% \chapter{Table and Sample Macros} % Here is a table, \cref{tab:list-of-samples}, where some cells are joined with the \mbox{\textbackslash multirow} command. Also, the sample-name macros (see \cref{sec:samplename_macros}) are used.\\ % \begin{table} \begin{tabular}{|c|c|c|c|} \hline \multirow{2}*{\textbf{Shorthand(s)}} & \textbf{EtOH} & \multirow{2}*{\textbf{Labelling}} & \multirow{2}*{\textbf{Mention in Publication}} \\ & \textbf{Water} & & \\ \hline \multirow{2}*{\pLinSample[D]{00}} & - & -, & \multirow{2}*{\autocite{Saeckel2024}} \\ & \SI{100}{\volpercent} & \chem{\textcolor{red}{^2H}_2O} & \\ \hline \multirow{2}*{\pLinSample{00}, \BulkSample{00}} & - & -, & \multirow{2}*{\autocite{Saeckel2024} (SI), \autocite{Saeckel2025}}\\ & \SI{100}{\volpercent} & \HTwoSvntnOHighlight & \\ \hline % \multirow{2}*{\pLinSample{05}} & \SI{95}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{-} \\ % & \SI{5}{\volpercent} & \HTwoSvntnOHighlight & \\ % \hline \multirow{2}*{\pLinSample{10}, \BulkSample{10}} & \SI{90}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\ & \SI{10}{\volpercent} & \HTwoSvntnOHighlight & \\ \hline \multirow{2}*{\pLinSample{20}, \BulkSample{20}} & \SI{80}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\ & \SI{20}{\volpercent} & \HTwoSvntnOHighlight & \\ \hline \multirow{2}*{\pLinSample[D]{30}, \BulkSample[D]{30}} & \SI{30}{\volpercent} & \chem{CH_3CH_2O\textcolor{red}{\underline{\textcolor{black}{H}}}}, & \multirow{2}*{\autocite{Saeckel2025}} \\ & \SI{70}{\volpercent} & \chem{\textcolor{red}{^2H}_2O} & \\ \hline \multirow{2}*{\pLinSample{30}, \BulkSample{30}} & \SI{30}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\ & \SI{70}{\volpercent} & \HTwoSvntnOHighlight & \\ \hline \multirow{2}*{\pLinSample{40}, \BulkSample{40}} & \SI{40}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\ & \SI{60}{\volpercent} & \HTwoSvntnOHighlight & \\ \hline \multirow{2}*{\pLinSample{50}, \BulkSample{50}} & \SI{50}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\ & \SI{50}{\volpercent} & \HTwoSvntnOHighlight & \\ \hline \multirow{2}*{\pLinSample{60}, \BulkSample{60}} & \SI{60}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\ & \SI{40}{\volpercent} & \HTwoSvntnOHighlight & \\ \hline \multirow{2}*{\pLinSample{70}, \BulkSample{70}} & \SI{70}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\ & \SI{30}{\volpercent} & \HTwoSvntnOHighlight & \\ \hline \multirow{2}*{\pLinSample{90}, \BulkSample{90}} & \SI{90}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\ & \SI{10}{\volpercent} & \HTwoSvntnOHighlight & \\ \hline \multirow{2}*{\pLinSample{100}, \BulkSample{100}} & \SI{100}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{\autocite{Saeckel2025}} \\ & - & - & \\ \hline \multirow{2}*{\pMGSample} & - & -, & \multirow{2}*{-} \\ & \SI{100}{\volpercent} & \chem{\textcolor{red}{^2H}_2O} & \\ \hline \multirow{2}*{\BayreuthSample[D]{00}} & - & -, & \multirow{2}*{\autocite{Saeckel2024}, SI} \\ & \SI{100}{\volpercent} & \chem{\textcolor{red}{^2H}_2O} & \\ \hline \multirow{2}*{\BayreuthSample{30}} & \SI{30}{\volpercent} & \EtOHDTwoChemHighlight, & \multirow{2}*{-} \\ & \SI{100}{\volpercent} & \chem{\textcolor{red}{^2H}_2O} & \\ \hline \end{tabular} \caption{List of samples, introducing abbreviations and corresponding solvent concentrations and labelling. Abbreviations denote polymer type (\textbf{Lin}ear, \textbf{M}icro\textbf{G}el, polymer-\textbf{F}ree), \textbf{E}thanol and \textbf{W}ater concentrations (in \si{\volpercent}) and a subscript to indicate which isotope labelling was used for the water component. Thereby the shorthand notation also implicitly gives the labelling of ethanol (W\textsubscript{O} $\rightarrow$ ethanol-d\textsubscript{2}, W\textsubscript{D} $\rightarrow$ natural abundance ethanol). Samples prepared for experiments in the \AEON are marked with a star, e.g. \BayreuthSample[D]{00}. All polymer samples listed here contain \SI{4}{\wtpercent} polymer. Note that for neat \DTwoO, data from literature \autocite{Hindman1971} was used. Note further that hydrogen exchange leads to a distribution of $^2$H between water and ethanol in samples such as \BulkSample[D]{30}, whereby it is to be expected that $\gtrsim\SI{90}{\percent}$ of $^2$H is located in water molecules.} \label{tab:list-of-samples} \end{table}