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% This is an auxiliary file used by the 'biblatex' package.
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% required.
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\begingroup
\makeatletter
\@ifundefined{ver@biblatex.sty}
  {\@latex@error
     {Missing 'biblatex' package}
     {The bibliography requires the 'biblatex' package.}
      \aftergroup\endinput}
  {}
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\datalist[entry]{anyt/global//global/global}
  \entry{Bischofberger2014}{article}{}
    \name{author}{3}{}{%
      {{hash=BI}{%
         family={Bischofberger},
         familyi={B\bibinitperiod},
         given={I.},
         giveni={I\bibinitperiod},
      }}%
      {{hash=CDCE}{%
         family={Calzolari},
         familyi={C\bibinitperiod},
         given={D.\bibnamedelima C.\bibnamedelima E.},
         giveni={D\bibinitperiod\bibinitdelim C\bibinitperiod\bibinitdelim
  E\bibinitperiod},
      }}%
      {{hash=TV}{%
         family={Trappe},
         familyi={T\bibinitperiod},
         given={V.},
         giveni={V\bibinitperiod},
      }}%
    }
    \list{publisher}{1}{%
      {The Royal Society of Chemistry}%
    }
  \keyw{pNIPAM,linear,microgel,cononsolvency,methanol,ethanol,propanol,SLS,radius
  of gyration,hydrodynamic radius,aqueous alcohol,excess enthalpy}
    \strng{namehash}{BI+1}
    \strng{fullhash}{BICDCETV1}
    \field{labelnamesource}{author}
    \field{labeltitlesource}{title}
    \field{labelalpha}{Bis+14}
    \field{sortinit}{B}
    \field{sortinithash}{B}
    \field{abstract}{%
    We investigate the co-nonsolvency of poly-N-isopropyl acrylamide (PNiPAM)
  in different water–alcohol mixtures and show that this phenomenon is due to
  two distinct solvation contributions governing the phase behavior of PNiPAM
  in the water-rich and alcohol-rich regime respectively. While hydrophobic
  hydration is the predominant contribution governing the phase behavior of
  PNiPAM in the water-rich regime{,} the mixing contributions governing the
  phase behavior of classical polymer solutions determine the phase behavior of
  PNiPAM in the alcohol-rich regime. This is evidenced by distinct scaling
  relations denoting the energetic state of the aqueous medium as a key
  parameter for the phase behavior of PNiPAM in the water-rich regime{,} while
  the volume fractions of respectively water{,} alcohol and PNiPAM become
  relevant parameters in the alcohol-rich regime. Adding alcohol to water
  decreases the energetics of the aqueous medium{,} which gradually suppresses
  hydrophobic hydration{,} while adding water to alcohol decreases the solvent
  quality. Consequently{,} PNiPAM is insoluble in the intermediate range of
  solvent composition{,} where neither hydrophobic hydration nor the mixing
  contributions prevail. This accounts for the co-nonsolvency phenomenon
  observed for PNiPAM in water–alcohol mixtures.%
    }
    \verb{doi}
    \verb 10.1039/C4SM01345J
    \endverb
    \field{issue}{41}
    \field{pages}{8288\bibrangedash 8295}
    \field{title}{Co-nonsolvency of PNiPAM at the transition between solvation
  mechanisms}
    \verb{url}
    \verb http://dx.doi.org/10.1039/C4SM01345J
    \endverb
    \field{volume}{10}
    \verb{file}
    \verb :Bischofberger2014 - Co Nonsolvency of PNiPAM at the Transition betwe
    \verb en Solvation Mechanisms.pdf:PDF;:CononsolvencyOfPNIPAMAtTheTransition
    \verb BetweenSolvationMechanisms-Corrections_BischofbergerEtAl_SoftMatter20
    \verb 14.pdf:PDF
    \endverb
    \field{journaltitle}{Soft Matter}
    \field{year}{2014}
  \endentry

  \entry{Costa2002}{article}{}
    \name{author}{2}{}{%
      {{hash=CROR}{%
         family={Costa},
         familyi={C\bibinitperiod},
         given={Ricardo O.\bibnamedelima R.},
         giveni={R\bibinitperiod\bibinitdelim O\bibinitperiod\bibinitdelim
  R\bibinitperiod},
      }}%
      {{hash=FRFS}{%
         family={Freitas},
         familyi={F\bibinitperiod},
         given={Roberto F.\bibnamedelima S.},
         giveni={R\bibinitperiod\bibinitdelim F\bibinitperiod\bibinitdelim
  S\bibinitperiod},
      }}%
    }
    \keyw{Hydrophobic hydration, Lower critical solution temperature, LCST,
  Thermoreversible hydrogel, thermosensitive, PNIPAM, aqueous alcohol, UCST,
  cloud point, cononsolvency, chain length, hydrophobic hydration OR hydration
  shell, hydrophobic hydration OR hydration shell OR hydration water,
  hydrophobic hydration OR hydration shell OR hydration water OR clathrate}
    \strng{namehash}{CRORFRFS1}
    \strng{fullhash}{CRORFRFS1}
    \field{labelnamesource}{author}
    \field{labeltitlesource}{title}
    \field{labelalpha}{CF02}
    \field{sortinit}{C}
    \field{sortinithash}{C}
    \field{abstract}{%
    In this work, the phase behavior of linear poly(N-isopropylacrylamide)
  (PNIPA) in water--solvent mixtures was investigated. Several solvents,
  including low molecular weight alcohols, were selected and phase separation
  temperatures were determined through cloud point measurements. All the
  studied systems exhibited the cononsolvency effect, i.e. lower PNIPA
  compatibility within definite ranges of composition in water-rich mixtures.
  However, it was first detected that the coexistence of phase separation
  temperatures---a lower critical solution temperature (LCST) with an upper
  critical solution temperature (UCST)---at higher solvent concentrations in
  most systems, depend on the hydrophobic nature of the solvent. The change
  from a LCST to a UCST was correlated with the competition between
  polymer--water and polymer--solvent interactions mediated by compositional
  factors. The effects produced by the different solvents tested were
  qualitatively compared, considering aspects related to their particular
  molecular structures, such as the potential to form hydrogen bonds and the
  implications of the size and shape of non-polar groups for hydrophobic
  hydration.%
    }
    \verb{doi}
    \verb https://doi.org/10.1016/S0032-3861(02)00507-4
    \endverb
    \field{issn}{0032-3861}
    \field{number}{22}
    \field{pages}{5879\bibrangedash 5885}
    \field{title}{Phase behavior of poly(N-iso\-propyl\-acryl\-amide) in binary
  aqueous solutions}
    \verb{url}
    \verb https://www.sciencedirect.com/science/article/pii/S0032386102005074
    \endverb
    \field{volume}{43}
    \verb{file}
    \verb :Costa2002 - Phase Behavior of Poly(N Isopropylacrylamide) in Binary
    \verb Aqueous Solutions.pdf:PDF
    \endverb
    \field{journaltitle}{Polymer}
    \field{year}{2002}
  \endentry

  \entry{Carr1954}{article}{}
    \name{author}{2}{}{%
      {{hash=CHY}{%
         family={Carr},
         familyi={C\bibinitperiod},
         given={H.\bibnamedelima Y.},
         giveni={H\bibinitperiod\bibinitdelim Y\bibinitperiod},
      }}%
      {{hash=PEM}{%
         family={Purcell},
         familyi={P\bibinitperiod},
         given={E.\bibnamedelima M.},
         giveni={E\bibinitperiod\bibinitdelim M\bibinitperiod},
      }}%
    }
    \list{publisher}{1}{%
      {American Physical Society}%
    }
    \keyw{NMR, CPMG, Spin Echoes}
    \strng{namehash}{CHYPEM1}
    \strng{fullhash}{CHYPEM1}
    \field{labelnamesource}{author}
    \field{labeltitlesource}{title}
    \field{labelalpha}{CP54}
    \field{sortinit}{C}
    \field{sortinithash}{C}
    \verb{doi}
    \verb 10.1103/PhysRev.94.630
    \endverb
    \field{issue}{3}
    \field{pages}{630\bibrangedash 638}
    \field{title}{Effects of Diffusion on Free Precession in Nuclear Magnetic
  Resonance Experiments}
    \verb{url}
    \verb https://link.aps.org/doi/10.1103/PhysRev.94.630
    \endverb
    \field{volume}{94}
    \verb{file}
    \verb :Carr1954 - Effects of Diffusion on Free Precession in Nuclear Magnet
    \verb ic Resonance Experiments.pdf:PDF
    \endverb
    \field{journaltitle}{Physical Review}
    \field{month}{05}
    \field{year}{1954}
  \endentry

  \entry{Fujishige1989}{article}{}
    \name{author}{3}{}{%
      {{hash=FS}{%
         family={Fujishige},
         familyi={F\bibinitperiod},
         given={Shouei},
         giveni={S\bibinitperiod},
      }}%
      {{hash=KK}{%
         family={Kubota},
         familyi={K\bibinitperiod},
         given={K.},
         giveni={K\bibinitperiod},
      }}%
      {{hash=AI}{%
         family={Ando},
         familyi={A\bibinitperiod},
         given={I.},
         giveni={I\bibinitperiod},
      }}%
    }
    \keyw{PNIPAM, molecular weight, concentration-dependent, light scattering,
  DLS, SLS, thermoresponsive}
    \strng{namehash}{FS+1}
    \strng{fullhash}{FSKKAI1}
    \field{labelnamesource}{author}
    \field{labeltitlesource}{title}
    \field{labelalpha}{Fuj+89}
    \field{sortinit}{F}
    \field{sortinithash}{F}
    \field{abstract}{%
    When aqueous solutions of well-fractionated poly(N-isopropylacrylamide)
  samples are heated, the polymer molecular dimensions change abruptly at a
  critical temperature (~32{$^{\circ}$}C), followed by aggregation of
  individual polymer chains dispersed in a state of globular particles to give
  an optically detectable phase transition. The transition occurs independently
  of either the molecular weight of the polymer (5x10^4 to 840x10^4) or its
  concentration (0.01 to 1wt%). This behavior is reminiscent of the thermal
  denaturation of proteins in aqueous medium.%
    }
    \verb{doi}
    \verb 10.1021/j100345a085
    \endverb
    \verb{eprint}
    \verb https://doi.org/10.1021/j100345a085
    \endverb
    \field{number}{8}
    \field{pages}{3311\bibrangedash 3313}
    \field{title}{Phase transition of aqueous solutions of
  poly(N-isopropylacrylamide) and poly(N-isopropylmethacrylamide)}
    \verb{url}
    \verb https://doi.org/10.1021/j100345a085
    \endverb
    \field{volume}{93}
    \verb{file}
    \verb :Fujishige1989 - Phase Transition of Aqueous Solutions of Poly(N Isop
    \verb ropylacrylamide) and Poly(N Isopropylmethacrylamide).pdf:PDF
    \endverb
    \field{journaltitle}{Journal of Physical Chemistry}
    \field{year}{1989}
  \endentry

  \entry{Gedde2019}{book}{}
    \name{author}{2}{}{%
      {{hash=GUW}{%
         family={Gedde},
         familyi={G\bibinitperiod},
         given={Ulf\bibnamedelima W.},
         giveni={U\bibinitperiod\bibinitdelim W\bibinitperiod},
      }}%
      {{hash=HMS}{%
         family={Hedenqvist},
         familyi={H\bibinitperiod},
         given={Mikael\bibnamedelima S.},
         giveni={M\bibinitperiod\bibinitdelim S\bibinitperiod},
      }}%
    }
    \list{publisher}{1}{%
      {Springer Cham}%
    }
    \keyw{book, polymers}
    \strng{namehash}{GUWHMS1}
    \strng{fullhash}{GUWHMS1}
    \field{labelnamesource}{author}
    \field{labeltitlesource}{title}
    \field{labelalpha}{GH19}
    \field{sortinit}{G}
    \field{sortinithash}{G}
    \verb{doi}
    \verb doi.org/10.1007/978-3-030-29794-7
    \endverb
    \field{edition}{2}
    \field{isbn}{978-3-030-29794-7}
    \field{series}{Graduate Texts in Physics}
    \field{title}{Fundamental Polymer Science}
    \verb{file}
    \verb :Gedde2019 - Fundamental Polymer Science.pdf:PDF
    \endverb
    \field{year}{2019}
  \endentry

  \entry{Halperin2015}{article}{}
    \name{author}{3}{}{%
      {{hash=HA}{%
         family={Halperin},
         familyi={H\bibinitperiod},
         given={Avraham},
         giveni={A\bibinitperiod},
      }}%
      {{hash=KM}{%
         family={Kr{\"{o}}ger},
         familyi={K\bibinitperiod},
         given={Martin},
         giveni={M\bibinitperiod},
      }}%
      {{hash=WFM}{%
         family={Winnik},
         familyi={W\bibinitperiod},
         given={Fran{\c{c}}oise\bibnamedelima M.},
         giveni={F\bibinitperiod\bibinitdelim M\bibinitperiod},
      }}%
    }
    \keyw{lower critical solution temperature, mesoglobules, metastability,
  tacticity, type II phase behavior, PNIPAM, review}
    \strng{namehash}{HA+1}
    \strng{fullhash}{HAKMWFM1}
    \field{labelnamesource}{author}
    \field{labeltitlesource}{title}
    \field{labelalpha}{Hal+15}
    \field{sortinit}{H}
    \field{sortinithash}{H}
    \field{abstract}{%
    In 1968, Heskins and Guillet published the first systematic study of the
  phase diagram of poly(N-isopropylacrylamide) (PNIPAM), at the time a
  {\textquotedblleft}young polymer{\textquotedblright} first synthesized in
  1956. Since then, PNIPAM became the leading member of the growing families of
  thermoresponsive polymers and of stimuli-responsive,
  {\textquotedblleft}smart{\textquotedblright} polymers in general. Its thermal
  response is unanimously attributed to its phase behavior. Yet, in spite of
  50\hspace{0.25em}years of research, a coherent quantitative picture remains
  elusive. In this Review we survey the reported phase diagrams, discuss the
  differences and comment on theoretical ideas regarding their possible
  origins. We aim to alert the PNIPAM community to open questions in this
  reputably mature domain.%
    }
    \verb{doi}
    \verb 10.1002/anie.201506663
    \endverb
    \verb{eprint}
    \verb https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201506663
    \endverb
    \field{number}{51}
    \field{pages}{15342\bibrangedash 15367}
    \field{title}{Poly(N-isopropyl\-acrylamide) Phase Diagrams: Fifty Years of
  Research}
    \verb{url}
    \verb https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201506663
    \endverb
    \field{volume}{54}
    \verb{file}
    \verb :Halperin2015 - Poly(N Isopropylacrylamide) Phase Diagrams_ Fifty Yea
    \verb rs of Research.pdf:PDF
    \endverb
    \field{journaltitle}{Angewandte Chemie - International Edition}
    \field{year}{2015}
  \endentry

  \entry{Hindman1971}{article}{}
    \name{author}{4}{}{%
      {{hash=HJC}{%
         family={Hindman},
         familyi={H\bibinitperiod},
         given={J.\bibnamedelima C.},
         giveni={J\bibinitperiod\bibinitdelim C\bibinitperiod},
      }}%
      {{hash=ZAJ}{%
         family={Zielen},
         familyi={Z\bibinitperiod},
         given={A.\bibnamedelima J.},
         giveni={A\bibinitperiod\bibinitdelim J\bibinitperiod},
      }}%
      {{hash=SA}{%
         family={Svirmickas},
         familyi={S\bibinitperiod},
         given={A.},
         giveni={A\bibinitperiod},
      }}%
      {{hash=WM}{%
         family={Wood},
         familyi={W\bibinitperiod},
         given={M.},
         giveni={M\bibinitperiod},
      }}%
    }
    \keyw{2h-nmr,17o-nmr,water,d2o,h217o,t1,spin-lattice
  relaxation,thermodynamics,entropy,enthalpy,SED,quadrupole coupling
  constant,qcc,H2O,nmr}
    \strng{namehash}{HJC+1}
    \strng{fullhash}{HJCZAJSAWM1}
    \field{labelnamesource}{author}
    \field{labeltitlesource}{title}
    \field{labelalpha}{Hin+71}
    \field{sortinit}{H}
    \field{sortinithash}{H}
    \verb{doi}
    \verb 10.1063/1.1674887
    \endverb
    \verb{eprint}
    \verb https://doi.org/10.1063/1.1674887
    \endverb
    \field{number}{2}
    \field{pages}{621\bibrangedash 634}
    \field{title}{Relaxation Processes in Water. The Spin–Lattice Relaxation
  of the Deuteron in D2O and Oxygen‐17 in H217O}
    \verb{url}
    \verb https://doi.org/10.1063/1.1674887
    \endverb
    \field{volume}{54}
    \verb{file}
    \verb :Hindman1971 - Relaxation Processes in Water. the Spin–Lattice Rela
    \verb xation of the Deuteron in D2O and Oxygen‐17 in H217O.pdf:PDF
    \endverb
    \field{journaltitle}{The Journal of Chemical Physics}
    \field{year}{1971}
  \endentry

  \entry{Korde2019}{article}{}
    \name{author}{2}{}{%
      {{hash=KJM}{%
         family={Korde},
         familyi={K\bibinitperiod},
         given={Jay\bibnamedelima M.},
         giveni={J\bibinitperiod\bibinitdelim M\bibinitperiod},
      }}%
      {{hash=KB}{%
         family={Kandasubramanian},
         familyi={K\bibinitperiod},
         given={Balasubramanian},
         giveni={B\bibinitperiod},
      }}%
    }
    \keyw{review, application focused, drug delivery, smart interfaces,
  application-focused}
    \strng{namehash}{KJMKB1}
    \strng{fullhash}{KJMKB1}
    \field{labelnamesource}{author}
    \field{labeltitlesource}{title}
    \field{labelalpha}{KK19}
    \field{sortinit}{K}
    \field{sortinithash}{K}
    \field{abstract}{%
    Over the past few decades, reversible responsive polymer materials have
  received interest conjointly from academia as well as industry owing to their
  ability to adapt to the surrounding environment, change adhesion and
  wettability of copious species upon extraneous stimulus, and regulate
  transportation of molecules and ions. Stimuli-responsive polymers or
  macromolecules also exhibit the ability to convert biochemical and chemical
  signals into mechanical, thermal, optical, and electrical signals, and vice
  versa, for which they are utilized in an array of applications like
  {\textquotedblleft}smart{\textquotedblright} optical systems, drug delivery,
  diagnostics, and tissue engineering, in conjunction with coatings, textiles,
  biosensors, and microelectromechanical systems. Extensive exploration on
  reversible responsive polymeric systems for a variety of engineering
  functionalities has been done; however, no collection of all the information
  is available as such. This Review consolidates profuse studies of reversible
  responsive polymers utilized in an assorted array of functions, inclusive of
  sensors, drug delivery, smart and self-healing coatings, etc.%
    }
    \verb{doi}
    \verb 10.1021/acs.iecr.9b00683
    \endverb
    \verb{eprint}
    \verb https://doi.org/10.1021/acs.iecr.9b00683
    \endverb
    \field{number}{23}
    \field{pages}{9709\bibrangedash 9757}
    \field{title}{Fundamentals and Effects of Biomimicking Stimuli-Responsive
  Polymers for Engineering Functions}
    \verb{url}
    \verb https://doi.org/10.1021/acs.iecr.9b00683
    \endverb
    \field{volume}{58}
    \verb{file}
    \verb :Korde2019 - Fundamentals and Effects of Biomimicking Stimuli Respons
    \verb ive Polymers for Engineering Functions.pdf:PDF;:FundamentalsAndEffect
    \verb sOfBiomimickingStimuliResponsivePolymersForEngineeringFunctions-Corre
    \verb ction_KordeEtAl_IndustrEngineerChemistryResearch2020.pdf:PDF
    \endverb
    \field{journaltitle}{Industrial and Engineering Chemistry Research}
    \field{year}{2019}
  \endentry

  \entry{Meiboom1958}{article}{}
    \name{author}{2}{}{%
      {{hash=MS}{%
         family={Meiboom},
         familyi={M\bibinitperiod},
         given={S.},
         giveni={S\bibinitperiod},
      }}%
      {{hash=GD}{%
         family={Gill},
         familyi={G\bibinitperiod},
         given={D.},
         giveni={D\bibinitperiod},
      }}%
    }
    \keyw{NMR, CPMG, Spin Echoes}
    \strng{namehash}{MSGD1}
    \strng{fullhash}{MSGD1}
    \field{labelnamesource}{author}
    \field{labeltitlesource}{title}
    \field{labelalpha}{MG58}
    \field{sortinit}{M}
    \field{sortinithash}{M}
    \verb{doi}
    \verb 10.1063/1.1716296
    \endverb
    \verb{eprint}
    \verb https://doi.org/10.1063/1.1716296
    \endverb
    \field{number}{8}
    \field{pages}{688\bibrangedash 691}
    \field{title}{Modified Spin-Echo Method for Measuring Nuclear Relaxation
  Times}
    \verb{url}
    \verb https://doi.org/10.1063/1.1716296
    \endverb
    \field{volume}{29}
    \field{journaltitle}{Review of Scientific Instruments}
    \field{year}{1958}
  \endentry

  \entry{PubChem2005NIPAM}{misc}{}
    \keyw{synthesis,molecular weights,NIPPA}
    \field{labelalpha}{Pub}
    \field{sortinit}{P}
    \field{sortinithash}{P}
    \verb{url}
    \verb https://pubchem.ncbi.nlm.nih.gov/compound/Propanamide_-N-isopropyl
    \endverb
    \field{urlday}{11}
    \field{urlmonth}{11}
    \field{urlyear}{2024}
  \endentry

  \entry{Rubinstein2004}{book}{}
    \name{author}{2}{}{%
      {{hash=RM}{%
         family={Rubinstein},
         familyi={R\bibinitperiod},
         given={Michael},
         giveni={M\bibinitperiod},
      }}%
      {{hash=CRH}{%
         family={Colby},
         familyi={C\bibinitperiod},
         given={Ralph\bibnamedelima H.},
         giveni={R\bibinitperiod\bibinitdelim H\bibinitperiod},
      }}%
    }
    \list{publisher}{1}{%
      {Oxford University Press}%
    }
    \strng{namehash}{RMCRH1}
    \strng{fullhash}{RMCRH1}
    \field{labelnamesource}{author}
    \field{labeltitlesource}{title}
    \field{labelalpha}{RC04}
    \field{sortinit}{R}
    \field{sortinithash}{R}
    \field{isbn}{019852059x}
    \field{title}{Polymer Physics}
    \field{year}{2004}
  \endentry

  \entry{Slichter1990}{book}{}
    \name{author}{1}{}{%
      {{hash=SCP}{%
         family={Slichter},
         familyi={S\bibinitperiod},
         given={Charles\bibnamedelima P.},
         giveni={C\bibinitperiod\bibinitdelim P\bibinitperiod},
      }}%
    }
    \name{editor}{1}{}{%
      {{hash=LHKV}{%
         family={Lotsch},
         familyi={L\bibinitperiod},
         given={Helmut K.\bibnamedelima V.},
         giveni={H\bibinitperiod\bibinitdelim K\bibinitperiod\bibinitdelim
  V\bibinitperiod},
      }}%
    }
    \list{publisher}{1}{%
      {Springer Berlin-Heidelberg}%
    }
    \keyw{NMR,theory,book}
    \strng{namehash}{SCP1}
    \strng{fullhash}{SCP1}
    \field{labelnamesource}{author}
    \field{labeltitlesource}{title}
    \field{labelalpha}{Sli90}
    \field{sortinit}{S}
    \field{sortinithash}{S}
    \verb{doi}
    \verb 10.1007/978-3-662-09441-9
    \endverb
    \field{edition}{Third}
    \field{isbn}{978-3-662-09441-9}
    \field{series}{Springer series in solid-state sciences}
    \field{title}{Principles of Magnetic Resonance}
    \verb{file}
    \verb :Slichter1963 - Principles of Magnetic Resonance_ with Examples from
    \verb Solid State Physics.pdf:PDF
    \endverb
    \field{year}{1990}
  \endentry

  \entry{Saeckel2024}{article}{}
    \name{author}{5}{}{%
      {{hash=SC}{%
         family={Säckel},
         familyi={S\bibinitperiod},
         given={Christoph},
         giveni={C\bibinitperiod},
      }}%
      {{hash=vKR}{%
         prefix={von},
         prefixi={v\bibinitperiod},
         family={Klitzing},
         familyi={K\bibinitperiod},
         given={Regine},
         giveni={R\bibinitperiod},
      }}%
      {{hash=SR}{%
         family={Siegel},
         familyi={S\bibinitperiod},
         given={Renée},
         giveni={R\bibinitperiod},
      }}%
      {{hash=SJ}{%
         family={Senker},
         familyi={S\bibinitperiod},
         given={Jürgen},
         giveni={J\bibinitperiod},
      }}%
      {{hash=VM}{%
         family={Vogel},
         familyi={V\bibinitperiod},
         given={Michael},
         giveni={M\bibinitperiod},
      }}%
    }
    \keyw{NMR,pNIPAM,2H-NMR,spin-lattice relaxation,T1,spin-spin
  relaxation,D2O,spectral density,field cycling,confinement,lcst}
    \strng{namehash}{SC+1}
    \strng{fullhash}{SCKRvSRSJVM1}
    \field{labelnamesource}{author}
    \field{labeltitlesource}{title}
    \field{labelalpha}{Sä+24}
    \field{sortinit}{S}
    \field{sortinithash}{S}
    \field{abstract}{%
    We use <sup>2</sup>H nuclear magnetic resonance to study the dynamics of
  deuterated water in a solution of linear poly (N-isopropyl acrylamide)
  (pNIPAM, 4 wt%) across its coil-to-globule transition at a lower critical
  solubility temperature (LCST) around 32°C. In agreement with previous
  studies, we find that the <sup>2</sup>H spin-lattice (T<sub>1</sub>) and, in
  particular, spin-spin (T<sub>2</sub>) relaxation times abruptly decrease when
  heating through the LCST, indicating that the polymer collapse causes an
  emergence of a water fraction with strongly reduced mobility. To quantify the
  dynamics of this slow water fraction, we exploit the fact that <sup>2</sup>H
  field-cycling relaxometry allows us to measure the spectral density of the
  water reorientation in a broad frequency range. We find that the slow water
  fraction is characterised by a broad logarithmic Gaussian distribution of
  correlation times (σ<sub>LG</sub> = 2.3), which is centred about
  τ<sub>LG</sub> ≈ 10<sup>–9</sup> s near the LCST. Hence, the common
  assumption of a Debye spectral density does not apply. We argue that a minor
  water fraction, which is located inside the pNIPAM globules and shows
  dynamics governed by the disordered polymer matrix, accompanies a major water
  fraction with bulk-like dynamics above the LCST. The former fraction amounts
  to about 0.4 water molecules per NIPAM monomer. Several findings indicate
  fast exchange between these bound and free water fractions on the
  T<sub>1</sub> and T<sub>2</sub> time scales.%
    }
    \verb{doi}
    \verb 10.3389/frsfm.2024.1379816
    \endverb
    \field{issn}{2813-0499}
    \field{title}{Water dynamics in solutions of linear poly (N-isopropyl
  acrylamide) studied by 2H NMR field-cycling relaxometry}
    \verb{url}
    \verb https://www.frontiersin.org/articles/10.3389/frsfm.2024.1379816
    \endverb
    \field{volume}{4}
    \verb{file}
    \verb :Saeckel2024 - Water Dynamics in Solutions of Linear Poly (N Isopropy
    \verb l Acrylamide) Studied by 2H NMR Field Cycling Relaxometry.pdf:PDF;:Fr
    \verb ontiers_2024_Jan_Published-2024-03-21-SI.PDF:PDF
    \endverb
    \field{journaltitle}{Frontiers in Soft Matter}
    \field{year}{2024}
  \endentry

  \entry{Saeckel2025}{article}{}
    \name{author}{3}{}{%
      {{hash=SC}{%
         family={Säckel},
         familyi={S\bibinitperiod},
         given={Christoph},
         giveni={C\bibinitperiod},
      }}%
      {{hash=vKR}{%
         prefix={von},
         prefixi={v\bibinitperiod},
         family={Klitzing},
         familyi={K\bibinitperiod},
         given={Regine},
         giveni={R\bibinitperiod},
      }}%
      {{hash=VM}{%
         family={Vogel},
         familyi={V\bibinitperiod},
         given={Michael},
         giveni={M\bibinitperiod},
      }}%
    }
    \list{publisher}{1}{%
      {The Royal Society of Chemistry}%
    }
    \keyw{NMR,pNIPAM,2H-NMR,spin-lattice relaxation,T1,spin-spin
  relaxation,D2O,cononsolvency,field cycling,confinement,aqueous
  alcohol,ethanol,h217o,T2,lcst,ucst}
    \strng{namehash}{SC+1}
    \strng{fullhash}{SCKRvVM1}
    \field{labelnamesource}{author}
    \field{labeltitlesource}{title}
    \field{labelalpha}{Sä+25}
    \field{sortinit}{S}
    \field{sortinithash}{S}
    \verb{doi}
    \verb 10.1039/d5sm00055f
    \endverb
    \field{title}{$^2$H and$^{17}$O NMR studies of solvent dynamics related to
  the cononsolvency of poly(N-isopropyl acrylamide) in ethanol-water mixtures}
    \verb{url}
    \verb http://dx.doi.org/10.1039/D5SM00055F
    \endverb
    \verb{file}
    \verb :/autohome/saeckech/Promotion/Papers/2024_Cononsolvency/Published/2HA
    \verb nd17ONMRStudiesOfSolventDynamicsRelatedToTheCononsolvencyOfPolyNIsopr
    \verb opylacrylamideInEthanolWaterMixtures_SaeckelEtAl_SoftMatter2025.pdf:P
    \verb DF;:/autohome/saeckech/Promotion/Papers/2024_Cononsolvency/Published/
    \verb 2HAnd17ONMRStudiesOfSolventDynamicsRelatedToTheCononsolvencyOfPolyNIs
    \verb opropylacrylamideInEthanolWaterMixtures_SaeckelEtAl_SoftMatter2025_SI
    \verb .pdf:PDF
    \endverb
    \field{journaltitle}{Soft Matter}
    \field{year}{2025}
  \endentry
\enddatalist
\endinput
