verb opropylacrylamideInEthanolWaterMixtures_SaeckelEtAl_SoftMatter2025_SI
\verb .pdf:PDF
\endverb
\field{journaltitle}{Soft Matter}
\field{year}{2025}
\endentry
\enddatalist
\endinput

65
Diss_main.blg Normal file
View File

@@ -0,0 +1,65 @@
This is BibTeX, Version 0.99d (TeX Live 2022/Debian)
Capacity: max_strings=200000, hash_size=200000, hash_prime=170003
The top-level auxiliary file: Diss_main.aux
The style file: biblatex.bst
Reallocated glb_str_ptr (elt_size=4) to 20 items from 10.
Reallocated global_strs (elt_size=200001) to 20 items from 10.
Reallocated glb_str_end (elt_size=4) to 20 items from 10.
Reallocated singl_function (elt_size=4) to 100 items from 50.
Reallocated singl_function (elt_size=4) to 100 items from 50.
Reallocated singl_function (elt_size=4) to 100 items from 50.
Reallocated wiz_functions (elt_size=4) to 6000 items from 3000.
Reallocated singl_function (elt_size=4) to 100 items from 50.
Reallocated singl_function (elt_size=4) to 100 items from 50.
Reallocated singl_function (elt_size=4) to 100 items from 50.
Reallocated singl_function (elt_size=4) to 100 items from 50.
Reallocated singl_function (elt_size=4) to 100 items from 50.
Reallocated singl_function (elt_size=4) to 100 items from 50.
Reallocated singl_function (elt_size=4) to 100 items from 50.
Reallocated singl_function (elt_size=4) to 100 items from 50.
Database file #1: Diss_main-blx.bib
Database file #2: Promotion_Literatur.bib
Biblatex version: 3.18
Reallocated wiz_functions (elt_size=4) to 9000 items from 6000.
Reallocated singl_function (elt_size=4) to 100 items from 50.
You've used 15 entries,
6399 wiz_defined-function locations,
1363 strings with 22069 characters,
and the built_in function-call counts, 133792 in all, are:
= -- 10663
> -- 2096
< -- 669
+ -- 3666
- -- 1057
* -- 10384
:= -- 14925
add.period$ -- 0
call.type$ -- 15
change.case$ -- 333
chr.to.int$ -- 76
cite$ -- 30
duplicate$ -- 12826
empty$ -- 11823
format.name$ -- 1027
if$ -- 27206
int.to.chr$ -- 0
int.to.str$ -- 35
missing$ -- 0
newline$ -- 658
num.names$ -- 755
pop$ -- 5084
preamble$ -- 1
purify$ -- 405
quote$ -- 0
skip$ -- 3031
stack$ -- 0
substring$ -- 20872
swap$ -- 2730
text.length$ -- 527
text.prefix$ -- 21
top$ -- 1
type$ -- 498
warning$ -- 0
while$ -- 1734
width$ -- 0
write$ -- 644

21
Diss_main.glignored Normal file
View File

@@ -0,0 +1,21 @@
\glossarysection[\glossarytoctitle]{\glossarytitle}\glossarypreamble
\begin{theglossary}\glossaryheader
\glsgroupheading{A}\relax \glsresetentrylist %
\glossentry{athermal}{\glossaryentrynumbers{\relax
\setentrycounter[]{page}\glsnumberformat{14}\delimN
\setentrycounter[]{page}\glsnumberformat{40}}}\glsgroupskip
\glsgroupheading{C}\relax \glsresetentrylist %
\glossentry{complexation}{\glossaryentrynumbers{\relax
\setentrycounter[]{page}\glsnumberformat{14}}}\glsgroupskip
\glsgroupheading{D}\relax \glsresetentrylist %
\glossentry{Tdem}{\glossaryentrynumbers{\relax
\setentrycounter[]{page}\glsnumberformat{35}\delimN
\setentrycounter[]{page}\glsnumberformat{37}}}\glsgroupskip
\glsgroupheading{L}\relax \glsresetentrylist %
\glossentry{Larmor frequency}{\glossaryentrynumbers{\relax
\setentrycounter[]{page}\glsnumberformat{12}\delimN
\setentrycounter[]{page}\glsnumberformat{19}}}\glsgroupskip
\glsgroupheading{S}\relax \glsresetentrylist %
\glossentry{spectral density}{\glossaryentrynumbers{\relax
\setentrycounter[]{page}\glsnumberformat{13}}}%
\end{theglossary}\glossarypostamble

14
Diss_main.glignoredin Normal file
View File

@@ -0,0 +1,14 @@
\glossaryentry{Larmor frequency?\glossentry{Larmor frequency}|setentrycounter[]{page}"\glsnumberformat}{12}
\glossaryentry{Larmor frequency?\glossentry{Larmor frequency}|setentrycounter[]{page}"\glsnumberformat}{12}
\glossaryentry{spectral density?\glossentry{spectral density}|setentrycounter[]{page}"\glsnumberformat}{13}
\glossaryentry{spectral density?\glossentry{spectral density}|setentrycounter[]{page}"\glsnumberformat}{13}
\glossaryentry{athermal?\glossentry{athermal}|setentrycounter[]{page}"\glsnumberformat}{14}
\glossaryentry{athermal?\glossentry{athermal}|setentrycounter[]{page}"\glsnumberformat}{14}
\glossaryentry{complexation?\glossentry{complexation}|setentrycounter[]{page}"\glsnumberformat}{14}
\glossaryentry{complexation?\glossentry{complexation}|setentrycounter[]{page}"\glsnumberformat}{14}
\glossaryentry{complexation?\glossentry{complexation}|setentrycounter[]{page}"\glsnumberformat}{14}
\glossaryentry{Larmor frequency?\glossentry{Larmor frequency}|setentrycounter[]{page}"\glsnumberformat}{19}
\glossaryentry{demixing temperature?\glossentry{Tdem}|setentrycounter[]{page}"\glsnumberformat}{35}
\glossaryentry{demixing temperature?\glossentry{Tdem}|setentrycounter[]{page}"\glsnumberformat}{37}
\glossaryentry{demixing temperature?\glossentry{Tdem}|setentrycounter[]{page}"\glsnumberformat}{37}
\glossaryentry{athermal?\glossentry{athermal}|setentrycounter[]{page}"\glsnumberformat}{40}

7
Diss_main.glignoredl Normal file
View File

@@ -0,0 +1,7 @@
This is makeindex, version 2.16 [TeX Live 2022] (kpathsea + Thai support).
Scanning style file ./Diss_main.ist...........................done (27 attributes redefined, 0 ignored).
Scanning input file Diss_main.glignoredin....done (14 entries accepted, 0 rejected).
Sorting entries....done (68 comparisons).
Generating output file Diss_main.glignored....done (21 lines written, 0 warnings).
Output written in Diss_main.glignored.
Transcript written in Diss_main.glignoredl.

6
Diss_main.glunignored Normal file
View File

@@ -0,0 +1,6 @@
\glossarysection[\glossarytoctitle]{\glossarytitle}\glossarypreamble
\begin{theglossary}\glossaryheader
\glsgroupheading{H}\relax \glsresetentrylist %
\glossentry{Rh}{\glossaryentrynumbers{\relax
\setentrycounter[]{page}\glsnumberformat{12}}}%
\end{theglossary}\glossarypostamble

2
Diss_main.glunignoredin Normal file
View File

@@ -0,0 +1,2 @@
\glossaryentry{hydrodynamic radius?\glossentry{Rh}|setentrycounter[]{page}"\glsnumberformat}{12}
\glossaryentry{hydrodynamic radius?\glossentry{Rh}|setentrycounter[]{page}"\glsnumberformat}{12}

7
Diss_main.glunignoredl Normal file
View File

@@ -0,0 +1,7 @@
This is makeindex, version 2.16 [TeX Live 2022] (kpathsea + Thai support).
Scanning style file ./Diss_main.ist...........................done (27 attributes redefined, 0 ignored).
Scanning input file Diss_main.glunignoredin....done (2 entries accepted, 0 rejected).
Sorting entries....done (2 comparisons).
Generating output file Diss_main.glunignored....done (6 lines written, 0 warnings).
Output written in Diss_main.glunignored.
Transcript written in Diss_main.glunignoredl.

29
Diss_main.ist Normal file
View File

@@ -0,0 +1,29 @@
% makeindex style file created by the glossaries package
% for document 'Diss_main' on 2025-9-26
actual '?'
encap '|'
level '!'
quote '"'
keyword "\\glossaryentry"
preamble "\\glossarysection[\\glossarytoctitle]{\\glossarytitle}\\glossarypreamble\n\\begin{theglossary}\\glossaryheader\n"
postamble "\%\n\\end{theglossary}\\glossarypostamble\n"
group_skip "\\glsgroupskip\n"
item_0 "\%\n"
item_1 "\%\n"
item_2 "\%\n"
item_01 "\%\n"
item_x1 "\\relax \\glsresetentrylist\n"
item_12 "\%\n"
item_x2 "\\relax \\glsresetentrylist\n"
delim_0 "\{\\glossaryentrynumbers\{\\relax "
delim_1 "\{\\glossaryentrynumbers\{\\relax "
delim_2 "\{\\glossaryentrynumbers\{\\relax "
delim_t "\}\}"
delim_n "\\delimN "
delim_r "\\delimR "
headings_flag 1
heading_prefix "\\glsgroupheading\{"
heading_suffix "\}\\relax \\glsresetentrylist "
symhead_positive "glssymbols"
numhead_positive "glsnumbers"
page_compositor "."

2750
Diss_main.log Normal file
View File

File diff suppressed because it is too large Load Diff

0
Diss_main.out Normal file
View File

BIN
Diss_main.pdf Normal file
View File

Binary file not shown.

96
Diss_main.run.xml Normal file
View File

@@ -0,0 +1,96 @@
<?xml version="1.0" standalone="yes"?>
<!-- logreq request file -->
<!-- logreq version 1.0 / dtd version 1.0 -->
<!-- Do not edit this file! -->
<!DOCTYPE requests [
<!ELEMENT requests (internal | external)*>
<!ELEMENT internal (generic, (provides | requires)*)>
<!ELEMENT external (generic, cmdline?, input?, output?, (provides | requires)*)>
<!ELEMENT cmdline (binary, (option | infile | outfile)*)>
<!ELEMENT input (file)+>
<!ELEMENT output (file)+>
<!ELEMENT provides (file)+>
<!ELEMENT requires (file)+>
<!ELEMENT generic (#PCDATA)>
<!ELEMENT binary (#PCDATA)>
<!ELEMENT option (#PCDATA)>
<!ELEMENT infile (#PCDATA)>
<!ELEMENT outfile (#PCDATA)>
<!ELEMENT file (#PCDATA)>
<!ATTLIST requests
version CDATA #REQUIRED
>
<!ATTLIST internal
package CDATA #REQUIRED
priority (9) #REQUIRED
active (0 | 1) #REQUIRED
>
<!ATTLIST external
package CDATA #REQUIRED
priority (1 | 2 | 3 | 4 | 5 | 6 | 7 | 8) #REQUIRED
active (0 | 1) #REQUIRED
>
<!ATTLIST provides
type (static | dynamic | editable) #REQUIRED
>
<!ATTLIST requires
type (static | dynamic | editable) #REQUIRED
>
<!ATTLIST file
type CDATA #IMPLIED
>
]>
<requests version="1.0">
<internal package="biblatex" priority="9" active="0">
<generic>latex</generic>
<provides type="dynamic">
<file>Diss_main.aux</file>
<file>Diss_main-blx.bib</file>
</provides>
<requires type="dynamic">
<file>Diss_main.bbl</file>
</requires>
<requires type="static">
<file>blx-dm.def</file>
<file>blx-compat.def</file>
<file>blx-bibtex.def</file>
<file>biblatex.def</file>
<file>blx-natbib.def</file>
<file>standard.bbx</file>
<file>alphabetic.bbx</file>
<file>alphabetic.cbx</file>
<file>biblatex.cfg</file>
<file>english.lbx</file>
<file>british.lbx</file>
<file>german.lbx</file>
<file>ngerman.lbx</file>
</requires>
</internal>
<external package="biblatex" priority="5" active="0">
<generic>bibtex</generic>
<cmdline>
<binary>bibtex</binary>
<option>-min-crossrefs 2</option>
<infile>Diss_main</infile>
</cmdline>
<input>
<file>Diss_main.aux</file>
</input>
<output>
<file>Diss_main.bbl</file>
</output>
<provides type="dynamic">
<file>Diss_main.bbl</file>
</provides>
<requires type="dynamic">
<file>Diss_main.aux</file>
<file>Diss_main-blx.bib</file>
</requires>
<requires type="editable">
<file>Promotion_Literatur.bib</file>
</requires>
<requires type="static">
<file>biblatex.bst</file>
</requires>
</external>
</requests>

BIN
Diss_main.synctex.gz Normal file
View File

Binary file not shown.

110
Diss_main.tex Normal file
View File

@@ -0,0 +1,110 @@
%Latex template based on my (Christoph Säckel, 2025) dissertation. Hope it helps, but no guarantees. Took initial advise on LaTeX structure from http://alexanderfabisch.github.io/latex-for-dissertations.html (2023-03-22)
\documentclass[
draft=false,
paper=a4,
paper=portrait,
pagesize=auto,
fontsize=11pt,
version=last,
headings=onelinechapter,%twolinechapter=chapter-number\\chapter-title
open=any,% start parts and chapters on both even and odd pages
listof=totoc,
listof=chapterentry]
{scrbook}
\usepackage{scrhack}%"fixes some common problems"
\usepackage[a-1b]{pdfx}%pdfa format because it is required. images in the pdf format may cause errors
\DeclareUnicodeCharacter{2009}{\,}%helps compile bibliography if some authors/journals use thin spaces in cited fields
\DeclareUnicodeCharacter{0398}{$\theta$}%helps compile bibliography if some authors/journals use the theta temperature in cited fields
\DeclareUnicodeCharacter{2212}{-}%glossary acronyms of chemicals (maybe caused by apostrophies?) throw error otherwise
%\DeclareUnicodeCharacter{030A}{°}%helps compile bibliography if some (scandinavian) authors/journals use 'combining ring above' in cited fields.
\input{Diss_OrdinaryPackages.tex}%collects normal packages, does not include packages which require a lot of extra attention e.g. the bibliography package
\input{Diss_ConvenienceCommands.tex}%defines commands I found useful: Shorthands, macros to keep options for future typesetting, global variables for figure size or to show/hide comments etc
\input{Diss_Hyphenation.tex}%latex did not do too well with hyphenation (babel, british english). When a weird hyphen was spotted on a linebreak, I specified hyphenation for that word here.
\input{Diss_Glossary.tex}%Handles that e.g. acronyms are spelled out and have their abbreviation introduced (by default) only on their first occurrence, even if you later rearrange sections of your document. Glossaries are a lot of work to set up, but in the end I think it was worth it. This tex file also defines some custom commands and structures I found useful, e.g. to manually treat an acronym as if it was its first occurrence, which I used in the conclusion in case a reader did not read anything else.
\input{Diss_Bibliography}%Handles references. Tex file shows which package options I used.
%Chapters you do not currently work on need not be re-compiled to see changes in the chapter you are currently editing. This can save a lot of compiling time, however, I did not get it to work. But I also didn't try too hard, so feel free to give it a try. Instead of \input{chapter.tex}, you should then use \include{chapter.tex}. Note that \include creates a pagebreak by default
%\includeonly{
% Diss_OrdinaryPackages.tex,
% Diss_ConvenienceCommands,
% Diss_Glossary.tex,
% Diss_Bibliography,
% Diss_titlepages.tex,
% Diss_Abstract,
% Diss_Introduction.tex,
% Diss_Theory.tex,
% Diss_ExperimentalDetails.tex,
% Diss_ResultsDiscussion.tex,
% Diss_SideProjects.tex,
% %Diss_Conclusion.tex,
% %Diss_Appendix.tex,
% Diss_Acknowledgements.tex
%}
%\listfiles%makes it easier to find package versions in the log file. See https://tex.stackexchange.com/questions/13304/which-package-version-am-i-using
\begin{document}
\frontmatter
\input{Diss_titlepages.tex}%fulfills formal requirements from the university/department
\input{Diss_Abstract.tex}
\renewcommand{\contentsname}{Table of Contents}%rename the table of contents (default name 'Contents')
\setuptoc{toc}{totoc}%adds the table of contents to the table of contents and to the selectable sections in a pdf viewer.
%reduce upper margin for table of contents, because otherwise it currently happens to create a new page for the single last entry
%https://tex.stackexchange.com/questions/62125/how-to-remove-top-margin-above-tableofcontents
\begingroup
\makeatletter
% Redefine the \chapter* header macro [on which table of contents is based in most cases] to remove vertical space
\def\@makeschapterhead#1{%
%\vspace*{50\p@}% Remove the vertical space
{\parindent \z@ \raggedright
\normalfont
\interlinepenalty\@M
\Huge \bfseries #1\par\nobreak
\vskip 40\p@
}}
\makeatother
\tableofcontents
\endgroup%reinstate normal chapter heading spacing
\mainmatter
%
%Split dissertation in separate parts for a better overview, possibly also to keep compiling times reasonable if you get \includeonly to work. Assemble the separate .tex files with the commands \input{samplechapter.tex} (same as copy-pasting the contents) and/or \include{samplechapter.tex} (creates a pagebreak before including the file) %you can put \includeonly{mychapter, mychapter2} in the preamble to only compile a selected subset of all chapters. It does supposedly not mess up the references (e.g., table of contents, bibliography, and glossary) while keeping compiling times short.
\input{Diss_Introduction.tex}
\input{Diss_Theory.tex}
\input{Diss_ExperimentalDetails.tex}
% \input{Diss_ResultsDiscussion.tex}
\input{Diss_Conclusion.tex}
\appendix%signals some commonly reasonable changes, e.g. a change in chapter numbering from arabic to alphabetic
\input{Diss_Appendix.tex}%information which is nice to have, but not essential to follow the arguments in the main text
\backmatter%disables chapter numbering
\clearpage
\input{Diss_Acknowledgements}%say thank you
\printglossary[type=acronym,title=Abbreviations,toctitle=Abbreviations]
%\printglossaries \todo[color=red]{ensure that ignored glossary does not show up in appendix and TOC}
%currently decided against lists of figures and tables. commands appear to work properly though, feel free to un-comment.
%\listoffigures
%\listoftables
\clearpage%https://tex.stackexchange.com/questions/8458/making-the-bibliography-appear-in-the-table-of-contents
\phantomsection%https://tex.stackexchange.com/questions/60556/link-to-bibliography-in-the-toc-fails
\addcontentsline{toc}{chapter}{\bibname}%{Bibliography}%needs manual adjustment of Bibliography title and TOC entry
% \begingroup%disable the clearpage command, to avoid a pagebreak between bibliography title and entries when switching to twocolumn layout
% \renewcommand{\cleardoublepage}{}%only necessary if the openright option is used. Otherwise only acting on \clearpage is sufficient, but keeping \cleardoublepage does no harm.
% \renewcommand{\clearpage}{}
\printbibliography%[title=References]%\printbibliography[heading=none]
% \endgroup
\input{Diss_AcademicCV.tex}%formal requirement from the university/department to have this
\end{document}

54
Diss_main.toc Normal file
View File

@@ -0,0 +1,54 @@
\babel@toc {british}{}\relax
\babel@toc {ngerman}{}\relax
\contentsline {chapter}{\nonumberline Zusammenfassung}{iv}{chapter*.1}%
\babel@toc {british}{}\relax
\contentsline {chapter}{\nonumberline Abstract}{iv}{chapter*.2}%
\contentsline {chapter}{\nonumberline Table of Contents}{vi}{chapter*.3}%
\contentsline {part}{\numberline {I}Parts Only Serve Demonstration Purposes Here}{1}{part.1}%
\contentsline {chapter}{\numberline {1}Spacing}{1}{chapter.1}%
\contentsline {section}{\numberline {1.1}Special Spacing for The First Chapter in a Given Part}{1}{section.1.1}%
\contentsline {section}{\numberline {1.2}Margins}{1}{section.1.2}%
\contentsline {chapter}{\numberline {2}References with \textbackslash cref}{5}{chapter.2}%
\contentsline {section}{\numberline {2.1}Simple Uses of \textbackslash cref}{5}{section.2.1}%
\contentsline {section}{\numberline {2.2}Highlighting References}{5}{section.2.2}%
\contentsline {section}{\numberline {2.3}Advanced Uses of \textbackslash cref}{6}{section.2.3}%
\contentsline {chapter}{\numberline {3}Citations}{8}{chapter.3}%
\contentsline {chapter}{\numberline {4}Glossary}{12}{chapter.4}%
\contentsline {section}{\numberline {4.1}Special Cases Depending on Acronym Occurrence Counts}{14}{section.4.1}%
\contentsline {subsection}{\numberline {4.1.1}Extra Special Cases Depending on Acronym Occurrence Counts}{15}{subsection.4.1.1}%
\contentsline {chapter}{\numberline {5}Macros}{16}{chapter.5}%
\contentsline {section}{\numberline {5.1}Typesetting}{17}{section.5.1}%
\contentsline {subsection}{\numberline {5.1.1}Actual Notes on Typesetting}{17}{subsection.5.1.1}%
\contentsline {subsubsection}{\nonumberline Indices}{17}{subsubsection*.5}%
\contentsline {subsubsection}{\nonumberline Units}{17}{subsubsection*.7}%
\contentsline {subsubsection}{\nonumberline Dashes and Space Between ``e.g.''}{18}{subsubsection*.9}%
\contentsline {subsubsection}{\nonumberline Odds and Ends}{18}{subsubsection*.11}%
\contentsline {subsubsection}{\nonumberline Textsuperscript \textsuperscript {2}H vs Math Mode $^2$H}{18}{subsubsection*.13}%
\contentsline {subsection}{\numberline {5.1.2}Macros for Typesetting}{19}{subsection.5.1.2}%
\contentsline {subsubsection}{\nonumberline Row Vectors}{20}{subsubsection*.15}%
\contentsline {subsection}{\numberline {5.1.3}Macros with Arguments}{21}{subsection.5.1.3}%
\contentsline {paragraph}{\nonumberline More Complicated Macro Example}{22}{paragraph*.17}%
\contentsline {section}{\numberline {5.2}Hyphenation}{23}{section.5.2}%
\contentsline {subsection}{\numberline {5.2.1}Controlling Linebreaks}{23}{subsection.5.2.1}%
\contentsline {chapter}{\numberline {6}Variables}{25}{chapter.6}%
\contentsline {section}{\numberline {6.1}Booleans}{25}{section.6.1}%
\contentsline {subsection}{\numberline {6.1.1}Todonotes}{26}{subsection.6.1.1}%
\contentsline {section}{\numberline {6.2}Other Types of Variables}{26}{section.6.2}%
\contentsline {chapter}{\numberline {7}Referencing Equations}{28}{chapter.7}%
\contentsline {section}{\numberline {7.1}Repeating an Equation while Referring to the Original}{29}{section.7.1}%
\contentsline {section}{\numberline {7.2}Equations with Cases}{30}{section.7.2}%
\contentsline {section}{\numberline {7.3}Multiline Equation}{30}{section.7.3}%
\contentsline {chapter}{\numberline {8}Figures}{32}{chapter.8}%
\contentsline {section}{\numberline {8.1}Placement}{32}{section.8.1}%
\contentsline {section}{\numberline {8.2}Subplot Labelling}{33}{section.8.2}%
\contentsline {section}{\numberline {8.3}Cropping}{36}{section.8.3}%
\contentsline {chapter}{\numberline {9}Table and Sample Macros}{38}{chapter.9}%
\contentsline {part}{\numberline {II}Conclusion}{40}{part.2}%
\contentsline {part}{\numberline {III}Appendix}{41}{part.3}%
\contentsline {chapter}{\numberline {A}Including the Appendix in your Main File}{41}{appendix.A}%
\contentsline {chapter}{\numberline {B}Reusing (Parts of) an Equation}{41}{appendix.B}%
\contentsline {chapter}{\nonumberline Acknowledgements}{42}{chapter*.27}%
\contentsline {chapter}{Abbreviations}{43}{section*.28}%
\contentsline {chapter}{Bibliography}{44}{section*.30}%
\contentsline {chapter}{\nonumberline Academic CV}{47}{chapter*.32}%
\providecommand \tocbasic@end@toc@file {}\tocbasic@end@toc@file

104
Diss_titlepages.tex Normal file
View File

@@ -0,0 +1,104 @@
%formal requirements were stated here:
%https://www.tu-darmstadt.de/media/dezernat_ii/promotionen_dokumente/Dissertation-Titelblatt.de.pdf
%https://www.physik.tu-darmstadt.de/media/fachbereich_physik/formulare_3/promotionen/besonderebestimmungenderphysikzurpromo.pdf
%the following are custom variables which help keep information consistent across e.g. the titlepage, the page with bibliographic data and the document metadata (the latter being influenced by the pdfusetitle option of the hyperref package). These custom commands themselves do not directly create the metadata, but are used in the appropriate structures later on.
\def\myauthor{Yourname Here} % Who wrote the thesis
\def\mytitleprimary{Christoph's Template for Writing a Dissertation with \LaTeX} % title in the primary language, probably English or German
\def\mytitlesecondary{Christophs Vorlage zum Schreiben von Dissertationen mit \LaTeX} % title in the secondary language, probably German or English
\def\myversionGer{Vorgelegte}% submitted (Ger: ``Vorgelegte'') or accepted (Ger: ``Genehmigte'') dissertation?
\def\myversionEng{Submitted}% submitted or accepted dissertation?
\def\mydateSubmissionGer{2025-05-20} % date of submission in German-acceptable format, assuming the titlepage is in German
\def\mydateExamGer{2025-07-07} % date of oral exam in German-acceptable format, assuming the titlepage is in German
\def\mydateSubmissionEng{20th of May 2025} % date of submission in English-acceptable format, assuming the context of the bibliographic data page is English
\def\mydateExamEng{7th of July 2025} % date of oral exam in English-acceptable format, assuming the context of the bibliographic data page is English
%to help you not miss giving/updating information, here are some more variables even though they are only used once
\def\myplaceBirth{Birthtown}% your place of birth. You may need to comment/uncomment the use of this, depending on whether you want to make this personal information public.
\def\myplaceSignature{Darmstadt}% where will be when you sign the ``Erklärungen laut Promotionsordnung''?
\def\mydateSignature{1.1.2000}% when are you going to sign the ``Erklärungen laut Promotionsordnung''?
%You still need to set the date(s) of publication.
\begin{titlepage}
\centering
%\includegraphics{athene}
{\huge \textbf{\mytitleprimary}\\[\bigskipamount]
\mytitlesecondary\\[2\bigskipamount]}
Vom Fachbereich Physik\\
der Technischen Universität Darmstadt\\[\bigskipamount]%[2\baselineskip]
Zur Erlangung des Grades\\
{\huge \textbf{Doctor rerum naturalium\\[0.25\baselineskip]
(Dr. rer. nat.)}}\\[2\bigskipamount]
\myversionGer\\
{\huge \textbf{Dissertation}\\[0.25\baselineskip]
von\\[0.25\baselineskip]
\textbf{\myauthor}}%\\[0.25\baselineskip]
% aus \myplaceBirth}%\\[2\baselineskip]%the tuprints publication team recommended not to make personal data (place of birth) public.
\bigskip
Erstgutachter: Prof. Dr. Michael Vogel\\
Zweitgutachterin: Your Second Referee\\[2\baselineskip]
Darmstadt 2025\\
Datum der Einreichung: \mydateSubmissionGer\\
Datum der mündlichen Prüfung: \mydateExamGer
\end{titlepage}%
%
\newpage
%
\mytitleprimary\\
\mytitlesecondary\\[\bigskipamount]
\myversionEng %%keep the whitespace or use something like the xspace package in the definition of myversionEng.
doctoral thesis by \myauthor\\[\bigskipamount]
Date of submission: \mydateSubmissionEng\\
Date of oral exam: \mydateExamEng\\[\bigskipamount]
Darmstadt, Technische Universität Darmstadt%
\vfill
Bitte zitieren Sie dieses Dokument als:\\
%you get URN and URI when uploading your thesis to tuprints: start the entry creation there, save it without submitting it, then the URN and URI will be created. Copy the identifiers here, then change upload or replace the file in the tuprints submission. Note that the choice of licence under which the file is published gets reset when you delete the old file and create a new one. Note further that the URI before the tuprints entry is submitted differs slightly from the URI of the final version: In my case, while preparing the submission, the URI was https://tuprints.ulb.tu-darmstadt.de/31123/ and the final URI is https://tuprints.ulb.tu-darmstadt.de/id/eprint/31123 which has an additional ``/id/eprint'' towards the end. You should use the URI which links to the final version.
URN: xxx\\
URI: \url{xxx}\\[\bigskipamount]
%
Dieses Dokument wird bereitgestellt von tuprints,\\
E-Publishing-Service der TU Darmstadt\\
\url{http://tuprints.ulb.tu-darmstadt.de}\\
tuprints@ulb.tu-darmstadt.de\\
Jahr der Veröffentlichung der Dissertation auf TUprints: 2025\\[\bigskipamount]%year of publication with tuprints
%
Die Veröffentlichung steht unter folgender Creative Commons Lizenz:\\
Namensnennung -- Nicht kommerziell -- Share Alike 4.0 International\\
\url{https://creativecommons.org/licenses/by-nc-sa/4.0/legalcode.de}\\[0.25\baselineskip]
This work is licensed under a Creative Commons License:\\
Attribution -- NonCommercial -- ShareAlike 4.0 International\\
\url{https://creativecommons.org/licenses/by-nc-sa/4.0/}
%
\newpage
%These declarations needed to be included in the dissertation, even the submitted version. Sign them after printing. With a pen. On paper. Like in the old days.
{\huge\textbf{Erklärungen laut Promotionsordnung}}\\\\
{\large\textbf{\S8 Abs 1 lit. c PromO}}\\
Ich versichere hiermit, dass die elektronische Version meiner Dissertation mit der schriftlichen Version
übereinstimmt.\\\\
{\large\textbf{\S8 Abs 1 lit. d PromO}}\\
Ich versichere hiermit, dass zu einem vorherigen Zeitpunkt noch keine Promotion versucht wurde.\\\\
{\large\textbf{\S9 Abs 1 PromO}}\\
Ich versichere hiermit, dass die vorliegende Dissertation selbstständig und nur unter Verwendung
der angegebenen Quellen verfasst wurde.\\\\
{\large\textbf{\S9 Abs 2 PromO}}\\
Ich versichere hiermit, dass die vorliegende Dissertation noch nicht zu Prüfungszwecken gedient hat.\\\\
%
%
%signature: https://tex.stackexchange.com/questions/48152/signature-date-line-with-fixed-width
\noindent\begin{tabular}{ll}
& \\%vertical space
& \\%vertical space
\makebox[2.5in]{\hrulefill} & \makebox[2.5in]{\hrulefill}\\
\myauthor & \myplaceSignature, \mydateSignature\\%insert place and date of signature so people dont need to decipher you handwriting
\end{tabular}

BIN
Figures/EnergyLevels_Zeeman-QP1.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 23 KiB

BIN
Figures/FloryHugginsLattice_GeddeEtAl_Springer2019.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 38 KiB

BIN
Figures/PhaseDiagram_LCST_Rubinstein_OxfordUnivPress2004.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 24 KiB

BIN
Figures/Uncertainties-CN3E_Abs_17O_FullX.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 47 KiB

BIN
Figures/Uncertainties-CN3E_Abs_17O_ZoomX.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 57 KiB

BIN
Figures/Uncertainties-CN3E_Abs_2H_FullX.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 45 KiB

BIN
Figures/Uncertainties-CN3E_Abs_2H_ZoomX.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 63 KiB

BIN
Figures/pNIPAM-5A_ImOfen40C_Cropped-1_000h.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 11 KiB

BIN
Figures/pNIPAM-5A_ImOfen40C_Cropped-2_016h.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 7.5 KiB

BIN
Figures/pNIPAM-5A_ImOfen40C_Cropped-3_023h.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 6.7 KiB

BIN
Figures/pNIPAM-5A_ImOfen40C_Cropped-4_046h.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 9.3 KiB

BIN
Figures/pNIPAM-5A_ImOfen40C_Cropped-5_095h.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 10 KiB

BIN
Figures/pNIPAM-5A_ImOfen40C_Cropped-6_136h.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 8.6 KiB

BIN
Figures/pNIPAM-5A_ImOfen40C_Cropped-7_161h.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 7.2 KiB

BIN
Figures/pNIPAM-CN0E_MonoExp_Proof.png Normal file
View File

Binary file not shown.
Side by Side

After

Width:  |  Height:  |  Size: 64 KiB

24268
Promotion_Literatur.bib Normal file
View File

File diff suppressed because one or more lines are too long

92
pdfa.xmpi Normal file
View File

@@ -0,0 +1,92 @@
<?xpacket begin='' id='W5M0MpCehiHzreSzNTczkc9d' ?>
<x:xmpmeta xmlns:x="adobe:ns:meta/" x:xmptk="Adobe XMP Core 4.0-c316 44.253921, Sun Oct 01 2006 17:14:39">
<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#">
<rdf:Description rdf:about=""
xmlns:pdfaExtension="http://www.aiim.org/pdfa/ns/extension/"
xmlns:pdfaSchema="http://www.aiim.org/pdfa/ns/schema#"
xmlns:pdfaProperty="http://www.aiim.org/pdfa/ns/property#"
>
<pdfaExtension:schemas>
<rdf:Bag>
<rdf:li rdf:parseType="Resource">
<pdfaSchema:namespaceURI>http://ns.adobe.com/pdfx/1.3/</pdfaSchema:namespaceURI>
<pdfaSchema:prefix>pdfx</pdfaSchema:prefix>
<pdfaSchema:schema>PDF/X Schema</pdfaSchema:schema>
<pdfaSchema:property><rdf:Seq>
<rdf:li rdf:parseType="Resource">
<pdfaProperty:category>external</pdfaProperty:category>
<pdfaProperty:description>URL to an online version or preprint</pdfaProperty:description>
<pdfaProperty:name>AuthoritativeDomain</pdfaProperty:name>
<pdfaProperty:valueType>Text</pdfaProperty:valueType>
</rdf:li></rdf:Seq>
</pdfaSchema:property>
</rdf:li>
<rdf:li rdf:parseType="Resource">
<pdfaSchema:namespaceURI>http://www.aiim.org/pdfua/ns/id/</pdfaSchema:namespaceURI>
<pdfaSchema:prefix>pdfuaid</pdfaSchema:prefix>
<pdfaSchema:schema>PDF/UA ID Schema</pdfaSchema:schema>
<pdfaSchema:property><rdf:Seq>
<rdf:li rdf:parseType="Resource">
<pdfaProperty:category>internal</pdfaProperty:category>
<pdfaProperty:description>Part of PDF/UA standard</pdfaProperty:description>
<pdfaProperty:name>part</pdfaProperty:name>
<pdfaProperty:valueType>Integer</pdfaProperty:valueType>
</rdf:li></rdf:Seq>
</pdfaSchema:property>
</rdf:li>
<rdf:li rdf:parseType="Resource">
<pdfaSchema:schema>PRISM metadata</pdfaSchema:schema>
<pdfaSchema:namespaceURI>http://prismstandard.org/namespaces/basic/2.2/</pdfaSchema:namespaceURI>
<pdfaSchema:prefix>prism</pdfaSchema:prefix>
<pdfaSchema:property><rdf:Seq>
<rdf:li rdf:parseType="Resource">
<pdfaProperty:name>aggregationType</pdfaProperty:name>
<pdfaProperty:valueType>Text</pdfaProperty:valueType>
<pdfaProperty:category>external</pdfaProperty:category>
<pdfaProperty:description>The type of publication. If defined, must be one of book, catalog, feed, journal, magazine, manual, newsletter, pamphlet.</pdfaProperty:description>
</rdf:li>
<rdf:li rdf:parseType="Resource">
<pdfaProperty:name>url</pdfaProperty:name>
<pdfaProperty:valueType>URL</pdfaProperty:valueType>
<pdfaProperty:category>external</pdfaProperty:category>
<pdfaProperty:description>URL for the article or unit of content</pdfaProperty:description>
</rdf:li>
</rdf:Seq></pdfaSchema:property>
</rdf:li>
</rdf:Bag>
</pdfaExtension:schemas>
</rdf:Description>
<rdf:Description rdf:about="" xmlns:pdf="http://ns.adobe.com/pdf/1.3/">
<pdf:Producer>pdfTeX</pdf:Producer>
</rdf:Description>
<rdf:Description rdf:about="" xmlns:dc="http://purl.org/dc/elements/1.1/">
<dc:format>application/pdf</dc:format>
</rdf:Description>
<rdf:Description rdf:about="" xmlns:prism="http://prismstandard.org/namespaces/basic/2.2/">
</rdf:Description>
<rdf:Description rdf:about="" xmlns:pdfx="http://ns.adobe.com/pdfx/1.3/">
</rdf:Description>
<rdf:Description rdf:about="" xmlns:pdfaid="http://www.aiim.org/pdfa/ns/id/">
<pdfaid:part>1</pdfaid:part>
<pdfaid:conformance>B</pdfaid:conformance>
</rdf:Description>
<rdf:Description rdf:about="" xmlns:xmp="http://ns.adobe.com/xap/1.0/">
<xmp:CreatorTool>LaTeX with hyperref</xmp:CreatorTool>
<xmp:ModifyDate>2025-09-26T14:30:35+02:00</xmp:ModifyDate>
<xmp:CreateDate>2025-09-26T14:30:35+02:00</xmp:CreateDate>
<xmp:MetadataDate>2025-09-26T14:30:35+02:00</xmp:MetadataDate>
</rdf:Description>
<rdf:Description rdf:about="" xmlns:xmpRights = "http://ns.adobe.com/xap/1.0/rights/">
</rdf:Description>
<rdf:Description rdf:about="" xmlns:xmpMM="http://ns.adobe.com/xap/1.0/mm/">
<xmpMM:DocumentID>uuid:CA6226A2-F442-A149-C843-30AECCE1C213</xmpMM:DocumentID>
<xmpMM:InstanceID>uuid:CFC41B2C-8F61-1D42-A9E8-FC654F3051B8</xmpMM:InstanceID>
</rdf:Description>
</rdf:RDF>
</x:xmpmeta>
<?xpacket end='w'?>